The effect of Si content on the martensitic transfor-mation temperature of Ni55.5e18Ga26.5–xSix alloys

doi:10.1088/1674-1056/20/4/046102

中国物理B ›› 2011, Vol. 20 ›› Issue (4): 46102-046102.doi: 10.1088/1674-1056/20/4/046102

The effect of Si content on the martensitic transfor-mation temperature of Ni_55.5e₁₈Ga_26.5–xSi_x alloys

申华海¹, 付浩¹, 郭袁俊¹, 祖小涛¹, 傅永庆², 余华军³

(1)Department of Applied Physics, University of Electronic Science and Technology of China, Chengdu 610054, China; (2)School of Engineering and Physical Sciences, Heriot Watt University, Edinburgh, EH14 4AS, UK; (3)The College of Physics and Electronic Information, Gannan Normal University, Ganzhou 314000, Jiangxi Province, China

收稿日期:2010-06-18 修回日期:2010-11-22 出版日期:2011-04-15 发布日期:2011-04-15
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 10976007), the Fundamental Research Funds for the Central Universities (Grant Nos. ZYGX2009J046 and ZYGX2009X007) and Royal Academy of Engineering-Research Exchanges with China and India Awards in UK.

The effect of Si content on the martensitic transfor-mation temperature of Ni_55.5e₁₈Ga_26.5–xSi_x alloys

Shen Hua-Hai(申华海)^a),Yu Hua-Jun(余华军)^b), Fu Hao(付浩)^a), Guo Yuan-Jun(郭袁俊)^a), Fu Yong-Qing(傅永庆)^c),and Zu Xiao-Tao(祖小涛)^a)^†

^a Department of Applied Physics, University of Electronic Science and Technology of China, Chengdu 610054, China; ^b The College of Physics and Electronic Information, Gannan Normal University, Ganzhou 314000, Jiangxi Province, China; ^c School of Engineering and Physical Sciences, Heriot Watt University, Edinburgh, EH14 4AS, UK

Received:2010-06-18 Revised:2010-11-22 Online:2011-04-15 Published:2011-04-15
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 10976007), the Fundamental Research Funds for the Central Universities (Grant Nos. ZYGX2009J046 and ZYGX2009X007) and Royal Academy of Engineering-Research Exchanges with China and India Awards in UK.

摘要/Abstract

摘要： This paper investigates the effects of substitution of Si for Ga on the martensitic transformation behaviours in Ni-Fe-Ga alloys by using optical metallographic microscope and differential scanning calorimetry (DSC) methods. The structure type of Ni_55.5Fe₁₈Ga_26.5-xSi_x alloys is determined by x-ray diffraction (XRD), and the XRD patterns show the microstructure of Ni-Fe-Ga-Si alloys transformed from body-centred tetragonal martensite (with Si content x = 0) to body-centred cubic austenite (with x = 2) at room temperature. The martensitic transformation temperatures of the Ni_55.5Fe₁₈Ga_26.5-xSi_x alloys decrease almost linearly with increasing Si content in the Si content range of x ≤ 3. Thermal treatment also plays an important role on martensitic transformation temperatures in the Ni-Fe-Ga-Si alloy. The valence electronic concentrations, size factor, L2₁ degree of order and strength of parent phase influence the martensitic transformation temperatures of the Ni-Fe-Ga-Si alloys. An understanding of the relationship between martensitic transformation temperatures and Si content will be significant for designing an appropriate Ni-Fe-Ga-Si alloy for a specific application at a given temperature.

关键词: Ni--Fe--Ga alloys, ferromagnetic shape memory alloys, martensitic transformation, thermal treatment

Abstract: This paper investigates the effects of substitution of Si for Ga on the martensitic transformation behaviours in Ni--Fe--Ga alloys by using optical metallographic microscope and differential scanning calorimetry (DSC) methods. The structure type of Ni$_{55.5}$Fe$_{18}$Ga$_{26.5 - x}$Si$_{x}$ alloys is determined by x-ray diffraction (XRD), and the XRD patterns show the microstructure of Ni--Fe--Ga--Si alloys transformed from body-centred tetragonal martensite (with Si content $x = 0$) to body-centred cubic austenite (with $x = 2$) at room temperature. The martensitic transformation temperatures of the Ni$_{55.5}$Fe$_{18}$Ga$_{26.5 - x}$Si$_{x}$ alloys decrease almost linearly with increasing Si content in the Si content range of $x \le 3$. Thermal treatment also plays an important role on martensitic transformation temperatures in the Ni--Fe--Ga--Si alloy. The valence electronic concentrations, size factor, L2$_{1}$ degree of order and strength of parent phase influence the martensitic transformation temperatures of the Ni--Fe--Ga--Si alloys. An understanding of the relationship between martensitic transformation temperatures and Si content will be significant for designing an appropriate Ni--Fe--Ga--Si alloy for a specific application at a given temperature.

