Simply synthesized TiO2 nanorods as an effective scattering layer for quantum dot sensitized solar cells

doi:10.1088/1674-1056/23/4/047302

中国物理B ›› 2014, Vol. 23 ›› Issue (4): 47302-047302.doi: 10.1088/1674-1056/23/4/047302

• CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES • 上一篇下一篇

Simply synthesized TiO₂ nanorods as an effective scattering layer for quantum dot sensitized solar cells

Mahmoud Samadpour^a, Azam Iraji zad^{b c}, Mehdi Molaei^d

a Department of Physics, Faculty of Science, K. N. Toosi University of Technology, P. O. Box 15418-49611, Tehran, Iran;
b Institute for Nanoscience and Nanotechnology, Sharif University of Technology, P. O. Box 11155-8639, Tehran, Iran;
c Department of Physics, Sharif University of Technology, P. O. Box 11155-9161, Tehran, Iran;
d Department of Physics, Faculty of Science,Vali-e-Asr University, Rafsanjan, Iran

收稿日期:2013-07-29 修回日期:2013-09-02 出版日期:2014-04-15 发布日期:2014-04-15

Simply synthesized TiO₂ nanorods as an effective scattering layer for quantum dot sensitized solar cells

Mahmoud Samadpour^a, Azam Iraji zad^{b c}, Mehdi Molaei^d

a Department of Physics, Faculty of Science, K. N. Toosi University of Technology, P. O. Box 15418-49611, Tehran, Iran;
b Institute for Nanoscience and Nanotechnology, Sharif University of Technology, P. O. Box 11155-8639, Tehran, Iran;
c Department of Physics, Sharif University of Technology, P. O. Box 11155-9161, Tehran, Iran;
d Department of Physics, Faculty of Science,Vali-e-Asr University, Rafsanjan, Iran

Received:2013-07-29 Revised:2013-09-02 Online:2014-04-15 Published:2014-04-15
Contact: Mahmoud Samadpour, Azam Iraji zad E-mail:samadpour@kntu.ac.ir;iraji@sharif.edu
About author:73.50.Pz; 73.50.Gr; 81.07.-b; 82.47.Jk

摘要/Abstract

摘要： TiO₂nanorod layers are synthesized by simple chemical oxidation of Ti substrates. Diffuse reflectance spectroscopy measurements show effective light scattering properties originating from nanorods with length scales on the order of one micron. The films are sensitized with CdSe quantum dots (QDs) by successive ionic layer adsorption and reaction (SILAR) and integrated as a photoanode in quantum dot sensitized solar cells (QDSCs). Incorporating nanorods in photoanode structures provided 4-to 8-fold enhancement in light scattering, which leads to a high power conversion efficiency, 3.03% (V_oc=497 mV, J_sc=11.32 mA/cm², FF=0.54), in optimized structures. High efficiency can be obtained just by tuning the photoanode structure without further treatments, which will make this system a promising nanostructure for efficient quantum dot sensitized solar cells.

关键词: solar cell, nanorod, quantum dot, scattering

Abstract: TiO₂nanorod layers are synthesized by simple chemical oxidation of Ti substrates. Diffuse reflectance spectroscopy measurements show effective light scattering properties originating from nanorods with length scales on the order of one micron. The films are sensitized with CdSe quantum dots (QDs) by successive ionic layer adsorption and reaction (SILAR) and integrated as a photoanode in quantum dot sensitized solar cells (QDSCs). Incorporating nanorods in photoanode structures provided 4-to 8-fold enhancement in light scattering, which leads to a high power conversion efficiency, 3.03% (V_oc=497 mV, J_sc=11.32 mA/cm², FF=0.54), in optimized structures. High efficiency can be obtained just by tuning the photoanode structure without further treatments, which will make this system a promising nanostructure for efficient quantum dot sensitized solar cells.

Key words: solar cell, nanorod, quantum dot, scattering

中图分类号: (Photoconduction and photovoltaic effects)

73.50.Pz

73.50.Gr (Charge carriers: generation, recombination, lifetime, trapping, mean free paths) 81.07.-b (Nanoscale materials and structures: fabrication and characterization) 82.47.Jk (Photoelectrochemical cells, photoelectrochromic and other hybrid electrochemical energy storage devices)

Mahmoud Samadpour, Azam Iraji zad, Mehdi Molaei. Simply synthesized TiO₂ nanorods as an effective scattering layer for quantum dot sensitized solar cells[J]. 中国物理B, 2014, 23(4): 47302-047302.

