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Chin. Phys. B, 2018, Vol. 27(10): 108201    DOI: 10.1088/1674-1056/27/10/108201
INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY Prev   Next  

Performance of n-type silicon/silver composite anode material in lithium ion batteries: A study on effect of work function matching degree

Guo-Jun Xu(徐国军), Chen-Xin Jin(金晨鑫), Kai-Jie Kong(孔凯捷), Xi-Xi Yang(杨西西), Zhi-Hao Yue(岳之浩), Xiao-Min Li(李晓敏), Fu-Gen Sun(孙福根), Hai-Bin Huang(黄海宾), Lang Zhou(周浪)
Institute of Photovoltaics, Nanchang University, Nanchang 330031, China
Abstract  

In this paper, two types of silicon (Si) particles ball-milled from n-type Si wafers, respectively, with resistivity values of 1 Ω·cm and 0.001 Ω·cm are deposited with silver (Ag). The Ag-deposited n-type 1-Ω·cm Si particles (n1-Ag) and Ag-deposited n-type 0.001-Ω·cm Si particles (n0.001-Ag) are separately used as an anode material to assemble coin cells, of which the electrochemical performances are investigated. For the matching of work function between n-type 1-Ω·cm Si (n1) and Ag, n1-Ag shows discharge specific capacity of up to 683 mAh·g-1 at a current density of 8.4 A·g-1, which is 40% higher than that of n0.001-Ag. Furthermore, the resistivity of n1-Ag is lower than half that of n0.001-Ag. Due to the mismatch of work function between n-type 0.001-Ω·cm Si (n0.001) and Ag, the discharge specific capacity of n0.001-Ag is 250.2 mAh·g-1 lower than that of n1-Ag after 100 cycles.

Keywords:  lithium ion battery      silicon anode materials      work function matching      contacts  
Received:  26 June 2018      Revised:  23 July 2018      Accepted manuscript online: 
PACS:  82.47.Aa (Lithium-ion batteries)  
  82.45.Fk (Electrodes)  
  65.40.gh (Work functions)  
  73.40.Cg (Contact resistance, contact potential)  
Fund: 

Project supported by the China Postdoctoral Science Foundation (Grant No. 2016M592115), the Jiangxi Postdoctoral Foundation, China (Grant No. 2015KY12), the Fund from the Jiangxi Provincial Education Department, China (Grant No. 150184), and the Fund from Nanchang University, China (Grant No. CX2017006).

Corresponding Authors:  Zhi-Hao Yue     E-mail:  yuezhihao@ncu.edu.cn

Cite this article: 

Guo-Jun Xu(徐国军), Chen-Xin Jin(金晨鑫), Kai-Jie Kong(孔凯捷), Xi-Xi Yang(杨西西), Zhi-Hao Yue(岳之浩), Xiao-Min Li(李晓敏), Fu-Gen Sun(孙福根), Hai-Bin Huang(黄海宾), Lang Zhou(周浪) Performance of n-type silicon/silver composite anode material in lithium ion batteries: A study on effect of work function matching degree 2018 Chin. Phys. B 27 108201

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