Liu Zhen1, 2, Li Chun1, Shang Qiu-Yu1, Zhao Li-Yun1, Zhong Yang-Guang1, Gao Yan1, Du Wen-Na3, Mi Yang3, Chen Jie3, Zhang Shuai3, Liu Xin-Feng3, Fu Ying-Shuang2, †, Zhang Qing1, ‡
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(color online) (a) Schematic of hexagonal WGM perovskite of CH3NH3PbI3−aXa (X = I, Br, Cl) and the corresponding lasing mode.[52] (b) Schematic of small perovskite lasers based on a WGM cavity with square shape (left panel). The PL emission image from the CsPbBr3 NP above the threshold; the green color shows PL out-coupling from the NP (middle panel). The simulation of the electric field distribution for the square perovskite cavity; the pattern shows that the WGM is supported by the cavity, and the four corners show the stronger out-coupling than that at any other place (right panel).[53] (c) Schematic of a CsPbX3 (X = Cl, Br, or I) NP on mica substrate pumped by 400 nm laser excitation (left panel). Emission spectra with pump fluence increasing from 1.0 μJ·cm−2 to 3.2 μJ·cm−2 (right panel). The FWHM is ∼ 0.15 nm and the “S” curve shows a process from spontaneous emission to lasing. After photoexcitation with pump fluence below P ≈ 0.8 Pth and above threshold (≈ 1.2Pth), TRPL decay kinetics shows an ∼ 3.0 ns spontaneous emission decay process and a <30 ps lasing process, respectively.[53] |