Oscillator strength and cross section study of the valence-shell excitations of NO2 by fast electron scattering

doi:10.1088/1674-1056/acf5d6

中国物理B ›› 2023, Vol. 32 ›› Issue (11): 113402-113402.doi: 10.1088/1674-1056/acf5d6

所属专题： Featured Column — DATA PAPER

Oscillator strength and cross section study of the valence-shell excitations of NO₂ by fast electron scattering

Qiang Sun(孙强), Jin-Feng Chen(陈锦峰), Zhi-Wei Nie(聂智伟), Jian-Hui Zhu(朱剑辉), and Lin-Fan Zhu(朱林繁)^†

Department of Modern Physics, University of Science and Technology of China, Hefei 230026, China

收稿日期:2023-08-02 修回日期:2023-08-25 接受日期:2023-09-01 出版日期:2023-10-16 发布日期:2023-10-26
通讯作者: Lin-Fan Zhu E-mail:lfzhu@ustc.edu.cn
基金资助:
Project supported by the National Key Research and Development Program of China (Grant No. 2022YFA1602500) and the National Natural Science Foundation of China (Grant Nos. 12334010 and U1932207).

Oscillator strength and cross section study of the valence-shell excitations of NO₂ by fast electron scattering

Qiang Sun(孙强), Jin-Feng Chen(陈锦峰), Zhi-Wei Nie(聂智伟), Jian-Hui Zhu(朱剑辉), and Lin-Fan Zhu(朱林繁)^†

Department of Modern Physics, University of Science and Technology of China, Hefei 230026, China

Received:2023-08-02 Revised:2023-08-25 Accepted:2023-09-01 Online:2023-10-16 Published:2023-10-26
Contact: Lin-Fan Zhu E-mail:lfzhu@ustc.edu.cn
Supported by:
Project supported by the National Key Research and Development Program of China (Grant No. 2022YFA1602500) and the National Natural Science Foundation of China (Grant Nos. 12334010 and U1932207).

摘要/Abstract

摘要： Oscillator strengths and cross sections of the valence-shell excitations in NO₂ are of great significance in testing the theoretical calculations and monitoring the state of the ozone layer in the earth's atmosphere. In the present work, the generalized oscillator strengths of the valence-shell excitations in NO₂ were obtained based on the fast electron scattering technique at an incident electron energy of 1.5 keV and an energy resolution of about 70 meV. By extrapolating the generalized oscillator strengths to the limit of a zero squared momentum transfer, the optical oscillator strengths for the dipole-allowed transitions have been obtained, which provide an independent cross check to the previous experimental results. Based on the BE-scaling method, the corresponding integral cross sections have also been derived systematically from the excitation threshold to 5000 eV. The present dynamic parameters can provide the fundamental spectroscopic data of NO₂ and have important applications in the studies of atmospheric science. The datasets presented in this paper, including the GOSs, OOSs and ICSs, are openly available at https://doi.org/10.57760/sciencedb.j00113.00156.

关键词: nitrogen dioxide, oscillator strength, integral cross section, electron scattering

Abstract: Oscillator strengths and cross sections of the valence-shell excitations in NO₂ are of great significance in testing the theoretical calculations and monitoring the state of the ozone layer in the earth's atmosphere. In the present work, the generalized oscillator strengths of the valence-shell excitations in NO₂ were obtained based on the fast electron scattering technique at an incident electron energy of 1.5 keV and an energy resolution of about 70 meV. By extrapolating the generalized oscillator strengths to the limit of a zero squared momentum transfer, the optical oscillator strengths for the dipole-allowed transitions have been obtained, which provide an independent cross check to the previous experimental results. Based on the BE-scaling method, the corresponding integral cross sections have also been derived systematically from the excitation threshold to 5000 eV. The present dynamic parameters can provide the fundamental spectroscopic data of NO₂ and have important applications in the studies of atmospheric science. The datasets presented in this paper, including the GOSs, OOSs and ICSs, are openly available at https://doi.org/10.57760/sciencedb.j00113.00156.

Key words: nitrogen dioxide, oscillator strength, integral cross section, electron scattering

中图分类号: (Molecular excitation and ionization)

34.80.Gs

25.30.Dh (Inelastic electron scattering to specific states) 95.30.Ky (Atomic and molecular data, spectra, and spectralparameters (opacities, rotation constants, line identification, oscillator strengths, gf values, transition probabilities, etc.))

Qiang Sun(孙强), Jin-Feng Chen(陈锦峰), Zhi-Wei Nie(聂智伟), Jian-Hui Zhu(朱剑辉), and Lin-Fan Zhu(朱林繁). Oscillator strength and cross section study of the valence-shell excitations of NO₂ by fast electron scattering[J]. 中国物理B, 2023, 32(11): 113402-113402.