Mahmoud Samadpour, Azam Iraji zad, Mehdi Molaei. Simply synthesized TiO₂ nanorods as an effective scattering layer for quantum dot sensitized solar cells[J]. Chin. Phys. B, 2014, 23(4): 47302-047302.

参考文献 53

[1]	Bisquert J, Cahen D, Hodes G, Rühle S and Zaban A 2004 J. Phys. Chem. B 108 8106
[2]	Tao X B, Xue Z B, Jing B, Qing Z, Biao L Y, Min C W and Jun C 2008 Chin. Phys. B 17 3713
[3]	Jian L P, Kai C, Fu C Y, Gao W Z, Xin H, Bo L J, Rui H J and Li Z W 2012 Chin. Phys. B 21 118101
[4]	Hodes G 2008 J. Phys. Chem. C 112 17778
[5]	Kamat P V 2008 J. Phys. Chem. C 112 18737
[6]	Kamat P V, Tvrdy K, Baker D R and Radich J G 2010 Chem. Rev. 110 6664
[7]	Mora-Seró I and Bisquert J 2010 J. Phys. Chem. Lett. 1 3046
[8]	Mora-Seró I, Giménez S, Fabregat-Santiago F, Gómez R, Shen Q, Toyoda T and Bisquert J 2009 Accounts of Chemical Research 42 1848
[9]	O'Regan B and Grätzel M 1991 Nature 353 737
[10]	Rühle S, Shalom M and Zaban A 2010 Chem. Phys. Chem. 11 2290
[11]	Alivisatos A P 1996 Science 271 933
[12]	Yu W W, Qu L, Guo W and Peng X 2003 Chem. Mater. 15 2854
[13]	Ellingson R J, Beard M C, Johnson J C, Yu P, Micic O I, Nozik A J, Shabaev A and Efros A L 2005 Nano Lett. 5 865
[14]	Sambur J B, Novet T and Parkinson B A 2010 Science 330 63
[15]	Schaller R D and Klimov V I 2004 Phys. Rev. Lett. 92 186601
[16]	Samadpour M, Boix P P, Giménez S, Iraji Zad A, Taghavinia N, Mora-Seró I and Bisquert J 2011 J. Phys. Chem. C 115 14400
[17]	Y L Lee and Y S Lo 2009 Adv. Func. Mater. 19 604
[18]	Mora-Seró I, Giménez S, Fabregat-Santiago F, Gómez R, Shen Q, Toyoda T and Bisquert J 2009 Acc. Chem. Res. 42 1848
[19]	Shen Q, Kobayashi J, Diguna L J and Toyoda T 2008 J. Appl. Phys. 103 084304
[20]	Kongkanand A, Tvrdy K, Takechi K, Kuno M and Kamat P V 2008 J. Am. Chem. Soc. 130 4007
[21]	Santra P K and Kamat P V 2012 J. Am. Chem. Soc. 134 2508
[22]	Robel I, Subramanian V, Kuno M and Kamat P V 2006 J. Am. Chem. Soc. 128 2385
[23]	Lee H J, Chen P, Moon S J, Sauvage F, Sivula K, Bessho T, Gamelin D R, Comte P, Zakeeruddin S M, Seok S I, Grätzel M and Nazeeruddin M K 2009 Langmuir 25 7602
[24]	Lee Y L and Chang C H 2008 J. Power Sources 185 584
[25]	Li L, Yang X, Gao J, Tian H, Zhao J, Hagfeldt A and Sun L 2011 J. Am. Chem. Soc. 133 8458
[26]	Yu Z, Zhang Q, Qin D, Luo Y, Li D, Shen Q, Toyoda T and Meng Q 2010 Electrochem. Commun. 12 1776
[27]	Jovanovski V, González-Pedro V, Giménez S, Azaceta E, Cabañero G, Grande H, Tena-Zaera R, Mora-Seró I and Bisquert J 2011 J. Am. Chem. Soc. 133 20156
[28]	Yang Z, Chen C Y, Liu C W, Li C L and Chang H T 2011 Adv. Energy Mater. 1 259
[29]	Deng M, Huang S, Zhang Q, Li D, Luo Y, Shen Q, Toyoda T and Meng Q 2010 Chem. Lett. 39 1168
