Structural and dielectric properties of giant dielectric Na1/2Sm1/2Cu3Ti4O12 ceramics prepared by reactive sintering methods

doi:10.1088/1674-1056/ab37f1

摘要/Abstract

摘要：

Na_0.5Sm_0.5Cu₃Ti₄O₁₂ (NSCTO) ceramics have been prepared by reactive sintering of amorphous powder. Spark plasma sintering (SPS) for 10 min at 1025℃ and conventional sintering (CS) for 10 h at 1090℃ have been employed. X-ray diffraction measurements confirmed the pure CCTO-like phase for SPS and CS NSCTO ceramics. The SPS ceramic showed an average grain size of 500 nm, which is much smaller than that of the CS (~5 μm) sample. The impedance spectroscopy measurements revealed an electrically inhomogeneous structure in the prepared ceramics. While the resistivities of grains of both ceramic samples were in the same order of magnitude, the resistivity of grain-boundaries of the CS ceramic was three orders of magnitude greater than that of the SPS ceramic. Both of the samples showed giant dielectric constant (>10³) over wide ranges of temperatures and frequencies. Nevertheless, the room-temperature dielectric loss of the SPS NSCTO (3.2 at 1.1 kHz) ceramic sample was higher than that of the CS NSCTO (0.08 at 1.1 kHz) ceramic sample due to the reduced grain-boundary resistivity of the former. Two dielectric relaxations were detected for each sample and attributed to the relaxations in grains and grain-boundaries. The dielectric behavior of the SPS and CS NSCTO ceramics could be interpreted in terms of the internal barrier layer capacitor (IBLC) model.

关键词: ceramics, sintering, dielectric loss and relaxation

Abstract:

Key words: ceramics, sintering, dielectric loss and relaxation

中图分类号: (Ceramics in electrochemistry)

82.45.Xy

81.20.Ev (Powder processing: powder metallurgy, compaction, sintering, mechanical alloying, and granulation) 77.22.Gm (Dielectric loss and relaxation) 84.37.+q (Measurements in electric variables (including voltage, current, resistance, capacitance, inductance, impedance, and admittance, etc.))

H Mahfoz Kotb. Structural and dielectric properties of giant dielectric Na_1/2Sm_1/2Cu₃Ti₄O₁₂ ceramics prepared by reactive sintering methods[J]. 中国物理B, 2019, 28(9): 98202-098202.

H Mahfoz Kotb. Structural and dielectric properties of giant dielectric Na_1/2Sm_1/2Cu₃Ti₄O₁₂ ceramics prepared by reactive sintering methods[J]. Chin. Phys. B, 2019, 28(9): 98202-098202.

