Shock temperature and reflectivity of precompressed H2O up to 350 GPa:Approaching the interior of planets

doi:10.1088/1674-1056/27/12/126202

中国物理B ›› 2018, Vol. 27 ›› Issue (12): 126202-126202.doi: 10.1088/1674-1056/27/12/126202

• CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES • 上一篇下一篇

Shock temperature and reflectivity of precompressed H₂O up to 350 GPa:Approaching the interior of planets

1 Shanghai Institute of Laser Plasma, CAEP, P. O. Box 800-229, Shanghai 201800, China;
2 IFSA Collaborative Innovation Center, Shanghai Jiaotong University, Shanghai 200240, China;
3 Institute of Applied Physics and Computational Mathematics, Beijing 100088, China;
4 Center for High Pressure Science and Technology Advance Research, Beijing 100094, China

收稿日期:2018-07-23 修回日期:2018-09-20 出版日期:2018-12-05 发布日期:2018-12-05
通讯作者: Fan Zhang E-mail:innocentman001@163.com
基金资助:
Project supported by the National Key Research and Development Program of China (Grant No. 2017YFA0403200) and the Science Challenge Project (Grant No. TZ2016001).

Shock temperature and reflectivity of precompressed H₂O up to 350 GPa:Approaching the interior of planets

Zhi-Yu He(贺芝宇)¹, Hua Shu(舒桦)¹, Xiu-Guang Huang(黄秀光)^1,2, Qi-Li Zhang(张其黎)³, Guo Jia(贾果)¹, Fan Zhang(张帆)¹, Yu-Chun Tu(涂昱淳)¹, Jun-Yue Wang(王寯越)⁴, Jun-Jian Ye(叶君建)¹, Zhi-Yong Xie(谢志勇)¹, Zhi-Heng Fang(方智恒)¹, Wen-Bing Pei(裴文兵)^1,2, Si-Zu Fu(傅思祖)^1,2

1 Shanghai Institute of Laser Plasma, CAEP, P. O. Box 800-229, Shanghai 201800, China;
2 IFSA Collaborative Innovation Center, Shanghai Jiaotong University, Shanghai 200240, China;
3 Institute of Applied Physics and Computational Mathematics, Beijing 100088, China;
4 Center for High Pressure Science and Technology Advance Research, Beijing 100094, China

Received:2018-07-23 Revised:2018-09-20 Online:2018-12-05 Published:2018-12-05
Contact: Fan Zhang E-mail:innocentman001@163.com
Supported by:
Project supported by the National Key Research and Development Program of China (Grant No. 2017YFA0403200) and the Science Challenge Project (Grant No. TZ2016001).

摘要/Abstract

摘要：

Using a combination of static precompression and laser-driven shock compression, shock temperature and reflectivity of H₂O have been measured up to 350 GPa and 2.1×10⁴ K. Here, two calibration standards were applied to enhance temperature measurement reliability. Additionally, in temperature calculations, the discrepancy in reflectivity between active probe beam wavelength and self-emission wavelength has been taken into account to improve the data's precision. Precompressed water's temperature-pressure data are in very good agreement with our quantum molecular dynamics model, suggesting a superionic conductor of H₂O in the icy planets' deep interior. A sluggish slope gradually approaching Dulong-Petit limit at high temperature was found at a specific heat capacity. Also, high reflectivity and conductivity were observed at the same state. By analyzing the temperature-pressure diagram, reflectivity, conductivity and specific heat comprehensively at conditions simulating the interior of planets in this work, we found that as the pressure rises, a change in ionization appears; it is supposedly attributed to energetics of bond-breaking in the H₂O as it transforms from a bonded molecular fluid to an ionic state. Such molecular dissociation in H₂O is associated with the conducting transition because the dissociated hydrogen atoms contribute to electrical properties.

关键词: high temperature measurement, equation of state of water, laser-driven shock, diamond anvil cell

Abstract:

Key words: high temperature measurement, equation of state of water, laser-driven shock, diamond anvil cell

中图分类号: (High-pressure effects in solids and liquids)

62.50.-p

51.30.+i (Thermodynamic properties, equations of state) 64.30.-t (Equations of state of specific substances) 52.25.Kn (Thermodynamics of plasmas)

贺芝宇, 舒桦, 黄秀光, 张其黎, 贾果, 张帆, 涂昱淳, 王寯越, 叶君建, 谢志勇, 方智恒, 裴文兵, 傅思祖. Shock temperature and reflectivity of precompressed H₂O up to 350 GPa:Approaching the interior of planets[J]. 中国物理B, 2018, 27(12): 126202-126202.

Zhi-Yu He(贺芝宇), Hua Shu(舒桦), Xiu-Guang Huang(黄秀光), Qi-Li Zhang(张其黎), Guo Jia(贾果), Fan Zhang(张帆), Yu-Chun Tu(涂昱淳), Jun-Yue Wang(王寯越), Jun-Jian Ye(叶君建), Zhi-Yong Xie(谢志勇), Zhi-Heng Fang(方智恒), Wen-Bing Pei(裴文兵), Si-Zu Fu(傅思祖). Shock temperature and reflectivity of precompressed H₂O up to 350 GPa:Approaching the interior of planets[J]. Chin. Phys. B, 2018, 27(12): 126202-126202.

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Shock temperature and reflectivity of precompressed H₂O up to 350 GPa:Approaching the interior of planets

Shock temperature and reflectivity of precompressed H₂O up to 350 GPa:Approaching the interior of planets

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