Temperature-dependent Raman spectroscopic study of ferroelastic K2Sr(MoO4)

doi:10.1088/1674-1056/27/11/117801

中国物理B ›› 2018, Vol. 27 ›› Issue (11): 117801-117801.doi: 10.1088/1674-1056/27/11/117801

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Temperature-dependent Raman spectroscopic study of ferroelastic K₂Sr(MoO₄)

Ji Zhang(张季), De-Ming Zhang(张德明), Ran-Ran Zhang(张冉冉)

1 An Hui Xin Hua University, Hefei 230088, China;
2 Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China;
3 High Magnetic Field Laboratory of the Chinese Academy of Sciences, Hefei 230031, China

收稿日期:2018-07-02 修回日期:2018-08-09 出版日期:2018-11-05 发布日期:2018-11-05
通讯作者: Ji Zhang E-mail:18956063545@189.cn
基金资助:
Project supported by the Natural Science Foundation of Anhui Province, China (Grant Nos. KJ2018A0588 and KJ2017A625).

Temperature-dependent Raman spectroscopic study of ferroelastic K₂Sr(MoO₄)

Ji Zhang(张季)¹, De-Ming Zhang(张德明)², Ran-Ran Zhang(张冉冉)³

1 An Hui Xin Hua University, Hefei 230088, China;
2 Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China;
3 High Magnetic Field Laboratory of the Chinese Academy of Sciences, Hefei 230031, China

Received:2018-07-02 Revised:2018-08-09 Online:2018-11-05 Published:2018-11-05
Contact: Ji Zhang E-mail:18956063545@189.cn
Supported by:
Project supported by the Natural Science Foundation of Anhui Province, China (Grant Nos. KJ2018A0588 and KJ2017A625).

摘要/Abstract

摘要：

Raman scattering measurements of K₂Sr(MoO₄)₂ were performed in the temperature range of 25-750℃. The Raman spectrum of the low-temperature phase α-K₂Sr(MoO₄)₂ that was obtained by first-principle calculations indicated that the Raman bands in the wavenumber region of 250-500 cm^-1 are related to Mo-O bending vibrations in MoO₄ tetrahedra, while the Raman bands in the wavenumber region of 650-950 cm^-1 are attributed to stretching vibrations of Mo-O bonds. The temperature-dependent Raman spectra reveal that K₂Sr(MoO₄)₂ exhibits two sets of modifications in the Raman spectra at~150℃ and~475℃, attributed to structural phase transitions. The large change of the Raman spectra in the temperature range of 150℃ to 475℃ suggests structural instability of the medium-temperature phase β-K₂Sr(MoO₄)₂.

关键词: ferroelastics, K₂Sr(MoO₄)₂ crystal, Raman spectroscopy, phase transition

Abstract:

Key words: ferroelastics, K₂Sr(MoO₄)₂ crystal, Raman spectroscopy, phase transition

中图分类号: (Infrared and Raman spectra)

78.30.-j

81.70.-q (Methods of materials testing and analysis) 63.70.+h (Statistical mechanics of lattice vibrations and displacive phase transitions)

张季, 张德明, 张冉冉. Temperature-dependent Raman spectroscopic study of ferroelastic K₂Sr(MoO₄)[J]. 中国物理B, 2018, 27(11): 117801-117801.

Ji Zhang(张季), De-Ming Zhang(张德明), Ran-Ran Zhang(张冉冉). Temperature-dependent Raman spectroscopic study of ferroelastic K₂Sr(MoO₄)[J]. Chin. Phys. B, 2018, 27(11): 117801-117801.