参考文献 42

[40]	Ni L, Fu M, Liu Y, Tang T, Wang S, Zou B and Zhao S 2016 J. Mater. Sci.:Mater. Electron. 27 111
[1]	Krohns S, Lunkenheimer P, Meissner S, Reller A, Gleich B, Rathgeber A, Gaugler T, Buhl H U, Sinclair D C and Loidl A 2011 Nat Mater. 10 899 doi: 10.1038/nmat3180
[41]	Sun X, Wang C, Wang G, Lei C, Li T, Liu L and Feteira A 2013 J. Am. Ceram. Soc. 96 1497 doi: 10.1111/jace.12208
[2]	Subramanian M A, Li D, Duan N, Reisner B A and Sleight A W 2000 J. Solid State Chem. 151 323 doi: 10.1006/jssc.2000.8703
[42]	Yang L, Chao X, Wei L, Zhao N and Yang Z 2016 J. Mater. Sci.:Mater. Electron. 27 2221 doi: 10.1007/s10854-015-4014-z
[3]	Zhao N, Liang P, Wei L, Yang L and Yang Z 2015 Ceram. Int. 41 8501 doi: 10.1016/j.ceramint.2015.03.057
[4]	Sebald J, Krohns S, Lunkenheimer P, Ebbinghaus S G, Riegg S, Reller A and Loidl A 2010 Solid State Commun. 150 857 doi: 10.1016/j.ssc.2010.02.006
[5]	Ahmad M M and Mahfoz Kotb H 2015 J. Mater. Sci.:Mater. Electron. 26 8939 doi: 10.1007/s10854-015-3576-0
[6]	Su Y and Wang Y 2016 Appl. Phys. A 122 249
[7]	Thongbai P, Yamwong T and Maensiri S 2012 Mater. Res. Bull. 47 432 doi: 10.1016/j.materresbull.2011.10.027
[8]	Mahfoz Kotb H and Ahmad M M 2016 Chin. Phys. B 25 128201 doi: 10.1088/1674-1056/25/12/128201
[9]	Somphan W, Thongbai P, Yamwong T and Maensiri S 2013 Mater. Res. Bull. 48 4087 doi: 10.1016/j.materresbull.2013.06.028
[10]	Li Y, Liang P, Chao X and Yang Z 2013 Ceram. Int. 39 7879 doi: 10.1016/j.ceramint.2013.03.049
[11]	Zheng Q and Fan H 2012 J. Mater. Sci. & Technol. 28 920 doi: ter. Sci.
[12]	Kim B K, Lee H S, Lee J W, Lee S E and Cho Y S 2010 J. Am. Ceram. Soc. 93 2419 doi: 10.1111/j.1551-2916.2010.03738.x
[13]	Swatsitang E, Niyompan A and Putjuso T 2013 J. Mater. Sci.:Mater. Electron. 24 3514 doi: 10.1007/s10854-013-1278-z
[14]	Huang X, Jiang Y and Wu K 2015 Procedia Eng. 102 468 doi: 10.1016/j.proeng.2015.01.191
[15]	Jumpatam J, Putasaeng B, Chanlek N, Kidkhunthod P, Thongbai P, Maensiri S and Chindaprasirt P 2017 RSC Adv. 7 4092 doi: 10.1039/C6RA27381E
[16]	Cortés J A, Cotrim G, Orrego S, Simões A Z and Ramírez M A 2018 J. Alloys Compd. 735 140 doi: 10.1016/j.jallcom.2017.11.089
[17]	De Almeida-Didry S, Nomel M M, Autret C, Honstettre C, Lucas A, Pacreau F and Gervais F 2018 J. Eur. Ceram. Soc. 38 3182 doi: 10.1016/j.jeurceramsoc.2018.03.003
[18]	Lopera A, Ramirez M A, García C, Paucar C and Marín J 2014 Inorg. Chem. Commun. 40 5 doi: 10.1016/j.inoche.2013.11.025
[19]	Thomazini D, Gelfuso M V, Volpi G M S and Eiras J A 2015 Int. J. Appl. Ceram. Technol. 12 E73
