Fabrication and magnetic properties of 4SC(NH2)2-Ni0.97Cu0.03Cl2 single crystals

doi:10.1088/1674-1056/24/12/127503

中国物理B ›› 2015, Vol. 24 ›› Issue (12): 127503-127503.doi: 10.1088/1674-1056/24/12/127503

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Fabrication and magnetic properties of 4SC(NH₂)₂-Ni_0.97Cu_0.03Cl₂ single crystals

陈丽敏^a, 郭颖^b, 刘旭光^c, 解其云^a, 陶志阔^a, 谌静^a, 周玲玲^a, 刘春生^a

a Key Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing 210023, China;
b Jiangsu Key Laboratory of Big Data Analysis Technology; Jiangsu Collaborative Innovation Center on Atmospheric Environment and Equipment Technology, Nanjing 210044, China;
c Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei 230026, China

收稿日期:2015-06-05 修回日期:2015-08-21 出版日期:2015-12-05 发布日期:2015-12-05
通讯作者: Liu Chun-Sheng E-mail:csliu@njupt.edu.cn
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 11404316 and 11304159), the Natural Science Foundation of Jiangsu Province, China, and the Science Foundation of Nanjing University of Posts and Telecommunications, China (Grant Nos. BK20140863 and NY213075).

Fabrication and magnetic properties of 4SC(NH₂)₂-Ni_0.97Cu_0.03Cl₂ single crystals

Chen Li-Min (陈丽敏)^a, Guo Ying (郭颖)^b, Liu Xu-Guang (刘旭光)^c, Xie Qi-Yun (解其云)^a, Tao Zhi-Kuo (陶志阔)^a, Chen Jing (谌静)^a, Zhou Ling-Ling (周玲玲)^a, Liu Chun-Sheng (刘春生)^a

a Key Laboratory of Radio Frequency and Micro-Nano Electronics of Jiangsu Province, Nanjing 210023, China;
b Jiangsu Key Laboratory of Big Data Analysis Technology; Jiangsu Collaborative Innovation Center on Atmospheric Environment and Equipment Technology, Nanjing 210044, China;
c Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei 230026, China

Received:2015-06-05 Revised:2015-08-21 Online:2015-12-05 Published:2015-12-05
Contact: Liu Chun-Sheng E-mail:csliu@njupt.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 11404316 and 11304159), the Natural Science Foundation of Jiangsu Province, China, and the Science Foundation of Nanjing University of Posts and Telecommunications, China (Grant Nos. BK20140863 and NY213075).

摘要/Abstract

摘要： Single crystals of 4SC(NH₂)₂-Ni_1-xCu_xCl₂ (x=0.03) (Cu-DTN) containing spin S=1/2 Cu²⁺ and S=1 Ni²⁺ cations are synthesized by slow evaporation methods. Structural characterization demonstrates that the Cu-DTN is of a tetrahedral structure with lattice parameter c being 9.0995 Å, which is 1.32% expansion compared with that of parent material DTN due to the larger radius of the Cu ion. Direct current (DC) susceptibility measurements show that both the antiferromagnetic exchange interaction at low temperature and the large anisotropy of susceptibilities are suppressed after doping the Cu ion, which could be related to the structural distortion and the increase of the super-exchange paths in Cu-DTN.

关键词: magnetic metal-doped, magnetic materials, susceptibility, antiferromagnetic interaction

Abstract: Single crystals of 4SC(NH₂)₂-Ni_1-xCu_xCl₂ (x=0.03) (Cu-DTN) containing spin S=1/2 Cu²⁺ and S=1 Ni²⁺ cations are synthesized by slow evaporation methods. Structural characterization demonstrates that the Cu-DTN is of a tetrahedral structure with lattice parameter c being 9.0995 Å, which is 1.32% expansion compared with that of parent material DTN due to the larger radius of the Cu ion. Direct current (DC) susceptibility measurements show that both the antiferromagnetic exchange interaction at low temperature and the large anisotropy of susceptibilities are suppressed after doping the Cu ion, which could be related to the structural distortion and the increase of the super-exchange paths in Cu-DTN.

Key words: magnetic metal-doped, magnetic materials, susceptibility, antiferromagnetic interaction

中图分类号: (Magnetic impurity interactions)

75.30.Hx

75.30.Cr (Saturation moments and magnetic susceptibilities) 75.30.Gw (Magnetic anisotropy)

陈丽敏, 郭颖, 刘旭光, 解其云, 陶志阔, 谌静, 周玲玲, 刘春生. Fabrication and magnetic properties of 4SC(NH₂)₂-Ni_0.97Cu_0.03Cl₂ single crystals[J]. 中国物理B, 2015, 24(12): 127503-127503.

Chen Li-Min (陈丽敏), Guo Ying (郭颖), Liu Xu-Guang (刘旭光), Xie Qi-Yun (解其云), Tao Zhi-Kuo (陶志阔), Chen Jing (谌静), Zhou Ling-Ling (周玲玲), Liu Chun-Sheng (刘春生). Fabrication and magnetic properties of 4SC(NH₂)₂-Ni_0.97Cu_0.03Cl₂ single crystals[J]. Chin. Phys. B, 2015, 24(12): 127503-127503.

