Luminescent characteristics of Tm3+/Tb3+/Eu3+ tri-doped Na5Y9F32 single crystals for white emission with high thermal stability

doi:10.1088/1674-1056/ac6160

中国物理B ›› 2022, Vol. 31 ›› Issue (12): 127802-127802.doi: 10.1088/1674-1056/ac6160

Luminescent characteristics of Tm³⁺/Tb³⁺/Eu³⁺ tri-doped Na₅Y₉F₃₂ single crystals for white emission with high thermal stability

Lizhi Fang(方立志)¹, Xiong Zhou(周雄)¹, Zhiwei Zhao(赵志伟)², Biao Zheng(郑标)³, Haiping Xia(夏海平)^1,†, Jun Wang(王军)^3,‡, Hongwei Song(宋宏伟)⁴, and Baojiu Chen(陈宝玖)⁵

1 Key Laboratory of Photo-electronic Materials, Ningbo University, Ningbo 315211, China;
2 Taizhou Special Equipment Inspection and Research Institute, Taizhou 318000, China;
3 Fujian Provincial Key Laboratory of Functional Marine Sensing Materials, Center for Advanced Marine Sensing Materials and Smart Sensors, Minjiang University, Fuzhou 350108, China;
4 State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering and College of Physics, Jilin University, Changchun 130012, China;
5 Department of Physics, Dalian Maritime University, Dalian 116026, China

收稿日期:2022-01-09 修回日期:2022-03-15 接受日期:2022-03-28 出版日期:2022-11-11 发布日期:2022-11-19
通讯作者: Haiping Xia, Jun Wang E-mail:hpxcm@nbu.edu.cn;wjnaf@163.com
基金资助:
Project supported by the National Natural Science Foundation of China (Grant No. 62275133), the Natural Science Foundation of Zhejiang Province of China (Grant No. LY22E020002), the Natural Science Foundation of Ningbo (Grant Nos. 2021J077 and 202003N4099), and K.C. Wong Magna Fund in Ningbo University.

Luminescent characteristics of Tm³⁺/Tb³⁺/Eu³⁺ tri-doped Na₅Y₉F₃₂ single crystals for white emission with high thermal stability

1 Key Laboratory of Photo-electronic Materials, Ningbo University, Ningbo 315211, China;
2 Taizhou Special Equipment Inspection and Research Institute, Taizhou 318000, China;
3 Fujian Provincial Key Laboratory of Functional Marine Sensing Materials, Center for Advanced Marine Sensing Materials and Smart Sensors, Minjiang University, Fuzhou 350108, China;
4 State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering and College of Physics, Jilin University, Changchun 130012, China;
5 Department of Physics, Dalian Maritime University, Dalian 116026, China

Received:2022-01-09 Revised:2022-03-15 Accepted:2022-03-28 Online:2022-11-11 Published:2022-11-19
Contact: Haiping Xia, Jun Wang E-mail:hpxcm@nbu.edu.cn;wjnaf@163.com
Supported by:
Project supported by the National Natural Science Foundation of China (Grant No. 62275133), the Natural Science Foundation of Zhejiang Province of China (Grant No. LY22E020002), the Natural Science Foundation of Ningbo (Grant Nos. 2021J077 and 202003N4099), and K.C. Wong Magna Fund in Ningbo University.

摘要/Abstract

摘要： By using an improved Bridgman method, 0.3 mol% Tm$^{3+}/0.6$ mol% Tb$^{3+}/y$ mol% Eu$^{3+}$ ($y = 0$, 0.4, 0.6, 0.8) doped Na$_{5}$Y$_{9}$F$_{32}$ single crystals were prepared. The x-ray diffraction, excitation spectra, emission spectra and fluorescence decay curves were used to explore the crystal structure and optical performance of the obtained samples. When excited by 362 nm light, the cool white emission was realized by Na$_{5}$Y$_{9}$F$_{32}$ single crystal triply-doped with 0.3 mol% Tm$^{3+}/0.6$ mol% Tb$^{3+}/0.8$ mol% Eu$^{3+}$, in which the Commission Internationale de l'Eclairage (CIE) chromaticity coordinate was (0.2995, 0.3298) and the correlated color temperature (CCT) was 6586 K. The integrated normalized emission intensity of the tri-doped single crystal at 448 K could keep 62% of that at 298 K. The internal quantum yield (QY) was calculated to be $\sim 15.16$% by integrating spheres. These results suggested that the single crystals tri-doped with Tm$^{3+}$, Tb$^{3+}$ and Eu$^{3+}$ ions have a promising potential application for white light-emitting diodes (w-LEDs).

关键词: Tm³⁺/Tb³⁺/Eu³⁺ triply-doped Na₅Y₉F₃₂, white light emission, energy transfer process, thermal stability

Abstract: By using an improved Bridgman method, 0.3 mol% Tm$^{3+}/0.6$ mol% Tb$^{3+}/y$ mol% Eu$^{3+}$ ($y = 0$, 0.4, 0.6, 0.8) doped Na$_{5}$Y$_{9}$F$_{32}$ single crystals were prepared. The x-ray diffraction, excitation spectra, emission spectra and fluorescence decay curves were used to explore the crystal structure and optical performance of the obtained samples. When excited by 362 nm light, the cool white emission was realized by Na$_{5}$Y$_{9}$F$_{32}$ single crystal triply-doped with 0.3 mol% Tm$^{3+}/0.6$ mol% Tb$^{3+}/0.8$ mol% Eu$^{3+}$, in which the Commission Internationale de l'Eclairage (CIE) chromaticity coordinate was (0.2995, 0.3298) and the correlated color temperature (CCT) was 6586 K. The integrated normalized emission intensity of the tri-doped single crystal at 448 K could keep 62% of that at 298 K. The internal quantum yield (QY) was calculated to be $\sim 15.16$% by integrating spheres. These results suggested that the single crystals tri-doped with Tm$^{3+}$, Tb$^{3+}$ and Eu$^{3+}$ ions have a promising potential application for white light-emitting diodes (w-LEDs).

