中国物理B ›› 1997, Vol. 6 ›› Issue (3): 205-211.doi: 10.1088/1004-423X/6/3/006

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STUDY OF DOPING EFFECT ON THE Bi2Sr2Ca2Cu3Oy SUPERCONDUCTOR

胡玉才1, 李仁宸1, 刘建2, 白培光2   

  1. (1)Department of General Studies, Dalian Fisheries College, Dalian 116023, China; (2)Department of Physics, Inner Mogolia University, Hohhot 010021, China
  • 收稿日期:1995-12-13 出版日期:1997-03-20 发布日期:1997-03-20

STUDY OF DOPING EFFECT ON THE Bi2Sr2Ca2Cu3Oy SUPERCONDUCTOR

HU YU-CAI (胡玉才)a, LIU JIAN (刘建)b, LI REN-CHENG (李仁宸)a, BAI PEI-GUANG (白培光)b   

  1. a Department of General Studies, Dalian Fisheries College, Dalian 116023, China; b Department of Physics, Inner Mogolia University, Hohhot 010021, China
  • Received:1995-12-13 Online:1997-03-20 Published:1997-03-20

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摘要： We have systematically investigated the doping effect on the Bi2Sr2Ca2Cu3Oy superconductive material. After entering into the crystal lattice, Pb and/or Sb atoms cause not only variations of the temperature condition during the sample preparation process, but also variations of structures and superconductivity. By analyzing the experimental results, we have come to the conclusion that the Pb and/or Sb atoms enter into the Bi-O planes, preferably occupy the sites of Bi ions, regulate the crystal structures and the distribution of oxygen ions in Bi-O planes and nearby lattice sites, thus benefiting the formation of the high-Tc phase and improving the superconductivity.

Abstract: We have systematically investigated the doping effect on the Bi2Sr2Ca2Cu3Oy superconductive material. After entering into the crystal lattice, Pb and/or Sb atoms cause not only variations of the temperature condition during the sample preparation process, but also variations of structures and superconductivity. By analyzing the experimental results, we have come to the conclusion that the Pb and/or Sb atoms enter into the Bi-O planes, preferably occupy the sites of Bi ions, regulate the crystal structures and the distribution of oxygen ions in Bi-O planes and nearby lattice sites, thus benefiting the formation of the high-Tc phase and improving the superconductivity.

中图分类号:  (Effects of crystal defects, doping and substitution)

  • 74.62.Dh
74.62.Bf (Effects of material synthesis, crystal structure, and chemical composition)