Synthesis of black phosphorus structured polymeric nitrogen

doi:10.1088/1674-1056/aba9bd

Abstract

Since the discoveries of polymeric nitrogen, named cg-N (2004), LP-N (2014), HLP-N (2019), another polymorph named black phosphorus nitrogen (BP-N) was synthesized at high-pressure-high-temperature conditions. The narrow existing pressure region and similar synthesized pressure of BP-N compared with cg-N indicate that the stable energy and enthalpy of formation of these two structures are close to each other, which was confirmed by our theoretical calculation. In order to obtain the pressure region of BP-N phase, pure N₂ and TiN/Pb + N₂ precursors were used for laser-heating high pressure experiments in diamond anvil cell (DAC), and the phase identity was examined by Raman and XRD mapping. BP-N can be synthesized in the pressure range of 130 GPa to 140 GPa with the assistance of heating absorber. With the decrease of the pressure, BP-N can be quenched to ∼ 40 GPa. The synthesizing pressure–temperature and the stable pressure region of BP-N are important for further exploration of BP-N and its kinetic and thermal dynamic relationship with other polymeric nitrogen, especially cg-N.

Keywords: high pressure and high temperature energetic materials polymeric nitrogen diamond anvil cell

Received: 23 June 2020
Revised: 16 July 2020
Accepted manuscript online: 28 July 2020

PACS:	62.50.-p	(High-pressure effects in solids and liquids)
	61.05.cp	(X-ray diffraction)
	42.62.-b	(Laser applications)
	07.35.+k	(High-pressure apparatus; shock tubes; diamond anvil cells)

Corresponding Authors: ^†Corresponding author. E-mail: liuying8912@aliyun.com

About author:

†Corresponding author. E-mail: liuying8912@aliyun.com

* Project supported by the National Natural Science Foundation of China (Grant No. 11904281).

Cite this article:

Ying Liu(刘影)†, Haipeng Su(苏海鹏), Caoping Niu(牛草萍), Xianlong Wang(王贤龙), Junran Zhang(张俊然), Zhongxue Ge(葛忠学), and Yanchun Li(李延春) Synthesis of black phosphorus structured polymeric nitrogen 2020 Chin. Phys. B 29 106201

Fig. 1.

(a) Raman spectra of nitrogen heated at 143 GPa from run I (black) compared with the experimental spectra for BP-structured polymeric nitrogen (red bars) at 138 GPa, 2200 K.^[16] Inset shows the microscopic images of the sample under illumination with both reflected and transmitted light before and after laser heating. (b) Crystal structure of BP-N under 140 GPa.

Fig. 2.

Raman spectra of nitrogen before and after heating at 130 GPa using TiN and Pb as laser absorber, respectively.

Table 1.

Experimental details of the five experimental runs, including the experimental conditions and major results.

Fig. 3.

(a) Raman spectra of BP-N during the decompression. (b) Measured pressure dependence of Raman shift (run III) of BP-N and (run II) of CG-N compared with calculations and previously reported values^{[10,13,15,16]} of polymeric nitrogen. All measurements were performed during decompression.

Fig. 4.

(a) The equation of state, (b) formation enthalpy, and (c) energy density of CH-N, BP-N, and cg-N. The values of CH-N, BP-N, and cg-N phases are shown in red triangle, red circle, and blue square, respectively. The red vertical dotted line indicates the pressure (20 GPa), where CH-N becomes stable.