Key words: Tm³⁺/Tb³⁺/Eu³⁺ triply-doped Na₅Y₉F₃₂, white light emission, energy transfer process, thermal stability

中图分类号: (Optically stimulated luminescence)

78.60.Lc

78.66.Sq (Composite materials)

Lizhi Fang(方立志), Xiong Zhou(周雄), Zhiwei Zhao(赵志伟), Biao Zheng(郑标), Haiping Xia(夏海平), Jun Wang(王军), Hongwei Song(宋宏伟), and Baojiu Chen(陈宝玖). Luminescent characteristics of Tm³⁺/Tb³⁺/Eu³⁺ tri-doped Na₅Y₉F₃₂ single crystals for white emission with high thermal stability[J]. 中国物理B, 2022, 31(12): 127802-127802.

参考文献

[1] Xiao F, Yi R, Yuan H, Zang G and Xie C 2018 Spectrochim. Acta A 202 352
[2] Ray S, Tadge P, Dutta S, et al. 2018 Ceramics International 44 8334
[3] Jha K, Vishwakarma A K, Jayasimhadri M and Haranath D 2017 J. Alloys Compd. 719 116
[4] Chang J, Chen C, Rudysh M, Brik M G, Piasecki M and Liu W 2019 J. Lumin. 206 417
[5] Chen D, Zhou Y and Zhong J A 2016 RSC Advances 6 86285
[6] Wang X, Li X, Xu S, et al. 2020 J. Asian Ceram. Soc. 8 1066
[7] Kang F W, Hu Y H, Wu H Y, et al. 2011 Chin. Phys. Lett. 28 107201
[8] Dai P and Ma R 2020 J. Alloys Compd. 812 152143
[9] Mungra M, Steudel F, Ahrens B, et al. 2017 Journal of Luminescence 192 71
[10] Yu M, Xu X, Zhang W, Chen X, Zhang P and Huang Y 2020 J. Alloys Compd. 817 152761
[11] Shang M, Li C and Lin J 2014 Chem. Soc. Rev. 43 1372
[12] Liu Y, Liu G, Wang J, et al. 2014 Inorg. Chem. 53 11457
[13] Jin Y, Lu W, Zhang J, et al. 2014 J. Nanosci Nanotechno. 14 3683
[14] Naresh V, Gupta K, Reddy C P and Ham B S 2017 Spectrochim. Acta A 175 43
[15] Qiao Y, Zhou X, Zhang J, et al. 2020 J. Alloys Compd. 824 153987
[16] Qiao Y, Zhou X, Zhang J, Xia H, Song H and Chen B 2020 Infrared Phys. Techn. 105 103183
[17] Wang H, Xia H, Hu J, Zhu Y and Chen B 2018 J. Alloys Compd. 765 1035
[18] LeJemtel T H, Keung E, Sonnenblick E H, et al. 1979 Circulation 59 1098
[19] Chen D, Yu Y, Huang P, et al. 2010 Acta Mater. 58 3035
[20] Liu X, Chen G, Chen Y and Yang T 2017 J. Non-Cryst Solids 476 100
[21] Xu M, Ding Y, Luo W, et al. 2020 Optics & Laser Technology 121 105829
[22] Li B, Wang S, Sun Q, Lu C, Guo H and Huang X 2018 Dyes Pigments 154 252
[23] Cao J, Wang X, Li X, Wei Y, Chen L and Guo H 2016 J. Lumin. 170 207
[24] Jiao M, Guo N, Lü W, et al. 2013 Inorganic Chem. 52 10340
[25] Chen C, Gu Z, Li Q and Zhang Y 2020 J. Eur. Ceram. Soc. 40 4595
[26] Du P and Yu J S 2015 J. Alloys Compd. 653 468
[27] Luo D, Chen Q, Liu B, et al. 2019 Polymers 11 384
[28] Beck A R, Das S and Manam J 2017 J. Mater. Sci. 28 17168
[29] Xu F, Fang L, Zhou X, et al. 2020 Opt. Mater. 108 110222
[30] Yu B, Zheng B, Xia H, et al. 2021 Ceram. Int. 47 9668
[31] Jiao M, Xu Q, Liu M, et al. 2018 Chem. Phys. 20 26995
[32] Li Q, Zhang S, Lin W, Li W, Li Y, Mu Z and Wu F 2020 Spectrochim. Acta A 228 117755
[33] Zhang X, Zhou L, Pang Q, et al. 2014 J. Phys. Chem. C 118 7591
[34] Giraldo O G, Fei M, Wei R, Teng L, Zheng Z and Guo H 2020 J. Lumin. 219 116918
[35] Li J Y, Hou D, Zhang Y, Li H, Lin H, Lin Z, Zhou W and Huang R 2019 J. Lumin. 213 184
[36] Som S, Das S, Dutta S, et al. 2015 RSC Advances 5 70887
[37] Jiao Y, Wu X, Ren Q, et al. 2019 Optics & Laser Technology 109 470

Luminescent characteristics of Tm³⁺/Tb³⁺/Eu³⁺ tri-doped Na₅Y₉F₃₂ single crystals for white emission with high thermal stability

Luminescent characteristics of Tm³⁺/Tb³⁺/Eu³⁺ tri-doped Na₅Y₉F₃₂ single crystals for white emission with high thermal stability

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