Optimal migration path of Ag in HfO2: A first-principles study |
(a) Smaller balls represent O atoms, middling balls denote the Ag atoms, and bigger balls refer to Hf atoms. A supercell (2×2×2) containing 100 atoms with four Ag atoms in each of four unit cell at position 1. (b) The thermal motion position coordinates of Ag at the position 1 after sufficient relaxation of the structure. A cluster refers to the corresponding thermal motion position coordinates of one Ag. |