Synthesis and characterization of NaAlSi2O6 jadeite under 3.5 GPa

doi:10.1088/1674-1056/26/6/068202

中国物理B ›› 2017, Vol. 26 ›› Issue (6): 68202-068202.doi: 10.1088/1674-1056/26/6/068202

• INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY • 上一篇下一篇

Synthesis and characterization of NaAlSi₂O₆ jadeite under 3.5 GPa

National Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China

收稿日期:2017-01-02 修回日期:2017-02-16 出版日期:2017-06-05 发布日期:2017-06-05
通讯作者: Hong-An Ma, Xiao-Peng Jia E-mail:maha@jlu.edu.cn;jiaxp@jlu.edu.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 51172089 and 51171070) and the Graduate Innovation Fund of Jilin University, China (Grant No. 2016065).

Synthesis and characterization of NaAlSi₂O₆ jadeite under 3.5 GPa

National Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China

Received:2017-01-02 Revised:2017-02-16 Online:2017-06-05 Published:2017-06-05
Contact: Hong-An Ma, Xiao-Peng Jia E-mail:maha@jlu.edu.cn;jiaxp@jlu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 51172089 and 51171070) and the Graduate Innovation Fund of Jilin University, China (Grant No. 2016065).

摘要/Abstract

摘要： The high pressure and high temperature (HPHT) method is successfully used to synthesize jadeite in a temperature range of 1000℃-1400℃ under a pressure of 3.5 GPa. The initial raw materials are Na₂SiO₃·9H₂O and Al₂(SiO₃)₃. Through the HPHT method, the amorphous glass material is entirely converted into crystalline jadeite. We can obtain the good-quality jadeite by optimizing the reaction pressure and temperature. The measurements of x-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) and Raman scattering indicate that the properties of synthesized jadeite at 1260℃ under 3.5 GPa are extremely similar to those of the natural jadeite. What is more, the results will be valuable for understanding the formation process of natural jadeite. This work also reveals the mechanism for metamorphism of magma in the earth.

关键词: synthetic jadeite, structural properties, HPHT

Abstract: The high pressure and high temperature (HPHT) method is successfully used to synthesize jadeite in a temperature range of 1000℃-1400℃ under a pressure of 3.5 GPa. The initial raw materials are Na₂SiO₃·9H₂O and Al₂(SiO₃)₃. Through the HPHT method, the amorphous glass material is entirely converted into crystalline jadeite. We can obtain the good-quality jadeite by optimizing the reaction pressure and temperature. The measurements of x-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) and Raman scattering indicate that the properties of synthesized jadeite at 1260℃ under 3.5 GPa are extremely similar to those of the natural jadeite. What is more, the results will be valuable for understanding the formation process of natural jadeite. This work also reveals the mechanism for metamorphism of magma in the earth.

Key words: synthetic jadeite, structural properties, HPHT

中图分类号: (Synthesis, structure determination, structure modeling)

82.75.Fq

91.60.-x (Physical properties of rocks and minerals) 62.50.-p (High-pressure effects in solids and liquids)

李刚, 王健, 李亚东, 陈宁, 陈良超, 郭龙锁, 赵亮, 苗辛原, 马红安, 贾晓鹏. Synthesis and characterization of NaAlSi₂O₆ jadeite under 3.5 GPa[J]. 中国物理B, 2017, 26(6): 68202-068202.

Gang Li(李刚), Jian Wang(王健), Ya-Dong Li(李亚东), Ning Chen(陈宁), Liang-Chao Chen(陈良超), Long-Suo Guo(郭龙锁), Liang Zhao(赵亮), Xin-Yuan Miao(苗辛原), Hong-An Ma(马红安), Xiao-Peng Jia(贾晓鹏). Synthesis and characterization of NaAlSi₂O₆ jadeite under 3.5 GPa[J]. Chin. Phys. B, 2017, 26(6): 68202-068202.

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Synthesis and characterization of NaAlSi₂O₆ jadeite under 3.5 GPa

Synthesis and characterization of NaAlSi₂O₆ jadeite under 3.5 GPa

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