Congruent melting of tungsten phosphide at 5 GPa and 3200 °C for growing its large single crystals |
(a) XRD patterns of recovered samples synthesized under different high P–T conditions. (b) High P–T forming region of WP. No reaction is observed below black dashed line. Phase-pure WP occurs above black line. Between the two lines formed is WP with by-products of WP2 and WP4. |