Hydrothermal synthesis and characterization of carbon-doped TiO2 nanoparticles

doi:10.1088/1674-1056/ab9f29

中国物理B ›› 2020, Vol. 29 ›› Issue (11): 118102-.doi: 10.1088/1674-1056/ab9f29

Zafar Ali¹, Javaid Ismail¹, Rafaqat Hussain², A. Shah³, Arshad Mahmood³, Arbab Mohammad Toufiq⁴, Shams ur Rahman¹^,†()

收稿日期:2020-04-17 修回日期:2020-06-03 接受日期:2020-06-23 出版日期:2020-11-05 发布日期:2020-11-03

Hydrothermal synthesis and characterization of carbon-doped TiO₂ nanoparticles

Zafar Ali¹, Javaid Ismail¹, Rafaqat Hussain², A. Shah³, Arshad Mahmood³, Arbab Mohammad Toufiq⁴, and Shams ur Rahman^{1, †}

1 Department of Physics, COMSATS University Islamabad, Park Road, Islamabad 45550, Pakistan
2 Department of Chemistry, COMSATS University Islamabad, Park Road, Islamabad 45550, Pakistan
3 National Institute of Lasers and Optronics College, Pakistan Institute of Engineering and Applied Sciences (NILOP-C, PIEAS), Nilore 45650, Islamabad, Pakistan
4 Department of Physics, Hazara University Mansehra, Mansehra 21300, Pakistan

Received:2020-04-17 Revised:2020-06-03 Accepted:2020-06-23 Online:2020-11-05 Published:2020-11-03
Contact: ^†Corresponding author. E-mail: vitto.han@gmail.com
Supported by:
The authors would like to thank the Higher Education Commission of Pakistan for providing funding (NRPU project 5349/Federal/NRPU/R&D/HEC/2016).

摘要/Abstract

Abstract:

We report the hydrothermal growth of pure and doped TiO₂ nanoparticles with different concentrations of carbon. The microstructure of the as-synthesized samples is characterized by x-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy dispersive x-ray spectroscopy (EDX), and Raman spectroscopy to understand the structure and composition. The XRD patterns confirm the formation of anatase phase of TiO₂ with the average crystallite size is calculated to be in the range of 13 nm to 14.7 nm. The functional groups of these nanostructures are characterized by Fourier transformed infrared (FT-IR) spectroscopy, which further confirms the single anatase phase of the synthesized nanostructures. UV-visible absorption spectroscopy is used to understand the absorption behavior, which shows modification in the optical bandgap from 3.13 eV (pure TiO₂) to 3.74 eV (1.2 mol% C-doped TiO₂). Furthermore, the Ti³⁺ centers associated with oxygen vacancies are identified using electron paramagnetic resonance spectroscopy (EPR).

Key words: titanium dioxide, hydrothermal synthesis, defect states, bandgap

Zafar Ali, Javaid Ismail, Rafaqat Hussain, A. Shah, Arshad Mahmood, Arbab Mohammad Toufiq, Shams ur Rahman. [J]. 中国物理B, 2020, 29(11): 118102-.

Zafar Ali, Javaid Ismail, Rafaqat Hussain, A. Shah, Arshad Mahmood, Arbab Mohammad Toufiq, and Shams ur Rahman. Hydrothermal synthesis and characterization of carbon-doped TiO₂ nanoparticles[J]. Chin. Phys. B, 2020, 29(11): 118102-.