参考文献 33

[1]	Johnston D C, Kremer R K, Troyer M, Wang X, Klümper A, Bud'ko S L, Panchula A F and Canfield P C 2000 Phys. Rev. B 61 9558
[2]	Zvyagin S, Wosnitza J, Batista C D, Tsukamoto M, Kawashima N, Krzystek J, Zapf V S, Jaime M, Oliveira N F and Paduan-Filho A Jr 2007 Phys. Rev. Lett. 98 047205
[3]	Nikuni T, Oshikawa M, Oosawa A and Tanaka H 2000 Phys. Rev. Lett. 84 5868
[4]	Yamada F, Ono T, Fujisawa M, Tanaka H and Sakakibara T 2007 J. Magn. Magn. Mater. 310 1352
[5]	Jaime M, Correa V F, Harrison N, Batista C D, Kawashima N, Kazuma Y, Jorge G A, Stern R, Heinmaa I, Zvyagin S A, Sasago Y and Uchinokura K 2004 Phys. Rev. Lett. 93 087203
[6]	Sebastian S E 2005 Phys. Rev. B 72 100404
[7]	Radu T, Wilhelm H, Yushankhai V, Kovrizhin D, Coldea R, Tylczynski Z, Lühmann T and Steglich F 2005 Phys. Rev. Lett. 95 127202
[8]	Sun X F, Tao W, Fan C and Wang X M 2009 Phys. Rev. Lett. 102 167202
[9]	Zapf V S, Zocco D, Hansen B R, Jaime M, Harrison N, Batista C D, Kenzelmann M, Niedermayer C, Lacerda A and Paduan-Filho A 2006 Phys. Rev. Lett. 96 077204
[10]	Buttrey D J, Sullivan J D and Rheingold A L 1990 J. Solid State Chem. 88 291
[11]	Maslov S and Zheludev A 1998 Phys. Rev. B 57 68
[12]	Hase M, Terasaki I, Sasago Y, Uchinokura K and Obara H 1993 Phys. Rev. Lett. 71 4059
[13]	Oseroff S B, Cheong S W, Aktas B, Hundley M F, Fisk Z and Rupp L W 1995 Phys. Rev. Lett. 74 1450
[14]	Lussier J G, Coad S M, McMorrow D F and Paul D M K 1995 J. Phys.: Condens. Matter 7 L325
[15]	Sasgo Y, Koide N, Uchinokura K, Martin M C, Hase M, Hirota K and Shirane G 1996 Phys. Rev. B 54 R6835
[16]	Haravifard S, Rule K C, Dabkowska H A, Gaulin B D, Yamani Z and Buyers W J L 2007 J. Phys.: Condens. Matter 19 436222
[17]	Sebastian S E, Zapf V S, Harrison N, Batista C D, Sharma P A, Jaime M, Fisher I R and Lacerda A 2006 Phys. Rev. Lett. 96 189703
[18]	Yu R, Yin L, Sullivan N S, Xia J S and Huan C 2012 Nature 489 379
[19]	Yoshida Y, Kitano Y, Inagaki Y, Sakurai T, Kimata M, Okubo S, Ohta H, Koyama K, Motokawa M, Asano T and Ajiro Y 2007 J. Phys. Soc. Jpn. 76 113704
[20]	Inagaki Y, Wada O, Ienaga K, Morodomi H, Kawae T, Yoshida Y, Asano T, Frukawa Y and Ajiro Y 2009 J. Phys.: Conf. Ser. 150 042067
[21]	Chen L M, Tao W, Zhao Z Y, Li Q J, Ke W P, Wang X M, Liu X G, Fan C and Sun X F 2010 J. Cryst. Growth 312 3243
[22]	Paduan-Filho A, Chirico R D, Joung K O and Carlin R L 1981 J. Chem. Phys. 74 4103
[23]	Amparo L C and Truter M R 1963 J. Chem. Soc. 245 1309
[24]	Turnbull M M, Landee C P and Wells B M 2005 Coord. Chem. Rev. 249 2567
[25]	Block R and Jansen L 1982 Phys. Rev. B 26 148
[26]	Willett R D, Butcher R, Landee C P and Twamley B 2005 Polyhedron 24 2222
[27]	Snively L O, Haines D N, Emerson K and Drumheller J E 1982 Phys. Rev. B 26 5245
[28]	Willett R D, Twamley B, Montfrooij W, Granroth G G, Nagler S E, Hall D W, Park J H, Watson B C, Meisel M W and Talham D R 2006 Inorg. Chem. 45 7689
[29]	Straatman P, Block R and Jansen L 1984 Phys. Rev. B 29 1415
[30]	Marsh W E, Hatfield W E and Hodgson D J 1988 Inorg. Chem. 27 1819
[31]	Paduan-Filho A, Gratens X and Oliveira N F 2004 Phys. Rev. B 69 020405
[32]	Zapf V S, Correa V F, Batista C D, Murphy T P, Palm E D, Jaime M, Tozer S, Lacerda A and Paduan-Filho A 2007 J. Appl. Phys. 101 09E106
[33]	Zvyagin S A, Wosnitza J, Kolezhuk A K, Zapf V S, Jaime M, Paduan-Filho A, Glazkov V N, Sosin S S and Smirnov A I 2008 Phys. Rev. B 77 092413

Fabrication and magnetic properties of 4SC(NH₂)₂-Ni_0.97Cu_0.03Cl₂ single crystals

Fabrication and magnetic properties of 4SC(NH₂)₂-Ni_0.97Cu_0.03Cl₂ single crystals

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