中国物理B ›› 2002, Vol. 11 ›› Issue (10): 1047-1050.doi: 10.1088/1009-1963/11/10/315

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Investigation of the growth process of Si nanowires using the vapour-liquid-solid mechanism

邢英杰1, 奚中和1, 薛增泉1, 俞大鹏2   

  1. (1)Department of Electronics, Peking University, Beijing 100871, China; (2)School of Physics, Peking University, Beijing 100871, China
  • 收稿日期:2002-01-23 修回日期:2002-06-19 出版日期:2002-10-12 发布日期:2005-06-12
  • 基金资助:
    Project supported by the National Natural Science Foundation of China (Grant Nos 60071015 and 50025206) and by the Ministry of Science and Technology of China (Grant No 2001CB610503).

Investigation of the growth process of Si nanowires using the vapour-liquid-solid mechanism

Xing Ying-Jie (邢英杰)a, Yu Da-Peng (俞大鹏)b, Xi Zhong-He (奚中和)a, Xue Zeng-Quan (薛增泉)a   

  1. a Department of Electronics, Peking University, Beijing 100871, China; b School of Physics, Peking University, Beijing 100871, China
  • Received:2002-01-23 Revised:2002-06-19 Online:2002-10-12 Published:2005-06-12
  • Supported by:
    Project supported by the National Natural Science Foundation of China (Grant Nos 60071015 and 50025206) and by the Ministry of Science and Technology of China (Grant No 2001CB610503).

摘要: Silicon nanowires have been grown by the thermal decomposition of silane via the vapour-liquid-solid (VLS) mechanism. Three different stages of VLS growth (eutectic alloy formation, crystal nucleation and unidirectional growth) were studied separately using a scanning electron microscope and a high-resolution transmission electron microscope. Very short silicon nanowires prepared under particular conditions provide direct evidence of the VLS mechanism on a nanometre scale. Our results will be very helpful for the controllable synthesis of Si nanowires.

Abstract: Silicon nanowires have been grown by the thermal decomposition of silane via the vapour-liquid-solid (VLS) mechanism. Three different stages of VLS growth (eutectic alloy formation, crystal nucleation and unidirectional growth) were studied separately using a scanning electron microscope and a high-resolution transmission electron microscope. Very short silicon nanowires prepared under particular conditions provide direct evidence of the VLS mechanism on a nanometre scale. Our results will be very helpful for the controllable synthesis of Si nanowires.

Key words: nanowires, vapour-liquid-solid mechanism

中图分类号:  (Chemical synthesis methods)

  • 81.16.Be
82.30.Lp (Decomposition reactions (pyrolysis, dissociation, and fragmentation))