Rules essential for water molecular undercoordination
Sun Chang Q
       

Skin thermal-diffusivity elevation and specific-heat depression.[102,55] Numerical reproduction of the measured (insets) initial-temperature dependence of (a) the θ (θi, t) decay and (b) the skin-bulk temperature difference Δθ (θi, t) of warm water. High skin thermal diffusivity due to density loss ensures the characteristic intersection. (b) The Δθ (θi, t) arises from the skin lower specific heat because heat flux conserves at the interface.