Optical properties of phosphate glasses co-doped with Yb3+ and silver nanoparticles

doi:10.1088/1674-1056/23/12/124214

›› 2014, Vol. 23 ›› Issue (12): 124214-124214.doi: 10.1088/1674-1056/23/12/124214

• ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS • 上一篇下一篇

Optical properties of phosphate glasses co-doped with Yb³⁺ and silver nanoparticles

M. A. Vallejo H.^a, M. A. Martinez G.^a, A. V. Kiryanov^a, J. L. Lucio M.^b

a Centro de Investigaciones en Óptica, Loma del Bosque 115, Col. Lomas del Campestre, León 37150, Guanajuato, México;
b División de Ciencias e Ingenierías del Campus León de la Universidad de Guanajuato. Loma del Bosque 103,Col. Lomas del Campestre 37150, León Guanajuato, México

收稿日期:2014-04-24 修回日期:2014-07-01 出版日期:2014-12-15 发布日期:2014-12-15
基金资助:
Lucio M J L was financially supported by the CONACyT (Grant No. CB-2009-136186-F).

Optical properties of phosphate glasses co-doped with Yb³⁺ and silver nanoparticles

M. A. Vallejo H.^a, M. A. Martinez G.^a, A. V. Kiryanov^a, J. L. Lucio M.^b

a Centro de Investigaciones en Óptica, Loma del Bosque 115, Col. Lomas del Campestre, León 37150, Guanajuato, México;
b División de Ciencias e Ingenierías del Campus León de la Universidad de Guanajuato. Loma del Bosque 103,Col. Lomas del Campestre 37150, León Guanajuato, México

Received:2014-04-24 Revised:2014-07-01 Online:2014-12-15 Published:2014-12-15
Contact: M. A. Martinez E-mail:mamg@cio.mx
Supported by:
Lucio M J L was financially supported by the CONACyT (Grant No. CB-2009-136186-F).

摘要/Abstract

摘要： We report the fabrication and spectroscopic characterization of Yb³⁺-doped phosphate glass, also containing silver nitrate. Scanning electron microscopy (SEM) provides the evidence of the formation of silver nano-particles (SNPs), which are formed as a consequence of melting and thermal decomposition of AgNO₃. Absorption spectra of the samples in the visible-to-near-infrared spectral range reveal the presence of bands centered at 410 nm associated with the SNP-plasmon resonance, and at 976 nm due to the Yb³⁺. Under 916-nm laser-diode pumping, the effect of the SNP reflects that: i) the fluorescence in the 950-nm–1150-nm spectral range is strongly enhanced (～30 times), while the fluorescence decay time associated with the ²F_5/2→F_7/2 transition of Yb³⁺ increases 25%, and ii) the basic lasing properties (saturation pumping intensity, the emission and absorption cross sections) are substantially improved.

关键词: rare earths, phosphate glasses, silver nanoparticles

Abstract: We report the fabrication and spectroscopic characterization of Yb³⁺-doped phosphate glass, also containing silver nitrate. Scanning electron microscopy (SEM) provides the evidence of the formation of silver nano-particles (SNPs), which are formed as a consequence of melting and thermal decomposition of AgNO₃. Absorption spectra of the samples in the visible-to-near-infrared spectral range reveal the presence of bands centered at 410 nm associated with the SNP-plasmon resonance, and at 976 nm due to the Yb³⁺. Under 916-nm laser-diode pumping, the effect of the SNP reflects that: i) the fluorescence in the 950-nm–1150-nm spectral range is strongly enhanced (～30 times), while the fluorescence decay time associated with the ²F_5/2→F_7/2 transition of Yb³⁺ increases 25%, and ii) the basic lasing properties (saturation pumping intensity, the emission and absorption cross sections) are substantially improved.

Key words: rare earths, phosphate glasses, silver nanoparticles

中图分类号: (Optical materials)

42.70.-a

78.20.-e (Optical properties of bulk materials and thin films) 81.05.Kf (Glasses (including metallic glasses))

M. A. Vallejo H., M. A. Martinez G., A. V. Kiryanov, J. L. Lucio M.. Optical properties of phosphate glasses co-doped with Yb³⁺ and silver nanoparticles[J]. , 2014, 23(12): 124214-124214.

M. A. Vallejo H., M. A. Martinez G., A. V. Kiryanov, J. L. Lucio M.. Optical properties of phosphate glasses co-doped with Yb³⁺ and silver nanoparticles[J]. Chin. Phys. B, 2014, 23(12): 124214-124214.

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Optical properties of phosphate glasses co-doped with Yb³⁺ and silver nanoparticles

Optical properties of phosphate glasses co-doped with Yb³⁺ and silver nanoparticles

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