[1]	Uddin J, Barone V, Scuseria G E 2006 Mol. Phys. 104 745 DOI: 10.1080/00268970500417325
[2]	Mailhiot C, Yang L H, McMahan A K 1992 Phys. Rev. B 46 14419 DOI: 10.1103/PhysRevB.46.14419
[3]	Alemany M M G, Martins J L 2003 Phys. Rev. B 68 024110 DOI: 10.1103/PhysRevB.68.024110
[4]	Ma Y M, Oganov A R, Li Z, Xie Y, Kotakoski J 2009 Phys. Rev. Lett. 102 065501 DOI: 10.1103/PhysRevLett.102.065501
[5]	Mattson W D, Sanchez-Portal D, Chiesa S, Martin R M 2004 Phys. Rev. Lett. 93 125501 DOI: 10.1103/PhysRevLett.93.125501
[6]	Zahariev F, Hooper J, Alavi S, Zhang F, Woo T K 2007 Phys. Rev. B 75 140101 DOI: 10.1103/PhysRevB.75.140101
[7]	Zahariev F, Hu A, Hooper J, Zhang F, Woo T K 2005 Phys. Rev. B 72 214108 DOI: 10.1103/PhysRevB.72.214108
[8]	Yao Y, Tse J S, Tanaka K 2008 Phys. Rev. B 77 052103 DOI: 10.1103/PhysRevB.77.052103
[9]	Wang X l, Wang Y C, Miao M S, Zhong X, Lv J, Cui T, Li J F, Chen L, Pickard C J, Ma Y M 2012 Phys. Rev. Lett. 109 175502 DOI: 10.1103/PhysRevLett.109.175502
[10]	Eremets M I, Gavriliuk A G, Trojan I A, Dzivenko D A, Boehler R 2004 Nat. Mater. 3 558 DOI: 10.1038/nmat1146
[11]	Lipp M J, Klepeis J P, Baer B J, Cynn H, Evans W J, Iota V, Yoo C S 2007 Phys. Rev. B 76 014113 DOI: 10.1103/PhysRevB.76.014113
[12]	Lei L, Tang Q Q, Zhang F, Liu S, Wu B B, Zhou C Y 2020 Chin. Phys. Lett. 37 068101 DOI: 10.1088/0256-307X/37/6/068101
[13]	Tomasino D, Kim M, Smith J, Yoo C S 2014 Phys. Rev. Lett. 113 205502 DOI: 10.1103/PhysRevLett.113.205502
[14]	Laniel D, Geneste G, Weck G, Mezouar M, Loubeyre P 2019 Phys. Rev. Lett. 122 066001 DOI: 10.1103/PhysRevLett.122.066001
[15]	Laniel D, Winkler B, Fedotenko T, Pakhomova A, Chariton S, Milman V, Prakapenka V, Dubrovinsky L, Dubrovinskaia N 2020 Phys. Rev. Lett. 124 216001 DOI: 10.1103/PhysRevLett.124.216001
[16]	Ji C, Adeleke A A, Yang L X, Wan B, Gou H Y, Yao Y S, Li B, Meng Y, Smith J S, Prakapenka V B, Liu W J, Shen G Y, Mao W L, Mao H K 2020 Sci. Adv. 6 eaba9206 DOI: 10.1126/sciadv.aba9206
[17]	Zou G T, Ma Y Z, Mao H K, Hemley R J, Gramsch S A 2001 Rev. Sci. Instrum. 72 1298 DOI: 10.1063/1.1343864
[18]	Dewaele A, Mezouar M, Guignot N, Loubeyre P 2010 Phys. Rev. Lett. 104 255701 DOI: 10.1103/PhysRevLett.104.255701
[19]	Hirai S, Kojima Y, Ohfuji H, Nishiyama N, Irifune T, Klemme S, Bromiley G, Attfield J P 2011 Phys. Chem. Miner. 38 631 DOI: 10.1007/s00269-011-0435-2
[20]	Akahama Y, Kawamura H 2010 J. Phys.: Conf Ser. 215 012195 DOI: 10.1088/1742-6596/215/1/012195
[21]	Shen G, Mao H K 2017 Rep. Prog. Phys. 80 016101 DOI: 10.1088/1361-6633/80/1/016101
[22]	Prescher C, Prakapenka V B 2015 High Press. Res. 35 223 DOI: 10.1080/08957959.2015.1059835
[23]	Kresse G, Hafner J 1993 Phys. Rev. B 48 13115 DOI: 10.1103/PhysRevB.48.13115
[24]	Kresse G, Furthmüller J 1996 Phys. Rev. B 54 11169 DOI: 10.1103/PhysRevB.54.11169
[25]	Perdew J P, Burke K, Ernzerhof M 1996 Phys. Rev. Lett. 77 3865 DOI: 10.1103/PhysRevLett.77.3865
[26]	Blöchl P E 1994 Phys. Rev. B 50 17953 DOI: 10.1103/PhysRevB.50.17953
[27]	Joubert D 1999 Phys. Rev. B 59 1758 DOI: 10.1103/PhysRevB.59.1758
[28]	Qian G R, Niu H Y, Hu C H, Oganov A R, Zeng Q F, Zhou H Y 2016 Sci. Rep. 6 25947 DOI: 10.1038/srep25947
[29]	Yu S Y, Huang B W, Zeng Q F, Oganov A R, Zhang L T, Frapper G 2017 J. Phys. Chem. C 121 11037 DOI: 10.1021/acs.jpcc.7b00474
[30]	Laniel D, Winkler B, Koemets E, Fedotenko T, Bykov M, Bykova E, Dubrovinsky L, Dubrovinskaia N 2019 Nat. Commun. 10 4515 DOI: 10.1038/s41467-019-12530-w
[31]	Du H F, Ge Y F, Guo W, Zhu J L, Yao Y G PCCP revision
[32]	Eremets M I 1996 High Pressure Experimental Methods Oxford Oxford Univ. Press
[33]	Eremets M I, Gavriliuk A G, Serebryanaya N R, Trojan I A, Dzivenko D A, Boehler R, Mao H K, Hemley R J 2004 J. Chem. Phys. 121 11296 DOI: 10.1063/1.1814074
[34]	Eremets M I, Hemley R J, Mao H K, Gregoryanz E 2001 Nature 411 170 DOI: 10.1038/35075531
[35]	Benchafia E M, Yao Z H, Yuan G, Chou T M, Piao H, Wang X Q, Iqbal Z 2017 Nat. Commun. 8 930 DOI: 10.1038/s41467-017-00060-2
[36]	Shi X H, Liu B, Yao Z, Liu B B 2020 Chin. Phys. Lett. 37 047101 DOI: 10.1088/0256-307X/37/4/047101

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Synthesis of black phosphorus structured polymeric nitrogen

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