Semi-analytical method of calculating the electrostatic interaction of colloidal solutions
Tian Hongqing, Lian Zengju
       

(color online) Sketch of two charged spherical colloids trapped in an air–water interface. Three coordinate systems are set in the system: two parallel spherical coordinates whose origins are fixed on the center of the colloids and one cylindrical coordinate whose origin is fixed on the center of the first particle-interface intersecting plane. The flat interface is on z = 0 and separates an upper air phase (dielectric constant ) from a lower electrolytic phase (dielectric constant ). Two colloids are trapped in the air–water interface with a center–interface distance h and the center–center distance d.