Absence of magnetic order in dichloro [1,2-bis (diphenylphosphino) ethane] nickel2 + single crystal

doi:10.1088/1674-1056/abe233

中国物理B ›› 2021, Vol. 30 ›› Issue (5): 57501-057501.doi: 10.1088/1674-1056/abe233

Absence of magnetic order in dichloro [1,2-bis (diphenylphosphino) ethane] nickel^{2 +} single crystal

Shuaiqi Ma(马帅奇)^1,3, Linlin An(安琳琳)^2,3, and Xiangde Zhu(朱相德)^3,†

1 Institute of Physical Science and Information Technology, Anhui University, Hefei 230601, China;
2 School of Electronic Science and Applied Physics, Hefei University of Technology, Hefei 230009, China;
3 Anhui Province Key Laboratory of Condensed Matter Physics at Extreme Conditions, High Magnetic Field Laboratory, Chinese Academy of Sciences, Hefei 230031, China

收稿日期:2021-01-07 修回日期:2021-01-26 接受日期:2021-02-02 出版日期:2021-05-14 发布日期:2021-05-14
通讯作者: Xiangde Zhu E-mail:xdzhu@hmfl.ac.cn
基金资助:
Project supported by the National Key Research and Development Program of China (Grant No. 2017YFA0403502), the National Natural Science Foundation of China, and Youth Innovation Promotion Association of Chinese Academy of Sciences (Grant No. 2017483). A portion of this work was supported by the High Magnetic Field Laboratory of Anhui Province, China.

Absence of magnetic order in dichloro [1,2-bis (diphenylphosphino) ethane] nickel^{2 +} single crystal

Shuaiqi Ma(马帅奇)^1,3, Linlin An(安琳琳)^2,3, and Xiangde Zhu(朱相德)^3,†

1 Institute of Physical Science and Information Technology, Anhui University, Hefei 230601, China;
2 School of Electronic Science and Applied Physics, Hefei University of Technology, Hefei 230009, China;
3 Anhui Province Key Laboratory of Condensed Matter Physics at Extreme Conditions, High Magnetic Field Laboratory, Chinese Academy of Sciences, Hefei 230031, China

Received:2021-01-07 Revised:2021-01-26 Accepted:2021-02-02 Online:2021-05-14 Published:2021-05-14
Contact: Xiangde Zhu E-mail:xdzhu@hmfl.ac.cn
Supported by:
Project supported by the National Key Research and Development Program of China (Grant No. 2017YFA0403502), the National Natural Science Foundation of China, and Youth Innovation Promotion Association of Chinese Academy of Sciences (Grant No. 2017483). A portion of this work was supported by the High Magnetic Field Laboratory of Anhui Province, China.

摘要/Abstract

摘要： Dichloro [1,2-bis (diphenylphosphino) ethane] nickel²⁺ (NiCl₂(dppe)) is an organic compound containing C₂₆H₂₄P₂(dppe) molecules and Cl^-, Ni²⁺ ions. The large-size NiCl₂(dppe) single crystals with longest dimension of 4 mm were grown by the method of slow evaporation of organic solution. Single crystal x-ray diffraction spectrum indicates that the single crystal is of high quality. Magnetization results of the NiCl₂(dppe) single crystals show an anisotropic paramagnetism behavior and diamagnetic background, which come from Ni²⁺ ions and benzene ring, respectively. However, according to the specific heat results with temperature down to 0.1 K and magnetic field up to 14 T, no expected field-induced quantum phase transition was observed in NiCl₂(dppe) single crystals.

关键词: anisotropic, paramagnetic, single crystal, ultra low temperature, specific heat

Abstract: Dichloro [1,2-bis (diphenylphosphino) ethane] nickel²⁺ (NiCl₂(dppe)) is an organic compound containing C₂₆H₂₄P₂(dppe) molecules and Cl^-, Ni²⁺ ions. The large-size NiCl₂(dppe) single crystals with longest dimension of 4 mm were grown by the method of slow evaporation of organic solution. Single crystal x-ray diffraction spectrum indicates that the single crystal is of high quality. Magnetization results of the NiCl₂(dppe) single crystals show an anisotropic paramagnetism behavior and diamagnetic background, which come from Ni²⁺ ions and benzene ring, respectively. However, according to the specific heat results with temperature down to 0.1 K and magnetic field up to 14 T, no expected field-induced quantum phase transition was observed in NiCl₂(dppe) single crystals.

Key words: anisotropic, paramagnetic, single crystal, ultra low temperature, specific heat

中图分类号: (Magnetic anisotropy)

75.30.Gw

78.30.Jw (Organic compounds, polymers) 65.40.Ba (Heat capacity)

Shuaiqi Ma(马帅奇), Linlin An(安琳琳), and Xiangde Zhu(朱相德). Absence of magnetic order in dichloro [1,2-bis (diphenylphosphino) ethane] nickel^{2 +} single crystal[J]. 中国物理B, 2021, 30(5): 57501-057501.

Shuaiqi Ma(马帅奇), Linlin An(安琳琳), and Xiangde Zhu(朱相德). Absence of magnetic order in dichloro [1,2-bis (diphenylphosphino) ethane] nickel^{2 +} single crystal[J]. Chin. Phys. B, 2021, 30(5): 57501-057501.

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Absence of magnetic order in dichloro [1,2-bis (diphenylphosphino) ethane] nickel^{2 +} single crystal

Absence of magnetic order in dichloro [1,2-bis (diphenylphosphino) ethane] nickel^{2 +} single crystal

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