参考文献 28

[1]	Janovec V and Přívratska J 2006 Int. Tables Crystallogr. Dch. 3 4
[2]	Efremov V A and Trunov V K 1974 Crystallogr. Rep. 19 989
[3]	Trunov V K, Efremov V A and Velikodny Yu A 1986 Crystal Chemistry and Properties of Double Molybdates and Tungstates (Leningrad:Nauka)
[4]	Dudnik E F and Kiosse G A 1983 Bull. Acad. Sci. USSR Phys. Ser. 47 420
[5]	KepplerU 1970 Z. Kristallogr. 132 228 doi: 10.1524/zkri.1970.132.1-6.228
[6]	Guimaraes D M C 1979 Acta Crystallogr. A 35 108 doi: 10.1107/S056773947900019X
[7]	Trunov V K 1971 Russ. J. Inorg. Chem. 16 553
[8]	Tsyrenova G D, Pavlova E T, Solodovnikov S F, Popova N N, Kardash T Y, Stefanovich S Y, Gudkova I A, Solodovnikova Z A and Lazoryak B I 2016 J. Solid State Chem. 237 64 doi: 10.1016/j.jssc.2016.01.011
[9]	Zhang J, Zhang D, Zhang Q and Yin S 2016 Chin. Phys. B 25 037802 doi: 10.1088/1674-1056/25/3/037802
[10]	Cerderira F, Melo F E A and Lemos V 1983 Phys. Rev. B 27 7716 doi: 10.1103/PhysRevB.27.7716
[11]	Zhang J, Zhang D, Zhang Q and Yin S 2015 Chin. Phys. B 24 017801 doi: 10.1088/1674-1056/24/1/017801
[12]	Segall M D, Lindan P J D, Probert M J, Pickard C J, Hasnip P J, Clark S J and Payne M C J 2002 J. Phys.:Condens. Matter 14 2717 doi: 10.1088/0953-8984/14/11/301
[13]	Perdew J P, Burke K and Ernzerhof M 1996 Phys. Rev. Lett. 77 3865 doi: 10.1103/PhysRevLett.77.3865
[14]	Perdew J P 1991 Electron. Struct. Solids 17 11
[15]	Perdew J P, Burke K and Wang Y 1996 Phys. Rev. B 54 16533 doi: 10.1103/PhysRevB.54.16533
[16]	Goodwin A L, Calleja M, Conterio M J, Dove M T and Evans J S O 2005 Z. Kristallogr. 220 567
[17]	Zhang G Y 2001 Lattice Vibrational Spectroscopy (Beijing:Higher Education Press)
[18]	Hanuza J and Labuda L 1981 J. Raman Sprctrosc. 11 231 doi: 10.1002/jrs.1250110404
[19]	Moiseenko V N, Bogatirjov Yu I, Jeryemenko A M and Akimov S V 2000 J. Raman Sprctrosc. 31 539 doi: 10.1002/1097-4555(200006)31:6<539::AID-JRS550>3.0.CO;2-G
[20]	Kaminsk A A, Eichler H J, Grebe D, Macdonald R, Bagaev S N, Pavlyuk A A and Kuznetsov F A 1996 Phys. Stat. Sol. 153 281 doi: 10.1002/pssa.2211530129
[21]	Kamitsos E I, Karakassides M A and Chryssikos G D 1989 Phys. Chem. Glasses 30 229
[22]	Heyns A M, Range K J and Wildenauer M 1990 Spectrochim. Acta A 46 1621 doi: 10.1016/0584-8539(90)80274-3
[23]	Brown R G, Denning J, Hallett A and Ross S D 1970 Spectrochim. Acta Part. A 26 963 doi: 10.1016/0584-8539(70)80293-8
[24]	Khanna R K and Lippincott E R 1968 Spectrochim. Acta Part. A 24 905 doi: 10.1016/0584-8539(68)80189-8
[25]	Scott J F and Porto S 1967 Phys. Rev. 157 716 doi: 10.1103/PhysRev.157.716
[26]	Nikol M and Durana F 1971 J. Chem. Phys. 54 1436 doi: 10.1063/1.1675034
[27]	Silva K P D, Coelho J S, Maczka M, Paraguassu W and Freire P T C 2013 J. Solid State Chem. 199 7 doi: 10.1016/j.jssc.2012.09.021
[28]	Morozov V A, Lazoryak B I, Lebedev O I, Amelinckx S and Tendeloo V G 2003 J. Solid State Chem. 176 76

Temperature-dependent Raman spectroscopic study of ferroelastic K₂Sr(MoO₄)

Temperature-dependent Raman spectroscopic study of ferroelastic K₂Sr(MoO₄)