Key words: Ni–Fe–Ga alloys, ferromagnetic shape memory alloys, martensitic transformation, thermal treatment

中图分类号: (Alloys )

61.66.Dk

81.30.Kf (Martensitic transformations) 75.10.-b (General theory and models of magnetic ordering) 81.40.Ef (Cold working, work hardening; annealing, post-deformation annealing, quenching, tempering recovery, and crystallization)

申华海, 余华军, 付浩, 郭袁俊, 傅永庆, 祖小涛. The effect of Si content on the martensitic transfor-mation temperature of Ni_55.5e₁₈Ga_26.5–xSi_x alloys[J]. 中国物理B, 2011, 20(4): 46102-046102.

Shen Hua-Hai(申华海), Yu Hua-Jun(余华军), Fu Hao(付浩), Guo Yuan-Jun(郭袁俊), Fu Yong-Qing(傅永庆), and Zu Xiao-Tao(祖小涛) . The effect of Si content on the martensitic transfor-mation temperature of Ni_55.5e₁₈Ga_26.5–xSi_x alloys[J]. Chin. Phys. B, 2011, 20(4): 46102-046102.

参考文献 19

[1]	Ullakko K, Huang J K, Kantner C, O'Handley R C and Kokorin V V 1996 Appl. Phys. Lett. 69 1966
[2]	Murray S J, Marioni, Allen S M, O'Handley R C and Lograsso T A 2000 Appl. Phys. Lett. 77 886
[3]	Gejima F, Sutou Y, Kainuma R and Ishida K 1999 Metall. Mater. Trans. A 30 2721
[4]	Kakeshita T and Fukeuchi T 2002 Mater. Sci. Forum 394--395 531
[5]	Oikawa K, Ota T, Gejima F, Ohmori T, Kainuma R and Ishida K 2001 Mater. Trans. 42 2472
[6]	Oikawa K, Ota T, Ohmori T, Tanaka Y, Morito H, Fujita A, Kainuma R, Fukamichi K and Ishida K 2002 Appl. Phys. Lett. 81 5201
[7]	Morito H, Oikawa K, Fujita A, Fukamichi K, Kainuma R, Ishida K and Fukuda T 2005 J. Magn. Magn. Mater. 290--291 850
[8]	Zheng H X, Liu J, Xia M X and Li J G 2005 J. Alloy. Compd. 387 265
[9]	Yu H J, Fu H, Wang Z G and Zu X T 2009 Mater. Sci. Eng. A 507 37
[10]	Chernenko V A 1999 Scr. Mater. 40 523
[11]	Liu Z H, Liu H, Zhang X X, Zhang M, Dai X F, Hu H N, Chen J L and Wu G H 2004 Phys. Lett. A 329 214
[12]	Jin X, Marioni M, Bono D, Allen S M, O'Handley R C and Hsu T Y 2002 J. Appl. Phys. 91 8222
[13]	Kokorin V V, Osipenko I A and Shirina T V 1989 Phys. Met. Metallogr. 67 173
[14]	Zhao H, Guan Y F and Zhu B 1992 General Chemistry (Shanghai: East China Normal University Press) p. 365 (in Chinese)
[15]	Chen F, Wang H B, Zheng Y F, Cai W and Zhao L C 2005 J. Mater. Sci. 40 219
[16]	Wu J X, Jiang B H and Hsu T Y 1988 Acta Metallur. 36 1521
[17]	Miyazaki S and Otsuka K 1989 ISIJ Int. 29 353
[18]	Hsu T Y 1999 Martensitic Transformation and Martensite 2nd edn. (Beijing: Science Press) p. 64 (in Chinese)
[19]	Oikawa K, Omori T, Kainuma R and Ishida K 2004 J. Magn. Magn. Mater. 272--276 2043

The effect of Si content on the martensitic transfor-mation temperature of Ni_55.5e₁₈Ga_26.5–xSi_x alloys

The effect of Si content on the martensitic transfor-mation temperature of Ni_55.5e₁₈Ga_26.5–xSi_x alloys

