Observation of selective surface element substitution in FeTe0.5Se0.5 superconductor thin film exposed to ambient air by synchrotron radiation spectroscopy |
(a) The variation of Te-3d spectra with the increase of the etching thickness and after vacuum annealing. (b) Se-3d and Fe-3p spectra with the increase of the etching thickness and after vacuum annealing compared with those of the as-grown film, a peak at 52.9 eV appears after etching and decreases after annealing. |