Equivalent for small AC perturbation, which can explain the NC. Rc is the total series resistance generally caused by constant resistance of the cell; Rr is the recombination resistance including Rrac and Rrdc, and Cr is the recombination capacitance relate the electron transport process in film; Cμ is the chemical capacitance that stands for the change of electron density as a function of the Fermi level; Rct is a charge-transfer resistance related to the traditional recombination of free carriers at electrolyte interface. |