中国物理B ›› 2019, Vol. 28 ›› Issue (6): 68103-068103.doi: 10.1088/1674-1056/28/6/068103

• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇    下一篇

Fluorescence spectra of colloidal self-assembled CdSe nano-wire on substrate of porous Al2O3/Au nanoparticles

Xin Zhang(张欣), Li-Ping Shao(邵丽萍), Man Peng(彭嫚), Zhong-Chen Bai(白忠臣), Zheng-Ping Zhang(张正平), Shui-Jie Qin(秦水介)   

  1. 1 College of Big Data and Information Engineering, Guizhou University,, Guiyang 550025, China;
    2 College of Medicine, Guizhou University, Guiyang 550025, China;
    3 Guizhou Province Key Laboratory for Photoelectric Technology and Application, Guizhou University, Guiyang 550025, China
  • 收稿日期:2019-01-29 修回日期:2019-03-17 出版日期:2019-06-05 发布日期:2019-06-05
  • 通讯作者: Zhong-Chen Bai E-mail:zcbai@gzu.edu.cn
  • 基金资助:

    Project supported by the National Natural Science Foundation of China (Grant Nos. 61741505 and 61865002), the Guizhou Provincial Science and Technology Support Plan, China (Grant No QKHZ [2017]2887), the Guiding Local Science and Technology Development Plan of the Central Government of China (Grant No. QKZYD [2017]4004), the Guizhou Province Education and Teaching Reform for Graduate Student (Grant No. QJYH-JG [2016]15), the Guizhou University Introduces Talent Projects, China (Grant No. 2016002), and the Talents of Guizhou Municipal Science and Technology Cooperation Platform, China (Grant No. [2018]5781).

Fluorescence spectra of colloidal self-assembled CdSe nano-wire on substrate of porous Al2O3/Au nanoparticles

Xin Zhang(张欣)1,3, Li-Ping Shao(邵丽萍)1,3, Man Peng(彭嫚)1,3, Zhong-Chen Bai(白忠臣)2,3, Zheng-Ping Zhang(张正平)1,3, Shui-Jie Qin(秦水介)1,3   

  1. 1 College of Big Data and Information Engineering, Guizhou University,, Guiyang 550025, China;
    2 College of Medicine, Guizhou University, Guiyang 550025, China;
    3 Guizhou Province Key Laboratory for Photoelectric Technology and Application, Guizhou University, Guiyang 550025, China
  • Received:2019-01-29 Revised:2019-03-17 Online:2019-06-05 Published:2019-06-05
  • Contact: Zhong-Chen Bai E-mail:zcbai@gzu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Grant Nos. 61741505 and 61865002), the Guizhou Provincial Science and Technology Support Plan, China (Grant No QKHZ [2017]2887), the Guiding Local Science and Technology Development Plan of the Central Government of China (Grant No. QKZYD [2017]4004), the Guizhou Province Education and Teaching Reform for Graduate Student (Grant No. QJYH-JG [2016]15), the Guizhou University Introduces Talent Projects, China (Grant No. 2016002), and the Talents of Guizhou Municipal Science and Technology Cooperation Platform, China (Grant No. [2018]5781).

摘要:

We present a self-assembly method to prepare array nano-wires of colloidal CdSe quantum dots on a substrate of porous Al2O3 film modified by gold nanoparticles. The photoluminescence (PL) spectra of nanowires are in situ measured by using a scanning near-field optical microscopy (SNOM) probe tip with 100-nm aperture on the scanning near-field optical microscope. The results show that the binding sites from the edge of porous Al2O3 nanopores are combined with the carboxyl of CdSe quantum dots' surface to form an array of CdSe nanowires in the process of losing background solvent because of the gold nanoparticles filling the nano-holes of porous Al2O3 film. Compared with the area of non-self-assembled nano-wire, the fluorescence on the Al2O3/Au/CdSe interface is significantly enhanced in the self-assembly nano-wire regions due to the electron transfer conductor effect of the gold nanoparticles' surface. In addition, its full width at half maximum (FWHM) is also obviously widened. The method of enhancing fluorescence and energy transfer can widely be applied to photodetector, photocatalysis, optical display, optical sensing, and biomedical imaging, and so on.

关键词: enhanced photoluminescence, CdSe nano-wire, colloidal self-assembled method, porous Al2O3 film

Abstract:

We present a self-assembly method to prepare array nano-wires of colloidal CdSe quantum dots on a substrate of porous Al2O3 film modified by gold nanoparticles. The photoluminescence (PL) spectra of nanowires are in situ measured by using a scanning near-field optical microscopy (SNOM) probe tip with 100-nm aperture on the scanning near-field optical microscope. The results show that the binding sites from the edge of porous Al2O3 nanopores are combined with the carboxyl of CdSe quantum dots' surface to form an array of CdSe nanowires in the process of losing background solvent because of the gold nanoparticles filling the nano-holes of porous Al2O3 film. Compared with the area of non-self-assembled nano-wire, the fluorescence on the Al2O3/Au/CdSe interface is significantly enhanced in the self-assembly nano-wire regions due to the electron transfer conductor effect of the gold nanoparticles' surface. In addition, its full width at half maximum (FWHM) is also obviously widened. The method of enhancing fluorescence and energy transfer can widely be applied to photodetector, photocatalysis, optical display, optical sensing, and biomedical imaging, and so on.

Key words: enhanced photoluminescence, CdSe nano-wire, colloidal self-assembled method, porous Al2O3 film

中图分类号:  (Nanowires)

  • 81.07.Gf
81.16.Dn (Self-assembly) 67.25.dp (Films) 25.20.Lj (Photoproduction reactions)