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 28

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Chenjun Zhang(张晨骏), Xiaoke He(何小可), Zhiyu Min(闵志宇), and Baozhong Li(李保忠). Tailoring of thermal expansion and phase transition temperature of ZrW₂O₈ with phosphorus and enhancement of negative thermal expansion of ZrW_1.5P_0.5O_7.75[J]. 中国物理B, 2023, 32(4): 48201-048201.
[2]	Wangwei Xu(许望伟), Shijie Sun(孙诗杰), Muzi Yang(杨慕紫), Zhenliang Hao(郝振亮), Lei Gao(高蕾), Jianchen Lu(卢建臣), Jiasen Zhu(朱嘉森), Jian Chen(陈建), and Jinming Cai(蔡金明). Polarization Raman spectra of graphene nanoribbons[J]. 中国物理B, 2023, 32(4): 46803-046803.
[3]	Fuzhong Nian(年福忠) and Xia Zhang(张霞). Topological phase transition in network spreading[J]. 中国物理B, 2023, 32(3): 38901-038901.
[4]	Di Zhang(张迪), Yunrui Duan(段云瑞), Peiru Zheng(郑培儒), Yingjie Ma(马英杰), Junping Qian(钱俊平), Zhichao Li(李志超), Jian Huang(黄建), Yanyan Jiang(蒋妍彦), and Hui Li(李辉). Liquid-liquid phase transition in confined liquid titanium[J]. 中国物理B, 2023, 32(2): 26801-026801.
[5]	Long Zhou(周龙), Xu-Long Zhang(张旭龙), Yu-Ying Cao(曹玉莹), Fu Zheng(郑富), Hua Gao(高华), Hong-Fei Liu(刘红飞), and Zhi Ma(马治). Prediction of flexoelectricity in BaTiO₃ using molecular dynamics simulations[J]. 中国物理B, 2023, 32(1): 17701-017701.
[6]	Tina Raoufi, Jincheng He(何金城), Binbin Wang(王彬彬), Enke Liu(刘恩克), and Young Sun(孙阳). Magnetocaloric properties and Griffiths phase of ferrimagnetic cobaltite CaBaCo₄O₇[J]. 中国物理B, 2023, 32(1): 17504-017504.
[7]	Xia Zhao(赵霞), Sheng-Hua Mei(梅升华), Zhi Zheng(郑直), Yue Gao(高悦), Jiang-Zhi Chen(陈姜智), Yue-Gao Liu(刘月高), Jian-Guo Sun(孙建国), Yan Li(李艳), and Jian-Hui Sun(孙建辉). In situ study of calcite-III dimorphism using dynamic diamond anvil cell[J]. 中国物理B, 2022, 31(9): 96201-096201.
[8]	Wei Hu(胡伟), Wen-Wei Luo(罗文崴), Mu-Sheng Wu(吴木生), Bo Xu(徐波), and Chu-Ying Ouyang(欧阳楚英). Configurational entropy-induced phase transition in spinel LiMn₂O₄[J]. 中国物理B, 2022, 31(9): 98202-098202.
[9]	Meng Peng(彭猛), Jun-Bo Yang(杨俊波), Hao Chen(陈浩), Bo-Yuan Li(李博源), Xu-Lei Ge(葛绪雷), Xiao-Hu Yang(杨晓虎), Guo-Bo Zhang(张国博), and Yan-Yun Ma(马燕云). Radiation effects of electrons on multilayer FePS₃ studied with laser plasma accelerator[J]. 中国物理B, 2022, 31(8): 86102-086102.
[10]	Yong-Huan Wang(王永欢), Yun Zhang(张云), Yu Liu(刘瑜), Xiao Tan(谈笑), Ce Ma(马策), Yue-Chao Wang(王越超), Qiang Zhang(张强), Deng-Peng Yuan(袁登鹏), Dan Jian(简单), Jian Wu(吴健), Chao Lai(赖超), Xi-Yang Wang(王西洋), Xue-Bing Luo(罗学兵), Qiu-Yun Chen(陈秋云), Wei Feng(冯卫), Qin Liu(刘琴), Qun-Qing Hao(郝群庆), Yi Liu(刘毅), Shi-Yong Tan(谭世勇), Xie-Gang Zhu(朱燮刚), Hai-Feng Song(宋海峰), and Xin-Chun Lai(赖新春). Effect of f-c hybridization on the $\gamma\to \alpha$ phase transition of cerium studied by lanthanum doping[J]. 中国物理B, 2022, 31(8): 87102-087102.
[11]	Jianfei Chen(陈健菲), Chaohua Wu(吴超华), Jingtao Fan(樊景涛), and Gang Chen(陈刚). Characterization of topological phase of superlattices in superconducting circuits[J]. 中国物理B, 2022, 31(8): 88501-088501.
[12]	Xin Guan(关欣), Gang Chen(陈刚), Jing Pan(潘婧), and Zhi-Guo Gui(桂志国). Hard-core Hall tube in superconducting circuits[J]. 中国物理B, 2022, 31(8): 80302-080302.
[13]	Qingrong Shao(邵倾蓉), Jing Meng(孟婧), Xiaoyan Zhu(朱晓艳), Yali Xie(谢亚丽), Wenjuan Cheng(程文娟), Dongmei Jiang(蒋冬梅), Yang Xu(徐杨), Tian Shang(商恬), and Qingfeng Zhan(詹清峰). Exchange-coupling-induced fourfold magnetic anisotropy in CoFeB/FeRh bilayer grown on SrTiO₃(001)[J]. 中国物理B, 2022, 31(8): 87503-087503.
[14]	Yan-Wei Dai(代艳伟), Sheng-Hao Li(李生好), and Xi-Hao Chen(陈西浩). Universal order-parameter and quantum phase transition for two-dimensional q-state quantum Potts model[J]. 中国物理B, 2022, 31(7): 70502-070502.
[15]	Zhi-Xu Zhang(张志旭), Lu Qi(祁鲁), Wen-Xue Cui(崔文学), Shou Zhang(张寿), and Hong-Fu Wang(王洪福). Topological phase transition in cavity optomechanical system with periodical modulation[J]. 中国物理B, 2022, 31(7): 70301-070301.