图/表 8

参考文献 52

[1]	Khan A, Toufiq A M, Tariq F, Khan Y, Hussain R, Akhtar N, Rahman S U 2019 Mater. Res. Express. 6 065043 DOI: 10.1088/2053-1591/ab0aaf
[2]	Wu Z, Yang S, Wu W 2016 Nanoscale 8 1237 DOI: 10.1039/C5NR07681A
[3]	Zhang G, Xiao X, Li B, Gu P, Xue H, Pang H 2017 J. Mater. Chem. A 5 8155 DOI: 10.1039/C7TA02454A
[4]	Pandey S C, Xu X, Williamson I, Nelson E B, Li L 2017 Chem. Phys. Lett. 669 1 DOI: 10.1016/j.cplett.2016.12.005
[5]	Vardi N, Anouchi E, Yamin T, Middey S, Kareev M, Chakhalian J, Dubi Y, Sharoni A 2017 Adv. Mater. 29 1605029 DOI: 10.1002/adma.201605029
[6]	Hong F, Yue B, Hirao N, Liu Z, Chen B 2017 Sci. Rep. 7 44078 DOI: 10.1038/srep44078
[7]	Yin Z, Tordjman M, Lee Y, Vardi A, Kalish R, del Alamo J A 2018 Sci. Adv. 4 eaau0480 DOI: 10.1126/sciadv.aau0480
[8]	Ye K, Li K, Lu Y, Guo Z, Ni N, Liu H, Huang Y, Ji H, Wang P 2019 Trends Analyt Chem. 116 102 DOI: 10.1016/j.trac.2019.05.002
[9]	Ye K, Li Y, Yang H, Li M, Huang Y, Zhang S, Ji H 2019 Appl. Catal. B 259 118085 DOI: 10.1016/j.apcatb.2019.118085
[10]	Ye K H, Wang Z, Li H, Yuan Y, Huang Y, Mai W 2018 Sci. China Mater. 61 887 DOI: 10.1007/s40843-017-9199-5
[11]	Huang Y, Guo Z, Liu H, Zhang S, Wang P, Lu J, Tong Y 2019 Adv. Funct. Mater. 29 1903490 DOI: 10.1002/adfm.v29.45
[12]	Rahman M, Krishna K, Soga T, Jimbo T, Umeno M 1999 J. Phys. Chem. Solids 60 201 DOI: 10.1016/S0022-3697(98)00264-9
[13]	Beltran A, Gracia L, Andres J 2006 J. Phys. Chem. B 110 23417 DOI: 10.1021/jp0643000
[14]	Smith S J, Stevens R, Liu S, Li G, Navrotsky A, Boerio-Goates J, Woodfield B F 2009 Am. Mineral. 94 236 DOI: 10.2138/am.2009.3050
[15]	Zallen R, Moret M 2006 Solid State Commun. 137 154 DOI: 10.1016/j.ssc.2005.10.024
[16]	Djarri A, Achour A, Soussou M A, Sobti N, Achour S 2018 Mater. Charact. 135 139 DOI: 10.1016/j.matchar.2017.10.008
[17]	Barnard A, Curtiss L 2005 Nano Lett. 5 1261 DOI: 10.1021/nl050355m
[18]	Wu T, Kong W, Zhang Y, Xing Z, Zhao J, Wang T, Shi X, Luo Y, Sun X 2019 small Methods 3 1900356 DOI: 10.1002/smtd.v3.11
[19]	Wu T, Zhu X, Xing Z, Mou S, Li C, Qiao Y, Liu Q, Luo Y, Shi X, Zhang Y, Sun X 2019 Angew. Chem. Int. Ed. 58 18449 DOI: 10.1002/anie.v58.51
[20]	Li B, Zhu X, Wang J, Xing R, Liu Q, Shi X, Luo Y, Liu S, Niu X, Sun X 2020 Chem. Comm. 56 1074 DOI: 10.1039/C9CC08971C
[21]	Hiroshi I, Yuka W, Kazuhito H 2003 Chem. Lett. 32 772 DOI: 10.1246/cl.2003.772
[22]	Wang J, Tafen D N, Lewis J P, Hong Z, Manivannan A, Zhi M, Li M, Wu N 2009 J. Am. Chem. Soc. 131 12290 DOI: 10.1021/ja903781h
[23]	Yan X, Yuan K, Lu N, Xu H, Zhang S, Takeuchi N, Kobayashi H, Li R 2017 Appl. Catal. B 218 20 DOI: 10.1016/j.apcatb.2017.06.022
[24]	Nyamukamba P, Tichagwa L, Greyling C 2012 Mater. Sci. Forum 712 49 DOI: 10.4028/www.scientific.net/MSF.712
[25]	Umebayashi T, Yamaki T, Itoh H, Asai K 2002 Appl. Phys. Lett. 81 454 DOI: 10.1063/1.1493647
[26]	Ren W, Ai Z, Jia F, Zhang L, Fan X, Zou Z 2007 Appl. Catal. B 69 138 DOI: 10.1016/j.apcatb.2006.06.015
[27]	Ali M, Hussain R, Tariq F, Noreen Z, Toufiq A M, Bokhari H, Akhtar N, ur Rahman S 2020 Appl. Nanosci. 10 1005 DOI: 10.1007/s13204-019-01193-0
