A new technology for controlling in-situ oxygen fugacity in diamond anvil cells and measuring electrical conductivity of anhydrous olivine at high pressures and temperatures

doi:10.1088/1674-1056/ab5934

Abstract We present a novel technique for controlling oxygen fugacity, which is broadly used to in-situ measure the electrical conductivities in minerals and rocks during diamond anvil cell experiments. The electrical conductivities of olivine are determined under controlled oxygen fugacity conditions (Mo-MoO₂) at pressures up to 4.0 GPa and temperatures up to 873 K. The advantages of this new technique enable the measuring of the activation enthalpy, activation energy, and activation bulk volume in the Arrhenius relationship. This provides an improved understanding of the mechanism of conduction in olivine. Electrical conduction in olivine is best explained by small polaron movement, given the oxygen fugacity-dependent variations in conductivity.

Keywords: high pressure high temperature oxygen fugacity

Received: 30 September 2019
Revised: 08 November 2019
Accepted manuscript online:

PACS:	91.60.-x	(Physical properties of rocks and minerals)
	91.60.Gf	(High-pressure behavior)
	91.60.Ki	(Thermal properties)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 11674404, 41330206, and 11374121).

Corresponding Authors: Chun-Xiao Gao
E-mail: cc060109@qq.com

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Wen-Shu Shen(沈文舒), Lei Wu(吴雷), Tian-Ji Ou(欧天吉), Dong-Hui Yue(岳冬辉), Ting-Ting Ji(冀婷婷), Yong-Hao Han(韩永昊), Wen-Liang Xu(许文良), Chun-Xiao Gao(高春晓) A new technology for controlling in-situ oxygen fugacity in diamond anvil cells and measuring electrical conductivity of anhydrous olivine at high pressures and temperatures 2020 Chin. Phys. B 29 010702

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A new technology for controlling in-situ oxygen fugacity in diamond anvil cells and measuring electrical conductivity of anhydrous olivine at high pressures and temperatures

Cite this article:

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