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献 19

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	Yong Li(李勇), Liang Qin(覃亮), Hongguo Zhang(张红国), and Lingwei Li(李领伟). Tailored martensitic transformation and enhanced magnetocaloric effect in all-d-metal Ni₃₅Co₁₅Mn₃₃Fe₂Ti₁₅ alloy ribbons[J]. 中国物理B, 2022, 31(8): 87103-087103.
[2]	Chun-Mei Li(李春梅), Shun-Jie Yang(杨顺杰), and Jin-Ping Zhou(周金萍). Alloying and magnetic disordering effects on phase stability of Co₂ YGa (Y=Cr, V, and Ni) alloys: A first-principles study[J]. 中国物理B, 2022, 31(5): 56105-056105.
[3]	李勇, 徐鹏, 张小明, 刘国栋, 刘恩克, 李领伟. Electronic structures, magnetic properties, and martensitic transformation in all-d-metal Heusler-like alloys Cd₂MnTM(TM=Fe, Ni, Cu)[J]. 中国物理B, 2020, 29(8): 87101-087101.
[4]	周敏, 李玉霜, 张晨, 李来风. Elastocaloric effect and mechanical behavior for NiTi shape memory alloys[J]. 中国物理B, 2018, 27(10): 106501-106501.
[5]	罗小华, 任卫军, 金伟, 张志东. Large elastocaloric effect in Ti-Ni shape memory alloy below austenite finish temperature[J]. 中国物理B, 2017, 26(3): 36501-036501.
[6]	武雅乔, 胡明, 田玉明. Room temperature NO₂-sensing properties of hexagonal tungsten oxide nanorods[J]. 中国物理B, 2017, 26(2): 20701-020701.
[7]	Ishfaq Ahmad Shah, Najam ul Hassan, 刘俊, 龚元元, 徐桂舟, 徐锋. Effect of Sb-doping on martensitic transformation and magnetocaloric effect in Mn-rich Mn₅₀Ni₄₀Sn_10-xSb_x (x=1, 2, 3, and 4) alloys[J]. 中国物理B, 2017, 26(1): 17501-017501.
[8]	谭昌龙, 张琨, 田晓华, 蔡伟. Magnetic and mechanical properties of Ni–Mn–Ga/Fe–Ga ferromagnetic shape memory composite[J]. 中国物理B, 2015, 24(5): 57502-057502.
[9]	王立英, 代学芳, 王啸天, 林婷婷, 陈磊, 刘然, 崔玉亭, 刘国栋. Electronic structures and magnetisms of the Co₂TiSb_1-xSn_x (x=0, 0.25, 0.5) Heusler alloys: A theoretical study of the shape-memory behavior[J]. 中国物理B, 2015, 24(12): 126201-126201.
[10]	谢忍, 韦俊, 刘仲武, 唐妍梅, 唐涛, 唐少龙, 都有为. Evolution of magnetic domain structure of martensite in Ni-Mn-Ga films under the interplay of the temperature and magnetic field[J]. 中国物理B, 2014, 23(6): 68103-068103.
[11]	韦俊, 谢忍, 陈乐易, 唐研梅, 许连强, 唐少龙, 都有为. Relation between martensitic transformation temperature range and lattice distortion ratio of NiMnGaCoCu Heusler alloys[J]. 中国物理B, 2014, 23(4): 48107-048107.
[12]	张雅卓, 曹伽牧, 谭昌龙, 曹一江, 蔡伟. Pressure effects on magnetic properties and martensitic transformation of Ni–Mn–Sn magnetic shape memory alloys[J]. 中国物理B, 2014, 23(3): 37504-037504.
[13]	新梅, 胡礼中. Luminescence properties of ZnS：Cu, Eu semiconductor nanocrystals synthesized by a hydrothermal process[J]. 中国物理B, 2013, 22(8): 87804-087804.
[14]	李歌天, 柳祝红, 孟凡研, 马星桥, 吴光恒. Effects of Cu on the martensitic transformation and magnetic properties of Mn₅₀Ni₄₀In₁₀ alloy[J]. Chin. Phys. B, 2013, 22(12): 126201-126201.
[15]	谢忍, 唐少龙, 唐妍梅, 刘枭辰, 唐涛, 都有为. Transformation behaviors, structural and magnetic characteristics of Ni–Mn–Ga films on MgO (001)[J]. 中国物理B, 2013, 22(10): 107502-107502.