[28]	Shao J, Sheng W, Wang M, Li S, Chen J, Zhang Y, Cao S 2017 Appl. Catal. B 209 311 DOI: 10.1016/j.apcatb.2017.03.008
[29]	Noorimotlagh Z, Kazeminezhad I, Jaafarzadeh N, Ahmadi M, Ramezani Z, Martinez S S 2018 J. Hazard. Mater. 350 108 DOI: 10.1016/j.jhazmat.2018.02.022
[30]	Al-Degs Y S, El-Barghouthi M I, El-Sheikh A H, Walker G M 2008 Dyes Pigm. 77 16 DOI: 10.1016/j.dyepig.2007.03.001
[31]	Yang G, Jiang Z, Shi H, Xiao T, Yan Z 2010 J. Mater. Chem. 20 5301 DOI: 10.1039/C0JM00376J
[32]	Abdullah A M, Al-Thani N J, Tawbi K, Al-Kandari H 2016 Arab. J. Chem. 9 229 DOI: 10.1016/j.arabjc.2015.04.027
[33]	Sim L C, Leong K H, Ibrahim S, Saravanan P 2014 J. Mater. Chem. A 2 5315 DOI: 10.1039/C3TA14857B
[34]	Attar A S, Ghamsari M S, Hajiesmaeilbaigi F, Mirdamadi S 2008 J. Mater. Sci. 43 1723 DOI: 10.1007/s10853-007-2244-z
[35]	Toufiq A M, Wang F, Li Q, Li Y 2014 Appl. Phys. A 116 1127 DOI: 10.1007/s00339-013-8195-0
[36]	Shaban M, Ashraf A M, Abukhadra M R 2018 Sci. Rep. 8 781 DOI: 10.1038/s41598-018-19172-w
[37]	Ratova M, Klaysri R, Praserthdam P, Kelly P J 2018 Vacuum 149 214 DOI: 10.1016/j.vacuum.2018.01.003
[38]	Lin H, Huang C, Li W, Ni C, Shah S I, Tseng Y H 2006 Appl. Catal. B 68 1 DOI: 10.1016/j.apcatb.2006.07.018
[39]	Brus L E 1984 J. Chem. Phys. 80 4403 DOI: 10.1063/1.447218
[40]	Rino J-P, Studart N 1999 Phys. Rev. B 59 6643 DOI: 10.1103/PhysRevB.59.6643
[41]	Bhange P, Awate S, Gholap R, Gokavi G, Bhange D 2016 Mater. Res. Bull. 76 264 DOI: 10.1016/j.materresbull.2015.12.041
[42]	Linsebigler A L, Lu G, Yates J T Jr 1995 Chem. Rev. 95 735 DOI: 10.1021/cr00035a013
[43]	Lu X H, Huang X, Xie S L, Zheng D Z, Liu Z Q, Liang C L, Tong Y X 2010 Langmuir 26 7569 DOI: 10.1021/la904882t
[44]	Pham C V, Krueger M, Eck M, Weber S, Erdem E 2014 Appl. Phys. Lett. 104 132102 DOI: 10.1063/1.4870297
[45]	Lund A, Shiotani M, Shimada S 2011 Principles and applications of ESR spectroscopy New York Springer 91
[46]	Zhou S, Čižmár E, Potzger K, Krause M, Talut G, Helm M, Fassbender J, Zvyagin S, Wosnitza J, Schmidt H 2009 Phys. Rev. B 79 113201 DOI: 10.1103/PhysRevB.79.113201
[47]	Hurum D C, Gray K A, Rajh T, Thurnauer M C 2005 J. Phys. Chem. B 109 977 DOI: 10.1021/jp045395d
[48]	Ogale S B 2010 Adv. Mater. 22 3125 DOI: 10.1002/adma.200903891
[49]	Tian Y, Bakaul S R, Wu T 2012 Nanoscale 4 1529 DOI: 10.1039/c2nr11767c
[50]	Peng H, Li J, Li S S, Xia J B 2009 Phys. Rev. B 79 092411 DOI: 10.1103/PhysRevB.79.092411
[51]	Yoon S D, Chen Y, Yang A, Goodrich T L, Zuo X, Arena D A, Ziemer K, Vittoria C, Harris V G 2006 J. Phys.: Condens. Matter 18 L355 DOI: 10.1088/0953-8984/18/27/L01
[52]	Hong N H, Sakai J, Poirot N, Brizé V 2006 Phys. Rev. B 73 132404 DOI: 10.1103/PhysRevB.73.132404

Doping concentration of glucose/mol%	Absorption wavelength/nm	Bandgap/eV
0.00	396	3.13
0.20	350	3.54
0.60	339	3.66
1.20	332	3.74

Hydrothermal synthesis and characterization of carbon-doped TiO₂ nanoparticles

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

图/表 8

参考文献 52

相关文章 0

Metrics

本文评价

推荐阅读 0