Magnetic properties and magnetocaloric effects in (Ho1-xYx)5Pd2 compounds

doi:10.1088/1674-1056/28/5/057502

Abstract

The crystal structure, magnetic and magnetocaloric properties of (Ho_1-xY_x)₅Pd₂ (x=0, 0.25, and 0.5) compounds are investigated. All the compounds crystallize in a cubic Dy₅Pd₂-type structure with the space group Fd3m and undergo a second order transition from spin glass (SG) state to paramagnetic (PM) state. The spin glass transition temperatures T_g decrease from 26 K for x=0 to 13 K for x=0.5. In the PM region, the reciprocal susceptibilities for all the compounds obey the Curie-Weiss law. The paramagnetic Curie temperatures (θ_p) for Ho₅Pd₂, (Ho_0.75Y_0.25)₅Pd₂, and (Ho_0.5Y_0.5)₅Pd₂ are determined to be 32 K, 30 K, and 22 K, respectively, and the corresponding effective magnetic moments (μ_eff) are 10.8 μ_B/Ho, 10.3 μ_B/RE, and 7.5 μ_B/RE, respectively. Magnetocaloric effect (MCE) is anticipated according to the Maxwell relation, based on the isothermal magnetization curves. For a magnetic field change of 0-5 T, the maximum values of the isothermal magnetic entropy change -ΔS_M of the (Ho_1-xY_x)₅Pd₂ (x=0, 0.25, and 0.5) compounds are determined to be 11.5 J·kg^-1·K^-1, 11.1 J·kg^-1·K^-1, and 8.9 K J·kg^-1·K^-1, with corresponding refrigerant capacity values of 382.3 J·kg^-1, 336.2 J·kg^-1, and 242.5 J·kg^-1, respectively.

Keywords: (Ho_1-xY_x)₅Pd₂ compounds magnetic transition magnetocaloric effect

Received: 26 December 2018
Revised: 09 February 2019
Accepted manuscript online:

PACS:	71.20.Eh	(Rare earth metals and alloys)
	75.30.Kz	(Magnetic phase boundaries (including classical and quantum magnetic transitions, metamagnetism, etc.))
	75.30.Sg	(Magnetocaloric effect, magnetic cooling)

Fund:

Project supported by the National Basic Research Program of China (Grant No. 2014CB643703), the National Key Research and Development Program of China (Grant No. 2016YFB0700901), the National Natural Science Foundation of China (Grant Nos. 51261004 and 51761007), and Guangxi Natural Science Foundation, China (Grant No. 2018GXNSFAA294051).

Corresponding Authors: C P Guo, Y S Du
E-mail: cpguo@ustb.edu.cn;duyusong@guet.edu.cn

Cite this article:

X F Wu(武小飞), C P Guo(郭翠萍), G Cheng(成钢), C R Li(李长荣), J Wang(王江), Y S Du(杜玉松), G H Rao(饶光辉), Z M Du(杜振民) Magnetic properties and magnetocaloric effects in (Ho_1-xY_x)₅Pd₂ compounds 2019 Chin. Phys. B 28 057502

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Magnetic properties and magnetocaloric effects in (Ho1-xYx)5Pd2 compounds

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Magnetic properties and magnetocaloric effects in (Ho_1-xY_x)₅Pd₂ compounds