[20]	Lin H, He X, Gong Y, Pang D and Yi Z 2018 Ceram. Int. 44 8650 doi: 10.1016/j.ceramint.2018.02.089
[21]	Kumar R, Zulfequar M and Senguttuvan T D 2016 J. Mater. Sci.:Mater. Electron. 27 5233 doi: 10.1007/s10854-016-4418-4
[22]	Ahmad M M and Yamada K 2014 J. Appl. Phys. 115 154103 doi: 10.1063/1.4871979
[23]	Hao W, Xu P, Wang M, Yang S, Yupeng W, Wu H, Sun L, Cao E and Zhang Y 2018 J. Alloys Compd. 740 1159 doi: 10.1016/j.jallcom.2018.01.080
[24]	Li M, Shen Z, Nygren M, Feteira A, Sinclair D C and West A R 2009 J. Appl. Phys. 106 104106 doi: 10.1063/1.3253743
[25]	Li M, Sinclair D C and West A R 2011 J. Appl. Phys. 109 084106 doi: 10.1063/1.3572256
[26]	Barsoukov E and Macdonald J R 2005 Impedance spectroscopy:theory, experiment, and applications (New York:John Wiley & Sons) doi: ance spectroscopy:theory, experiment, and applications ???New York:John Wiley\|\|
[27]	Wu J, Qi T, Li T T, Qin Q W, Li G Q, Zhu B L, Xiang Z D and Xie C S 2012 J. Mater. Sci.:Mater. Electron. 23 1143 doi: 10.1007/s10854-011-0562-z
[28]	Abram E, Sinclair D and West A 2003 J. Electroceram. 10 165 doi: 10.1023/B:JECR.0000011215.56084.87
[29]	Dubey A K, Singh P, Singh S, Kumar D and Parkash O 2011 J. Alloys Compd. 509 3899 doi: 10.1016/j.jallcom.2010.12.156
[30]	Yuan W X 2012 Solid State Sci. 14 330 doi: 10.1016/j.solidstatesciences.2011.11.035
[31]	Liang P, Li Y, Zhao Y, Wei L and Yang Z 2013 J. Appl. Phys. 113 224102 doi: 10.1063/1.4809927
[32]	Costa S I R, Li M, Frade J R and Sinclair D C 2013 RSC Adv. 3 7030 doi: 10.1039/c3ra40216a
[33]	Schmidt R, Pandey S, Fiorenza P and Sinclair D C 2013 RSC Adv. 3 14580 doi: 10.1039/c3ra41319e
[34]	Ahmad M M 2013 Appl. Phys. Lett. 102 232908 doi: 10.1063/1.4811154
[35]	Jonscher A K 1977 Nature 267 673 doi: 10.1038/267673a0
[36]	Cortés J A, Cotrim G, Orrego S, Simões A Z and Ramírez M A 2018 J. Alloys Compd. 735 140 doi: 10.1016/j.jallcom.2017.11.089
[37]	Pradhan D K, Misra P, Puli V S, Sahoo S, Pradhan D K and Katiyar R S 2014 J. Appl. Phys. 115 243904 doi: 10.1063/1.4885420
[38]	Sinclair D C and West A R 1989 J. Appl. Phys. 66 3850 doi: 10.1063/1.344049
[39]	Wang C, Ni W, Zhang D, Sun X, Wang J, Li H and Zhang N 2016 J. Electroceram. 36 46 doi: 10.1007/s10832-016-0024-3
[40]	Ni L, Fu M, Liu Y, Tang T, Wang S, Zou B and Zhao S 2016 J. Mater. Sci.:Mater. Electron. 27 111
[41]	Sun X, Wang C, Wang G, Lei C, Li T, Liu L and Feteira A 2013 J. Am. Ceram. Soc. 96 1497 doi: 10.1111/jace.12208
[42]	Yang L, Chao X, Wei L, Zhao N and Yang Z 2016 J. Mater. Sci.:Mater. Electron. 27 2221 doi: 10.1007/s10854-015-4014-z

