Scanning the energy dissipation process of energetic materials based on excited state relaxation and vibration–vibration coupling<xref rid="cpb_27_10_104205fn1" ref-type="fn">*</xref><fn id="cpb_27_10_104205fn1"><label>*</label><p>Project supported by the National Natural Science Foundation of China (Grant Nos. 21573094, 11274142, 11474131, 11574112, and 51502109), the National Found for Fostering Talents of Basic Science, China (Grant No. J1103202), the Science Challenging Program (Grant No. JCKY2016212A501), and China Scholarship Council (CSC) during a visit of Ning Sui (Grant No. 201706175038) to MPIA is also acknowledged.</p></fn>

Scanning the energy dissipation process of energetic materials based on excited state relaxation and vibration–vibration coupling**

Project supported by the National Natural Science Foundation of China (Grant Nos. 21573094, 11274142, 11474131, 11574112, and 51502109), the National Found for Fostering Talents of Basic Science, China (Grant No. J1103202), the Science Challenging Program (Grant No. JCKY2016212A501), and China Scholarship Council (CSC) during a visit of Ning Sui (Grant No. 201706175038) to MPIA is also acknowledged.

Wang Wen-Yan¹, Sui Ning¹, Zhang Li-Quan¹, Wang Ying-Hui^{1, †}, Wang Lin¹, Wang Quan¹, Wang Jiao¹, Kang Zhi-Hui¹, Yang Yan-Qiang³, Zhou Qiang², Zhang Han-Zhuang^{1, ‡}

(color online) (a) The dynamic curve containing the Gaussian curve (orange line); (b) the relaxation curve involving exponential decay curve (black square), oscillation signal (red circle), dephasing component (blue line), and the amplitude relaxation of oscillation signal (green line); (c) the result of the Fourier transformation of the oscillation component as shown in panels (b); (d) the coupling mechanism of v₁ (682 cm⁻¹), v₂ (854 cm⁻¹), v₃ (1006 cm⁻¹), and v₄ (1023 cm⁻¹) vibrational modes in the nitrobenzene. Inset: The total signal relaxation curve in logarithmic coordinate.