Investigation of energy transfer from pyrromethene dye to cresyl violet 670 in ethanol

doi:10.1088/1674-1056/22/12/123402

中国物理B ›› 2013, Vol. 22 ›› Issue (12): 123402-123402.doi: 10.1088/1674-1056/22/12/123402

• ATOMIC AND MOLECULAR PHYSICS • 上一篇下一篇

Investigation of energy transfer from pyrromethene dye to cresyl violet 670 in ethanol

李晓晖^{a b}, 樊荣伟^{a b}, 于欣^{a b}, 陈德应^{a b}

a National Key Laboratory of Science and Technology on Tunable Laser, Harbin Institute of Technology, Harbin 150080, China;
b Institute of Opto-electronics, Harbin Institute of Technology, Harbin 150080, China

收稿日期:2013-02-27 修回日期:2013-05-21 出版日期:2013-10-25 发布日期:2013-10-25
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 61275127).

Investigation of energy transfer from pyrromethene dye to cresyl violet 670 in ethanol

Li Xiao-Hui (李晓晖)^{a b}, Fan Rong-Wei (樊荣伟)^{a b}, Yu Xin (于欣)^{a b}, Chen De-Ying (陈德应)^{a b}

a National Key Laboratory of Science and Technology on Tunable Laser, Harbin Institute of Technology, Harbin 150080, China;
b Institute of Opto-electronics, Harbin Institute of Technology, Harbin 150080, China

Received:2013-02-27 Revised:2013-05-21 Online:2013-10-25 Published:2013-10-25
Contact: Li Xiao-Hui, Chen De-Ying E-mail:lixiaohuihit@163.com;dychen@hit.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 61275127).

摘要/Abstract

摘要： In this paper, radiative and nonradiative energy transfer from laser dye pyrromethene 567 (PM567) and pyrromethene 580 (PM580) as donors to cresyl violet 670 (CV670) as acceptor in ethanol are investigated by using the steady-state emission measurement and the second harmonic generation (532 nm, ～ 13 ns) of a Q-switched Nd:YAG laser as the pumping source. The fluorescence intensity of the acceptor is improved due to the introduction of the donors, and the largest enhancement is obtained to be 128% in the PM567:CV670 dye mixture system. Energy transfer parameters, including the radiative and nonradiative energy transfer rate constants (K_R and K_NR), critical distance (R₀), and half quenching concentration ([A]_1/2) are investigated using the Stern–Volmer plots, and the acceptor concentration dependencies of radiative and nonradiative transfer efficiencies are also obtained. The values of K_R for PM567:CV670 and PM580:CV670 systems are 2032.0×10⁹ L·mol^-1·s^-1 and 2790.4×10⁹ L·mol^-1·s^-1, respectively, and the values of corresponding K_NR are 3.3×10⁹ L·mol^-1·s^-1 and 4.2×10⁹ L·mol^-1·s^-1, respectively. The results indicate that the dominant mechanism responsible for the energy transfer in the dye mixture systems is of the radiative type.

关键词: energy transfer, dye mixture, Stern–, Volmer plot, steady-state emission

Abstract: In this paper, radiative and nonradiative energy transfer from laser dye pyrromethene 567 (PM567) and pyrromethene 580 (PM580) as donors to cresyl violet 670 (CV670) as acceptor in ethanol are investigated by using the steady-state emission measurement and the second harmonic generation (532 nm, ～ 13 ns) of a Q-switched Nd:YAG laser as the pumping source. The fluorescence intensity of the acceptor is improved due to the introduction of the donors, and the largest enhancement is obtained to be 128% in the PM567:CV670 dye mixture system. Energy transfer parameters, including the radiative and nonradiative energy transfer rate constants (K_R and K_NR), critical distance (R₀), and half quenching concentration ([A]_1/2) are investigated using the Stern–Volmer plots, and the acceptor concentration dependencies of radiative and nonradiative transfer efficiencies are also obtained. The values of K_R for PM567:CV670 and PM580:CV670 systems are 2032.0×10⁹ L·mol^-1·s^-1 and 2790.4×10⁹ L·mol^-1·s^-1, respectively, and the values of corresponding K_NR are 3.3×10⁹ L·mol^-1·s^-1 and 4.2×10⁹ L·mol^-1·s^-1, respectively. The results indicate that the dominant mechanism responsible for the energy transfer in the dye mixture systems is of the radiative type.

Key words: energy transfer, dye mixture, Stern–, Volmer plot, steady-state emission

中图分类号: (Rotational and vibrational energy transfer)

34.50.Ez

33.50.-j (Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion)) 42.55.Mv (Dye lasers)

李晓晖, 樊荣伟, 于欣, 陈德应. Investigation of energy transfer from pyrromethene dye to cresyl violet 670 in ethanol[J]. 中国物理B, 2013, 22(12): 123402-123402.

Li Xiao-Hui (李晓晖), Fan Rong-Wei (樊荣伟), Yu Xin (于欣), Chen De-Ying (陈德应). Investigation of energy transfer from pyrromethene dye to cresyl violet 670 in ethanol[J]. Chin. Phys. B, 2013, 22(12): 123402-123402.

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Investigation of energy transfer from pyrromethene dye to cresyl violet 670 in ethanol

Investigation of energy transfer from pyrromethene dye to cresyl violet 670 in ethanol

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