Stabilization variation of organic conductor surfaces induced by \pi-\pi stacking interactions

The structures and stabilization of three crystal surfaces of TCNQ-based charge transfer complexes (CTCs) including PrQ(TCNQ)₂, MPM(TCNQ)₂, and MEM(TCNQ)₂, have been investigated by scanning tunneling microscopy (STM). The three bulk-truncated surfaces are all ac-surface, which are terminated with TCNQ molecular arrays. On the ac-surface of PrQ(TCNQ)₂, the TCNQ molecules form a tetramer structure with a wavelike row behavior and a \gamma angle of about 18° between adjacent molecules. Moreover, the dimer structures are resolved on both ac-surfaces of MPM(TCNQ)₂ and MEM(TCNQ)₂. In addition, the tetramer structure is the most stable structure, while the dimer structures are unstable and easily subject to the STM tip disturbance, which results in changeable unit cells. The main reasons for the surface stabilization variation among the three ac-surfaces are provided by using the '\pi-atom model'.