[30]	Tachan Z, Shalom M, Hod I, Rühle S, Tirosh S and Zaban A 2011 J. Phys. Chem. C 115 6162
[31]	Seol M, Ramasamy E, Lee J and Yong K 2011 J. Phys. Chem. C 115 22018
[32]	Fang B, Kim M, Fan S Q, Kim J H, Wilkinson D P, Ko J and Yu J S 2011 J. Mater. Chem. 21 8742
[33]	Santra P K and Kamat P V 2012 J. Am. Chem. Soc. 134 2508
[34]	Zhang Q, Guo X, Huang X, Huang S, Li D, Luo Y, Shen Q, Toyoda T and Meng Q 2011 Phys. Chem. Chem. Phys. 13 4659
[35]	González-Pedro V, Xu X, Mora-Seró I and Bisquert J 2010 ACS Nano 4 5783
[36]	Barbé J C, Arendse F, Comte P, Jirousek M, Lenzmann F, Shklover V and Grätzel M 1997 J. Am. Ceram. Soc. 80 3157
[37]	Ito S, Murakami T N, Comte P, Liska P, Grätzel C, Nazeeruddin M K and Grätzel M 2008 Thin Solid Films 516 4613
[38]	Guijarro N, Lana-Villarreal T, Shen Q, Toyoda T and Gómez R 2010 J. Phys. Chem. C 114 21928
[39]	Sudhagar P, Jung J H, Park S, Lee Y G, Sathyamoorthy R, Kang Y S and Ahn H 2009 Electrochem. Commun. 11 2220
[40]	Sudhagar P, Song T, Lee D H, Mora-Seró I, Bisquert J, Laudenslager M, Sigmund W M, Park Won Il, Paik U and Kang Y S 2011 J. Phys. Chem. Lett. 2 1984
[41]	Samadpour M, Giménez S, Iraji-Zad A, Taghavinia N and Mora-SeróI 2012 Phys. Chem. Chem. Phys. 14 522
[42]	Samadpour M, Giménez S, Boix P P, Shen Q, Calvo M E, Taghavinia N, Iraji-Zad A, Toyoda T, Míguez H and Mora-Seró I 2012 Electrochimica Acta 75 139
[43]	Samadpour M, Taghavinia N, Iraji-Zad A, Marandi M and Tajabadi F 2012 Euro. Phys. J: Appl. Phys. 57 20401
[44]	Lee H, Wang M, Chen P, Gamelin D R, Zakeeruddin S M, Grätzel M and Nazeeruddin M K 2009 Nano Lett. 9 4221
[45]	Lee H J, Bang J, Park J, Kim S and Park S M 2010 Chem. Mater. 22 5636
[46]	Shen Q, Kobayashi J, Diguna L J and Toyoda T 2008 J. Appl. Phys. 103 084304
[47]	Hodes G, Manassen J and Cahen D 1980 J. Electrochem. Soc. 127 544
[48]	Bisquert, J, Zaban A, Greenshtein M and Mora-Seró I 2004 J. Am. Chem. Soc. 126 13550
[49]	Fabregat-Santiago F, Bisquert J, Garcia-Belmonte G, Boschloo G and Hagfeldt A 2005 Solar Energy Materials and Solar Cells 87 117
[50]	Fabregat-Santiago F, Garcia-Belmonte G, Mora-Seró I and Bisquert J 2011 Phys. Chem. Chem. Phys. 13 9083
[51]	Barea E M, Shalom M, Giménez S, Hod I, Mora-Seró I, Zaban A and Bisquert J 2010 J. Am. Chem. Soc. 132 6834
[52]	Braga A, Giménez S, Concina I, Vomiero A and Mora-Seró I 2011 J. Phys. Chem. Lett. 2 454
[53]	Hod I, González-Pedro V, Tachan Z, Fabregat-Santiago F, Mora-Seró I, Bisquert J and Zaban A 2011 J. Phys. Chem. Lett. 2 3032

Simply synthesized TiO₂ nanorods as an effective scattering layer for quantum dot sensitized solar cells

Simply synthesized TiO₂ nanorods as an effective scattering layer for quantum dot sensitized solar cells

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