Fractional variant of Stokes-Einstein relation in aqueous ionic solutions under external static electric fields

doi:10.1088/1674-1056/ab695b

Abstract Both ionic solutions under an external applied static electric field E and glassy-forming liquids under undercooled state are in non-equilibrium state. In this work, molecular dynamics (MD) simulations with three aqueous alkali ion chloride (NaCl, KCl, and RbCl) ionic solutions are performed to exploit whether the glass-forming liquid analogous fractional variant of the Stokes-Einstein relation also exists in ionic solutions under E. Our results indicate that the diffusion constant decouples from the structural relaxation time under E, and a fractional variant of the Stokes-Einstein relation is observed as well as a crossover analogous to the glass-forming liquids under cooling. The fractional variant of the Stokes-Einstein relation is attributed to the E introduced deviations from Gaussian and the nonlinear effect.

Keywords: ionic solutions Stokes-Einstein relation non-equilibrium steady state molecular dynamics simulation

Received: 03 August 2019
Revised: 23 December 2019
Accepted manuscript online:

PACS:	61.20.Ja	(Computer simulation of liquid structure)
	78.30.cd	(Solutions and ionic liquids)
	82.20.Wt	(Computational modeling; simulation)

Fund: Project supported by the Science Foundation of Civil Aviation Flight University of China (Grant Nos. J2019-059 and JG2019-19).

Corresponding Authors: Gan Ren
E-mail: rengan@alumni.itp.ac.cn

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Gan Ren(任淦), Shikai Tian(田时开) Fractional variant of Stokes-Einstein relation in aqueous ionic solutions under external static electric fields 2020 Chin. Phys. B 29 036101

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Fractional variant of Stokes-Einstein relation in aqueous ionic solutions under external static electric fields

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