ANALYSIS OF THE HDO ABSORPTION SPECTRUM BETWEEN 9600-10200cm-1

doi:10.1088/1009-1963/9/12/002

中国物理B ›› 2000, Vol. 9 ›› Issue (12): 885-891.doi: 10.1088/1009-1963/9/12/002

ANALYSIS OF THE HDO ABSORPTION SPECTRUM BETWEEN 9600-10200cm^-1

王湘淮, 何圣贵, 胡水明, 郑晶晶, 朱清时

Open Laboratory of Bond-Selective Chemistry and High Institute for Advanced Research, University of Science and Technology of China, Hefei, 230026, China

收稿日期:2000-05-29 修回日期:2000-07-14 出版日期:2000-12-15 发布日期:2005-06-10
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 29892161 and 29903010), by the Founation of the Chinese Academy of Sciences (Grant No: KJ951-A1-510), and by the National ‘Climbing' Project of China.

ANALYSIS OF THE HDO ABSORPTION SPECTRUM BETWEEN 9600-10200cm^-1

Wang Xiang-huai (王湘淮), He Sheng-gui (何圣贵), Hu Shui-ming (胡水明), Zheng Jing-jing (郑晶晶), Zhu Qing-shi (朱清时)

Open Laboratory of Bond-Selective Chemistry and High Institute for Advanced Research, University of Science and Technology of China, Hefei, 230026, China

Received:2000-05-29 Revised:2000-07-14 Online:2000-12-15 Published:2005-06-10
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 29892161 and 29903010), by the Founation of the Chinese Academy of Sciences (Grant No: KJ951-A1-510), and by the National ‘Climbing' Project of China.

摘要/Abstract

摘要： The absorption spectrum of HD¹⁶ O was recorded at a resolution of 0.02 cm^-1 with a Bruker IFS 120HR Fourier Transform Spectrometer in the region of 9600-10200 cm^-1. As far as we know it is the first time to record and analyze the HDO spectrum in this region which was assigned as the ν₁+2ν₃ and 2ν₂+2ν₃ bands. With the strong resonance interactions between these two bands considered, the spectroscopic parameters were optimized by the nonlinear least squares method.

Abstract: The absorption spectrum of HD¹⁶ O was recorded at a resolution of 0.02 cm^-1 with a Bruker IFS 120HR Fourier Transform Spectrometer in the region of 9600-10200 cm^-1. As far as we know it is the first time to record and analyze the HDO spectrum in this region which was assigned as the $\nu$₁+2$\nu$₃ and 2$\nu$₂+2$\nu$₃ bands. With the strong resonance interactions between these two bands considered, the spectroscopic parameters were optimized by the nonlinear least squares method.

Key words: Vib-rotational spectrum, HDO

中图分类号: (General molecular conformation and symmetry; stereochemistry)

33.15.Bh

33.15.Mt (Rotation, vibration, and vibration-rotation constants) 33.20.Kf (Visible spectra) 33.20.Vq (Vibration-rotation analysis)

王湘淮, 何圣贵, 胡水明, 郑晶晶, 朱清时. ANALYSIS OF THE HDO ABSORPTION SPECTRUM BETWEEN 9600-10200cm^-1[J]. 中国物理B, 2000, 9(12): 885-891.

Wang Xiang-huai (王湘淮), He Sheng-gui (何圣贵), Hu Shui-ming (胡水明), Zheng Jing-jing (郑晶晶), Zhu Qing-shi (朱清时). ANALYSIS OF THE HDO ABSORPTION SPECTRUM BETWEEN 9600-10200cm^-1[J]. Chinese Physics, 2000, 9(12): 885-891.

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ANALYSIS OF THE HDO ABSORPTION SPECTRUM BETWEEN 9600-10200cm^-1

ANALYSIS OF THE HDO ABSORPTION SPECTRUM BETWEEN 9600-10200cm^-1

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