Temperature-dependent Raman spectroscopic study of bismuth borate Bi2ZnOB2O6

doi:10.1088/1674-1056/24/1/017801

中国物理B ›› 2015, Vol. 24 ›› Issue (1): 17801-017801.doi: 10.1088/1674-1056/24/1/017801

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Temperature-dependent Raman spectroscopic study of bismuth borate Bi₂ZnOB₂O₆

张季^a, 张德明^b, 张庆礼^b, 殷绍唐^b

a Anhui Xin Hua University, Hefei 230088, China;
b Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China

收稿日期:2014-05-06 修回日期:2014-07-15 出版日期:2015-01-05 发布日期:2015-01-05
基金资助:
Project supported by the National Natural Science Foundation of China (Grant Nos. 50932005 and 51102239).

Temperature-dependent Raman spectroscopic study of bismuth borate Bi₂ZnOB₂O₆

Zhang Ji (张季)^a, Zhang De-Ming (张德明)^b, Zhang Qing-Li (张庆礼)^b, Yin Shao-Tang (殷绍唐)^b

a Anhui Xin Hua University, Hefei 230088, China;
b Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China

Received:2014-05-06 Revised:2014-07-15 Online:2015-01-05 Published:2015-01-05
Contact: Zhang Ji E-mail:18956063545@189.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 50932005 and 51102239).

摘要/Abstract

摘要：

A temperature-dependent Raman spectroscopic study on Bi₂ZnOB₂O₆ crystal was carried out to investigate the structure change of the crystal with the increase of temperature. Raman spectra of crystal Bi₂ZnOB₂O₆ were recorded in the spectral range 10-1600 cm^-1 at room temperature first. Compared with the vibrational spectra of the referred compounds, satisfactory assignment of most of the high-energy modes to vibrations of Bi-O, B-O, and Zn-O bonds was achieved. In particular, the Raman high-frequency peak located at 1344 cm^-1 was attributed to the B-O vibration in the BO₃ triangle. This temperature-dependent Raman spectroscopic study was carried out up to 600 ℃. It was found that all the Raman lines exhibit decreases in frequency and the widths of the Raman peaks increase with increasing temperature. No phase transition was observed under 600 ℃.

关键词: Bi₂ZnOB₂O₆ crystal, high temperature Raman spectroscopy, vibrational mode

Abstract:

Key words: Bi₂ZnOB₂O₆ crystal, high temperature Raman spectroscopy, vibrational mode

中图分类号: (Infrared and Raman spectra)

78.30.-j

81.70.-q (Methods of materials testing and analysis) 63.70.+h (Statistical mechanics of lattice vibrations and displacive phase transitions)

张季, 张德明, 张庆礼, 殷绍唐. Temperature-dependent Raman spectroscopic study of bismuth borate Bi₂ZnOB₂O₆[J]. 中国物理B, 2015, 24(1): 17801-017801.

Zhang Ji (张季), Zhang De-Ming (张德明), Zhang Qing-Li (张庆礼), Yin Shao-Tang (殷绍唐). Temperature-dependent Raman spectroscopic study of bismuth borate Bi₂ZnOB₂O₆[J]. Chin. Phys. B, 2015, 24(1): 17801-017801.

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Temperature-dependent Raman spectroscopic study of bismuth borate Bi₂ZnOB₂O₆

Temperature-dependent Raman spectroscopic study of bismuth borate Bi₂ZnOB₂O₆

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