参考文献

[1] Katz M 1970 Can. J. Chem. Eng. 48 3
[2] Fuglestvedt J, Isaksen I and Wang W C 1996 Clim. Change 34 405
[3] Abedi A, Cicman P, Coupier B, Gulejov B, Buchanan G, Marston G, Mason N, Scheier P and Mrk T 2004 Int. J. Mass Spectrom. 232 147
[4] Rowland F S and Molina M J 1975 Rev. Geophys. 13 1
[5] Elliot S and Rowland F S 1987 J. Chem. Educ. 64 387
[6] Rolke J, Cann N, Zheng Y, Hollebone B, Brion C, Wang Y and Davidson E 1995 Chem. Phys. 201 1
[7] Hall T C J and Blacet F E 1952 J. Chem. Phys. 20 1745
[8] Verhoek F H and Daniels F 1931 J. Am. Chem. Soc. 53 1250
[9] Nakayama T, Kitamura M Y and Watanabe K 1959 J. Chem. Phys. 30 1180
[10] Johnston H S and Graham R 1974 Can. J. Chem. 52 1415
[11] Bass A M, Ledford A E J and Laufer A H 1976 J. Res. Natl. Bur. Stand. A:Phys Chem. 80A 143
[12] Schneider W, Moortgat G K, Tyndall G S and Burrows J P 1987 J. Photochem. Photobiol. A:Chem. 40 195
[13] Mrienne M F, Jenouvrier A and Coquart B 1995 J. Atmos. Chem. 20 281
[14] Coquart B, Jenouvrier A and Mrienne M F 1995 J. Atmos. Chem. 21 251
[15] Jenouvrier A, Coquart B and Mrienne M F 1996 J. Atmos. Chem. 25 21
[16] MrienneM F, Jenouvrier A and Coquart B L J P 1997 J. Atmos. Chem. 27 219
[17] Bogumil K, Orphal J, Homann T, Voigt S, Spietz P, Fleis-chmann O, Vogel A, Hartmann M, Kromminga H, Bovensmann H, Frerick J and Burrows J 2003 J. Photochem. Photobiol. A:Chem. 157 167
[18] Au J W and Brion C 1997 Chem. Phys. 218 109
[19] McEwen K L 2004 J. Chem. Phys. 32 1801
[20] Gangi R A and Burnelle L 2003 J. Chem. Phys. 55 851
[21] Lassettre E N 1965 J. Chem. Phys. 43 4479
[22] Tanaka H, Brunger M J, Campbell L, Kato H, Hoshino M and Rau A R P 2016 Rev. Mod. Phys. 88 025004
[23] Bethe H 1930 Ann. Phys. 397 325
[24] Wu S L, Zhong Z P, Feng R F, Xing S L, Yang B X and Xu K Z 1995 Phys. Rev. A 51 4494
[25] Xu K Z, Feng R F, Wu S L, Ji Q, Zhang X J, Zhong Z P and Zheng Y 1996 Phys. Rev. A 53 3081
[26] Liu X J, Zhu L F, Jiang X M, Yuan Z S, Cai B, Chen X J and Xu K Z 2001 Rev. Sci. Instrum. 72 3357
[27] Khakoo M A and Trajmar S 1986 Phys. Rev. A 34 138
[28] Nickel J C, Zetner P W, Shen G and Trajmar S 1989 J. Phys. E:Sci. Instr. 22 730
[29] Ni D D, Xu L Q, Liu Y W, Yang K, Hiraoka N, Tsuei K D and Zhu L F 2017 Phys. Rev. A 96 012518
[30] Liu Y W, Xu L Q, Ni D D, Xu X, Huang X C and Zhu L F 2017 J. Geophys. Res. Space Phys. 122 3459
[31] Zhong Z P, Feng R F, Xu K Z, Wu S L, Zhu L F, Zhang X J, Ji Q and Shi Q C 1997 Phys. Rev. A 55 1799
[32] Bethe V H 1932 Z. Phys. 76 293
[33] Cann N M and Thakkar A J 2002 J. Electron. Spectrosc. Relat. Phenom. 123 143
[34] Xie B P, Zhu L F, Yang K, Zhou B, Hiraoka N, Cai Y Q, Yao Y, Wu C Q, Wang E L and Feng D L 2010 Phys. Rev. A 82 032501
[35] Zhu L F, Wang L S, Xie B P, Yang K, Hiraoka N, Cai Y Q and Feng D L 2011 J. Phys. B:At. Mol. Opt. Phys. 44 025203
[36] Inokuti M 1971 Rev. Mod. Phys. 43 297
[37] Kim Y K 2001 Phys. Rev. A. 64 032713
[38] Kim Y K 2007 J. Chem. Phys. 126 064305
[39] Xu Y C, Du X J, Li T J, Wang L H, Ma Z R and Zhu L F 2020 Plasma Sources Sci. Technol. 29 085005
[40] Du X J, Xu Y C, Wang L H, Li T J, Ma Z R and Zhu L F 2020 J. Phys. B:At. Mol. Opt. Phys. 53 175103
[41] Wang S X and Zhu L F 2022 Chin. Phys. B 31 083401
[42] Mulliken R S 1942 Rev. Mod. Phys. 14 204

Oscillator strength and cross section study of the valence-shell excitations of NO₂ by fast electron scattering

Oscillator strength and cross section study of the valence-shell excitations of NO₂ by fast electron scattering

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