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Chin. Phys. B, 2019, Vol. 28(5): 053102    DOI: 10.1088/1674-1056/28/5/053102
ATOMIC AND MOLECULAR PHYSICS Prev   Next  

Tensile-strain induced phonon splitting in diamond

Meifang Pu(蒲梅芳)1, Feng Zhang(张峰)1, Shan Liu(刘珊)1, Tetsuo Irifune(入舩徹男)2, Li Lei(雷力)1
1 Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China;
2 Geodynamics Research Center, Ehime University, Matsuyama 790-8577, Japan
Abstract  

The first-order Raman spectroscopy of diamond exhibits splitting and redshift after the burst of high-pressure (160-200 GPa) and high-temperature (~2000 K). The observed longitudinal optical (LO) and the transverse optical (TO) splitting of Raman phonon is related to the tensile-strain induced activation of the forbidden or silent Raman modes that arise in the proximity of the Brillouin zone center.

Keywords:  diamond      tensile-strain      phonon splitting      Brillouin zone  
Received:  21 January 2019      Revised:  22 March 2019      Accepted manuscript online: 
PACS:  31.15.ae (Electronic structure and bonding characteristics)  
  61.43.-j (Disordered solids)  
  62.20.M- (Structural failure of materials)  
Fund: 

Project supported by the National Natural Science Foundation of China (Grant No. 11774247).

Corresponding Authors:  Li Lei     E-mail:  lei@scu.edu.cn

Cite this article: 

Meifang Pu(蒲梅芳), Feng Zhang(张峰), Shan Liu(刘珊), Tetsuo Irifune(入舩徹男), Li Lei(雷力) Tensile-strain induced phonon splitting in diamond 2019 Chin. Phys. B 28 053102

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