Study of glass transition kinetics of As2S3 and As2Se3 by ultrafast differential scanning calorimetry

doi:10.1088/1674-1056/28/4/047802

Abstract

Ultrafast differential scanning calorimetry (DSC) was employed to investigate the glass transition kinetics of As₂S₃ and As₂Se₃. By using the Arrhenius method, a fragility index of~22 can be estimated in both As₂S₃ and As₂Se₃. However, when the scanning rate is more than 200 K…^-1, non-Arrhenius behavior can be observed in such “strong” liquids where the Vogel-Fulcher method is more accurate to describe the glass transition kinetics. The fragilities of As₂S₃ and As₂Se₃ glasses are thus extrapolated as 28.3±1.94 and 23.7±1.80, respectively. This indicates that, As₂Se₃ glass has a better structural stability and it is a better candidate for device applications.

Keywords: ultrafast DSC glass transition kinetics fragility index

Received: 27 December 2018
Revised: 29 January 2019
Accepted manuscript online:

PACS:	78.55.Qr	(Amorphous materials; glasses and other disordered solids)
	64.70.P-	(Glass transitions of specific systems)
	61.43.Fs	(Glasses)

Corresponding Authors: Yimin Chen, Junqiang Wang
E-mail: chenyimin@nbu.edu.cn;jqwang@nimte.ac.cn

Cite this article:

Fan Zhang(张凡), Yimin Chen(陈益敏), Rongping Wang(王荣平), Xiang Shen(沈祥), Junqiang Wang(王军强), Tiefeng Xu(徐铁峰) Study of glass transition kinetics of As₂S₃ and As₂Se₃ by ultrafast differential scanning calorimetry 2019 Chin. Phys. B 28 047802

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Study of glass transition kinetics of As2S3 and As2Se3 by ultrafast differential scanning calorimetry

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Study of glass transition kinetics of As₂S₃ and As₂Se₃ by ultrafast differential scanning calorimetry