Improved photovoltaic effects in Mn-doped BiFeO3 ferroelectric thin films through band gap engineering*

Project supported by the National Natural Science Foundation of China (Grant Nos. 11274322, 51402318, 61404080, and 61675066), the National Key Technology Research and Development Program of China (Grant No. 2016YFA0201102), and the China Postdoctoral Science Foundation (Grant No. 2016LH0050).

Yan Tang-Liu1, 3, 4, Chen Bin3, 4, †, Liu Gang3, 4, Niu Rui-Peng2, Shang Jie3, 4, Gao Shuang3, 4, Xue Wu-Hong3, 4, Jin Jing1, ‡, Yang Jiu-Ru2, §, Li Run-Wei3, 4
       

(color online) (a) XRD –2 scan patterns of BiFeO3 (black), BiFe0.9Mn (blue), BiFe0.7Mn (red), and BiFe0.5Mn (green) thin films deposited on Nb-STO (100) substrates. The peaks are indexed as B for BFMO, S for Nb-STO. The left image is the enlarged view of XRD image. (b) AFM images of BiFe Mn O (x = 0, 0.1, 0.3, 0.5) thin films.