La-doped BiFeO3：Synthesis and multiferroic property study

doi:10.1088/1674-1056/23/4/047701

中国物理B ›› 2014, Vol. 23 ›› Issue (4): 47701-047701.doi: 10.1088/1674-1056/23/4/047701

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

La-doped BiFeO₃：Synthesis and multiferroic property study

蔺鹏婷^a, 李祥^a, 张丽^a, 阴津华^b, 程兴旺^a, 王志宏^c, 吴玉娟^d, 吴光恒^c

a School for Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;
b Physics Department, University of Science & Technology of Beijing, Beijing 100083, China;
c State Key Laboratory of Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
d Department of Materials and Mineral Resources Engineering, National Taipei University of Technology, Taiwan, China

收稿日期:2013-09-25 修回日期:2013-10-30 出版日期:2014-04-15 发布日期:2014-04-15

La-doped BiFeO₃：Synthesis and multiferroic property study

Lin Peng-Ting (蔺鹏婷)^a, Li Xiang (李祥)^a, Zhang Li (张丽)^a, Yin Jin-Hua (阴津华)^b, Cheng Xing-Wang (程兴旺)^a, Wang Zhi-Hong (王志宏)^c, Wu Yu-Chuan (吴玉娟)^d, Wu Guang-Heng (吴光恒)^c

a School for Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;
b Physics Department, University of Science & Technology of Beijing, Beijing 100083, China;
c State Key Laboratory of Magnetism, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
d Department of Materials and Mineral Resources Engineering, National Taipei University of Technology, Taiwan, China

Received:2013-09-25 Revised:2013-10-30 Online:2014-04-15 Published:2014-04-15
Contact: Li Xiang E-mail:aihyoo@bit.edu.cn
About author:77.80.Dj; 77.84.-s; 81.20.Ka

摘要/Abstract

摘要： A new sol-foam-gel method was developed to fabricate La-doped BiFeO₃ multiferroic materials. It was demonstrated that a gradual increase in the content of La-doped into BiFeO₃ results in its structure changing from rhombohedral to orthorhombic. A study of other property changes indicates that La-doping in BiFeO₃ enhances its ferromagnetism and ferroelectricity. A temperature-dependent magnetization study suggests that the magnetic property of La-doped BiFeO₃ samples varied from antiferromagnetic to ferromagnetic as the content of La-doped into BiFeO₃ increased from 0 to 20%. Unique temperature-dependent zero field cooling (ZFC) and field cooling (FC) magnetization behaviors were observed in 15% La-doped BiFeO₃ – its ZFC temperature-dependent magnetization being ferromagnetic and its FC temperature-dependent magnetization being antiferromagnetic. A possible mechanism of such an interesting M-T behavior is discussed.

关键词: multiferroic, BiFeO₃, ferromagnetism

Abstract: A new sol-foam-gel method was developed to fabricate La-doped BiFeO₃ multiferroic materials. It was demonstrated that a gradual increase in the content of La-doped into BiFeO₃ results in its structure changing from rhombohedral to orthorhombic. A study of other property changes indicates that La-doping in BiFeO₃ enhances its ferromagnetism and ferroelectricity. A temperature-dependent magnetization study suggests that the magnetic property of La-doped BiFeO₃ samples varied from antiferromagnetic to ferromagnetic as the content of La-doped into BiFeO₃ increased from 0 to 20%. Unique temperature-dependent zero field cooling (ZFC) and field cooling (FC) magnetization behaviors were observed in 15% La-doped BiFeO₃ – its ZFC temperature-dependent magnetization being ferromagnetic and its FC temperature-dependent magnetization being antiferromagnetic. A possible mechanism of such an interesting M-T behavior is discussed.

Key words: multiferroic, BiFeO₃, ferromagnetism

中图分类号: (Domain structure; hysteresis)

77.80.Dj

77.84.-s (Dielectric, piezoelectric, ferroelectric, and antiferroelectric materials) 81.20.Ka (Chemical synthesis; combustion synthesis)

蔺鹏婷, 李祥, 张丽, 阴津华, 程兴旺, 王志宏, 吴玉娟, 吴光恒. La-doped BiFeO₃：Synthesis and multiferroic property study[J]. 中国物理B, 2014, 23(4): 47701-047701.

Lin Peng-Ting (蔺鹏婷), Li Xiang (李祥), Zhang Li (张丽), Yin Jin-Hua (阴津华), Cheng Xing-Wang (程兴旺), Wang Zhi-Hong (王志宏), Wu Yu-Chuan (吴玉娟), Wu Guang-Heng (吴光恒). La-doped BiFeO₃：Synthesis and multiferroic property study[J]. Chin. Phys. B, 2014, 23(4): 47701-047701.

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La-doped BiFeO₃：Synthesis and multiferroic property study

La-doped BiFeO₃：Synthesis and multiferroic property study

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