中国物理B ›› 2019, Vol. 28 ›› Issue (2): 20204-020204.doi: 10.1088/1674-1056/28/2/020204

• GENERAL • 上一篇    下一篇

Competitive and synergistic adsorption of binary volatile organic compound mixtures on activated carbon

Jing Zhu(祝静), Hong-Lei Zhan(詹洪磊), Kun Zhao(赵昆), Xin-Yang Miao(苗昕扬), Qiong Zhou(周琼), Wen-Zheng Yue(岳文正)   

  1. 1 State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing 102249, China;
    2 Beijing Key Laboratory of Optical Detection Technology for Oil and Gas, China University of Petroleum, Beijing 102249, China;
    3 Petroleum and Chemical Industry Federation Key Laboratory of Oil and Gas Terahertz Spectroscopy and Photoelectric Detection, China University of Petroleum, Beijing 102249, China;
    4 Department of Material Science and Engineering, China University of Petroleum, Beijing 102249, China
  • 收稿日期:2018-07-26 修回日期:2018-10-12 出版日期:2019-02-05 发布日期:2019-02-05
  • 通讯作者: Hong-Lei Zhan E-mail:zhanhl@cup.edu.cn
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant No. 11574401), the Science Foundation of China University of Petroleum, Beijing (Grant Nos. 2462017YJRC029 and yjs2017019), and the Beijing Natural Science Foundation, China (Grant No. 1184016).

Competitive and synergistic adsorption of binary volatile organic compound mixtures on activated carbon

Jing Zhu(祝静)1,2, Hong-Lei Zhan(詹洪磊)2,4, Kun Zhao(赵昆)2,3, Xin-Yang Miao(苗昕扬)1,4, Qiong Zhou(周琼)4, Wen-Zheng Yue(岳文正)1   

  1. 1 State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing 102249, China;
    2 Beijing Key Laboratory of Optical Detection Technology for Oil and Gas, China University of Petroleum, Beijing 102249, China;
    3 Petroleum and Chemical Industry Federation Key Laboratory of Oil and Gas Terahertz Spectroscopy and Photoelectric Detection, China University of Petroleum, Beijing 102249, China;
    4 Department of Material Science and Engineering, China University of Petroleum, Beijing 102249, China
  • Received:2018-07-26 Revised:2018-10-12 Online:2019-02-05 Published:2019-02-05
  • Contact: Hong-Lei Zhan E-mail:zhanhl@cup.edu.cn
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant No. 11574401), the Science Foundation of China University of Petroleum, Beijing (Grant Nos. 2462017YJRC029 and yjs2017019), and the Beijing Natural Science Foundation, China (Grant No. 1184016).

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摘要： The adsorption of four substances and their binary mixture is investigated via the terahertz time domain spectroscopy (THz-TDS). The selected unary compound (ethanol, acetone, ethyl acetate, and n-propyl acetate) and binary mixture (solution 1 is composed of ethanol and acetone, and solution 2 is composed of ethyl acetate and n-propyl acetate) exhibit different adsorption behaviors with varied polarities. In comparison with single component, solution 1 shows shorter adsorption equilibrium time, faster adsorption rate, and stronger adsorption capacity, which conform to a synergistic adsorption mechanism, while the competitive behavior is attributed to the slower adsorption in solution 2. In addition, the pseudo-second-order equation with terahertz parameter is used to assess the rate of binary component organics. The present results indicate a further understanding of multicomponent adsorption mechanisms.

关键词: competitive adsorption, synergistic adsorption, oil-gas reservoirs, terahertz time domain spectroscopy (THz-TDS)

Abstract: The adsorption of four substances and their binary mixture is investigated via the terahertz time domain spectroscopy (THz-TDS). The selected unary compound (ethanol, acetone, ethyl acetate, and n-propyl acetate) and binary mixture (solution 1 is composed of ethanol and acetone, and solution 2 is composed of ethyl acetate and n-propyl acetate) exhibit different adsorption behaviors with varied polarities. In comparison with single component, solution 1 shows shorter adsorption equilibrium time, faster adsorption rate, and stronger adsorption capacity, which conform to a synergistic adsorption mechanism, while the competitive behavior is attributed to the slower adsorption in solution 2. In addition, the pseudo-second-order equation with terahertz parameter is used to assess the rate of binary component organics. The present results indicate a further understanding of multicomponent adsorption mechanisms.

Key words: competitive adsorption, synergistic adsorption, oil-gas reservoirs, terahertz time domain spectroscopy (THz-TDS)

中图分类号:  (General statistical methods)

  • 02.70.Rr
78.20.Ci (Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity)) 78.30.Jw (Organic compounds, polymers)