Study of second-order nonlinear hyperpolarisability of all-trans-β-carotene in solutions by linear spectroscopic technique

doi:10.1088/1674-1056/19/6/064213

中国物理B ›› 2010, Vol. 19 ›› Issue (6): 64213-064213.doi: 10.1088/1674-1056/19/6/064213

Study of second-order nonlinear hyperpolarisability of all-trans-β-carotene in solutions by linear spectroscopic technique

门志伟¹, 曲冠男¹, 杨光¹, 里佐威¹, 高淑琴¹, 陆国会¹, 孙成林², 房文汇³

(1)College of Physics, Jilin University, Changchun 130021, China; (2)State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130021, China; (3)State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130021, China;College of Physics, Jilin University, Changchun 130021, China

收稿日期:2009-05-04 出版日期:2010-06-15 发布日期:2010-06-15
基金资助:
Project supported by the National Natural Science Foundation of China (Gant Nos.~10774057 and 10974067).

Study of second-order nonlinear hyperpolarisability of all-trans-$\beta$-carotene in solutions by linear spectroscopic technique

Fang Wen-Hui(房文汇)^a)b), Men Zhi-Wei(门志伟)^b), Sun Cheng-Lin(孙成林)^a)^† Qu Guan-Nan(曲冠男)^b), Yang Guang(杨光)^b), Li Zuo-Wei(里佐威)^a)b),Gao Shu-Qin(高淑琴)^b), and Lu Guo-Hui(陆国会)^b)

^a State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130021, China; ^b College of Physics, Jilin University, Changchun 130021, China

Received:2009-05-04 Online:2010-06-15 Published:2010-06-15
Supported by:
Project supported by the National Natural Science Foundation of China (Gant Nos.~10774057 and 10974067).

摘要/Abstract

摘要： This paper demonstrates the second-order nonlinear hyperpolarisability \gamma of all-trans-β-carotene in different solvents by linear spectroscopic technique that is based on resonance Raman scattering and UV--VIS (Ultraviolet-visible) absorption spectroscopy. Owing to the two-level model well describing the link that exists between the resonance Raman scattering and stimulated Raman scattering, the stimulated Raman polarisability α_{\rm R} can be calculated through the two-photon resonance system. The value of \gamma of all-trans-β-carotene in carbon bisulfide solution is 6.435\times 10^{-33} esu (1~esu of resistance =8.98755\times10^{11}~\Omega) that is close to the true value, because the solution of all-trans-β-carotene in carbon bisulfide satisfies the rigid resonance Raman scattering condition. This method is expected to be worthy of applications to measure the second-order nonlinear hyperpolarisability of a conjugate organic molecule.

Abstract: This paper demonstrates the second-order nonlinear hyperpolarisability $\gamma$ of all-trans-$\beta$-carotene in different solvents by linear spectroscopic technique that is based on resonance Raman scattering and UV--VIS (Ultraviolet-visible) absorption spectroscopy. Owing to the two-level model well describing the link that exists between the resonance Raman scattering and stimulated Raman scattering, the stimulated Raman polarisability $\alpha_{\rm R}$ can be calculated through the two-photon resonance system. The value of $\gamma$ of all-trans-$\beta$-carotene in carbon bisulfide solution is $6.435\times 10^{-33}$ esu (1 esu of resistance = $8.98755\times10^{11}~\Omega$) that is close to the true value, because the solution of all-trans-$\beta$-carotene in carbon bisulfide satisfies the rigid resonance Raman scattering condition. This method is expected to be worthy of applications to measure the second-order nonlinear hyperpolarisability of a conjugate organic molecule.

Key words: all-trans-$\beta$-carotene, second-order nonlinear hyperpolarisability, rigid resonance Raman scattering, UV--VIS absorption spectroscopy

中图分类号:

78.30.Cp

78.40.Dw (Liquids) 61.25.Em (Molecular liquids)

房文汇, 门志伟, 孙成林, 曲冠男, 杨光, 里佐威, 高淑琴, 陆国会. Study of second-order nonlinear hyperpolarisability of all-trans-β-carotene in solutions by linear spectroscopic technique[J]. 中国物理B, 2010, 19(6): 64213-064213.

Fang Wen-Hui(房文汇), Men Zhi-Wei(门志伟), Sun Cheng-Lin(孙成林) Qu Guan-Nan(曲冠男), Yang Guang(杨光), Li Zuo-Wei(里佐威),Gao Shu-Qin(高淑琴), and Lu Guo-Hui(陆国会). Study of second-order nonlinear hyperpolarisability of all-trans-$\beta$-carotene in solutions by linear spectroscopic technique[J]. Chin. Phys. B, 2010, 19(6): 64213-064213.

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Study of second-order nonlinear hyperpolarisability of all-trans-β-carotene in solutions by linear spectroscopic technique

Study of second-order nonlinear hyperpolarisability of all-trans-$\beta$-carotene in solutions by linear spectroscopic technique

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