Tracking coherent low frequency vibrational information of Rh101 in ground and excited electronic states by broadband transient grating spectroscopy*

Project supported by the Science Challenge Project, China (Grant No. TZ2016001) and the National Natural Science Foundation of China (Grant No. 21673211).

Zhang Wei1, Liu Xiao-Song1, Wang Zan-Hao1, Song Yun-Fei2, Yang Yan-Qiang1, 2, †
       

(color online) (color online) Fourier transform power spectra in (a) ESA band-460 nm and (b) GSA & SE band-585 nm; Gaussian calculated Raman modes in minimum structure of (c) S1 state and (d) S0 state. Black-dotted lines connecting panels (a) and (b) represent the same vibrational modes. Dashed-blue arrows pointing to panel (c) from panel (d) denote calculated same vibrational mode blue shift from electronic ground state to excited state while the dashed red arrows refer to the corresponding experimental results.