Structural and dielectric properties of giant dielectric Na_1/2Sm_1/2Cu₃Ti₄O₁₂ ceramics prepared by reactive sintering methods

Structural and dielectric properties of giant dielectric Na_1/2Sm_1/2Cu₃Ti₄O₁₂ ceramics prepared by reactive sintering methods

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 42

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Xiao-Qin Liu(刘晓琴), Qian-Qian Hao(郝倩倩), Jie Liu(刘杰), Dan-Hua Liu(刘丹华), Wei-Wei Li(李威威), and Liang-Bi Su(苏良碧). Yb:CaF₂–YF₃ transparent ceramics ultrafast laser at dual gain lines[J]. 中国物理B, 2022, 31(11): 114205-114205.
[2]	Ke-Lun Xia(夏克伦), Guang Jia(贾光), Hao-Tian Gan(甘浩天), Yi-Ming Gui(桂一鸣), Xu-Sheng Zhang(张徐生), Zi-Jun Liu(刘自军), and Xiang Shen(沈祥). Ultrabroadband mid-infrared emission from Cr²⁺:ZnSe-doped chalcogenide glasses prepared via hot uniaxial pressing and melt-quenching[J]. 中国物理B, 2021, 30(9): 94208-094208.
[3]	王聪, 郝倩倩, 李威威, 黄海军, 王绍钊, 姜大朋, 刘杰, 梅炳初, 苏良碧. 575-fs passively mode-locked Yb:CaF₂ ceramic laser[J]. 中国物理B, 2020, 29(7): 74205-074205.
[4]	杨晓亮, 陈龙庆, 邱文彬, 宋阳一鹏, 唐毅, 崔旭东, 刘长松, 蒋燕, 张涛, 唐军. Irradiation hardening behaviors of tungsten-potassium alloy studied by accelerated 3-MeV W²⁺ ions[J]. 中国物理B, 2020, 29(4): 46102-046102.
[5]	郑巧瑜, 李杨, 吴文娟, 石明明, 杨波波, 邹军. Effect of sintering temperature on luminescence properties of borosilicate matrix blue-green emitting color conversion glass ceramics[J]. 中国物理B, 2019, 28(10): 108102-108102.
[6]	赵利敏, 程永光, 郝好山, 王娇, 刘少辉, 张宝森. Properties of negative thermal expansion β-eucryptite ceramics prepared by spark plasma sintering[J]. 中国物理B, 2018, 27(9): 96501-096501.
[7]	杨鸣, 寇自力, 刘腾, 卢景瑞, 刘方明, 刘银娟, 戚磊, 丁未, 龚红霞, 倪小林, 贺端威. Polycrystalline cubic boron nitride prepared with cubic-hexagonal boron nitride under high pressure and high temperature[J]. 中国物理B, 2018, 27(5): 56105-056105.
[8]	李亚男, 吴平, 张师平, 陈森, 闫丹, 杨金光, 王立, 淮秀兰. Thermoelectric properties of lower concentration K-doped Ca₃Co₄O₉ ceramics[J]. 中国物理B, 2018, 27(5): 57201-057201.
[9]	刘达权, 张玉伟, 康慧君, 李金玲, 杨雄, 王同敏. Effect of Nb doping on microstructures and thermoelectric properties of SrTiO₃ ceramics[J]. 中国物理B, 2018, 27(4): 47205-047205.
[10]	汪婷婷, 刘桂武, 黄志坤, 张相召, 徐紫巍, 乔冠军. Wettability of Si and Al-12Si alloy on Pd-implanted 6H-SiC[J]. 中国物理B, 2018, 27(4): 46101-046101.
[11]	陈勇, 薛思敏, 骆迁, 苏虎音, 陈琪, 黄镇, 徐玲芳, 曹万强, 黄兆祥. Study on the dielectric properties of Mg-doped NaBiTi₆O₁₄ ceramics[J]. 中国物理B, 2017, 26(4): 47701-047701.
[12]	徐玉青, 汪尧进, 王一平, 杨颖, 袁国亮. CuO added Pb_0.92Sr_0.06Ba_0.02(Mg_1/3Nb_2/3)_0.25(Ti_0.53Zr_0.47)_0.75O₃ ceramics sintered with Ag electrodes at 900℃ for multilayer piezoelectric actuator[J]. 中国物理B, 2017, 26(3): 37702-037702.
[13]	胡吉英, 李朝晖, 李启虎. Singular variation property of elastic constants of piezoelectric ceramics shunted to negative capacitance[J]. 中国物理B, 2017, 26(12): 127702-127702.
[14]	金慧, 李勇, 宋谋胜, 陈琳, 贾晓鹏, 马红安. Ceramic synthesis of 0.08BiGaO₃-0.90BaTiO₃-0.02LiNbO₃ under high pressure and high temperature[J]. 中国物理B, 2016, 25(7): 78202-078202.
[15]	熊青云, 沈启霞, 李蕊子, 申江, 田付阳. First-principle investigation on the thermodynamics of X₂N₂O (X= C, Si, Ge) compounds[J]. 中国物理B, 2016, 25(2): 26501-026501.