Mid-infrared luminescence of Dy3+-doped Ga2S3-Sb2S3-CsI chalcohalide glasses

doi:10.1088/1674-1056/27/7/077105

Abstract The mid-infrared (MIR) luminescent properties of Dy³⁺ ions in a new chalcohalide glass host, Ga₂S₃-Sb₂S₃-CsI, are investigated; and the suitability of the doped glass for MIR fiber lasers is evaluated. The Dy³⁺-doped chalcohalide glasses exhibit good thermal stability and intense MIR emissions around 2.96 μ and 4.41 μm. These emissions show quantum efficiencies (η) as high as ~60%, and have relatively large stimulated emission cross sections (σ_em). The low phonon energy (~307 cm^-1) of the host glass accounts for the intense MIR emissions, as well as the high η. These favorable thermal and emission properties make the Dy³⁺-doped Ga₂S₃-Sb₂S₃-CsI glasses promising materials for MIR fiber amplifiers or lasers.

Keywords: chalcogenide glasses rare earth emission property mid-infrared laser

Received: 24 January 2018
Revised: 30 March 2018
Accepted manuscript online:

PACS:	71.23.Cq	(Amorphous semiconductors, metallic glasses, glasses)
	76.30.Kg	(Rare-earth ions and impurities)
	78.45.+h	(Stimulated emission)
	95.85.Hp	(Infrared (3-10 μm))

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 61405080 and 61575086), Jiangsu Collaborative Innovation Centre of Advanced Laser Technology and Emerging Industry, China, and the Priority Academic Program Development of Jiangsu Higher Education Institutions, China.

Corresponding Authors: Zhiyong Yang
E-mail: yangzhiyong@jsnu.edu.cn

Cite this article:

Anping Yang(杨安平), Jiahua Qiu(邱嘉桦), Mingjie Zhang(张鸣杰), Mingyang Sun(孙明阳), Zhiyong Yang(杨志勇) Mid-infrared luminescence of Dy³⁺-doped Ga₂S₃-Sb₂S₃-CsI chalcohalide glasses 2018 Chin. Phys. B 27 077105

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Mid-infrared luminescence of Dy3+-doped Ga2S3-Sb2S3-CsI chalcohalide glasses

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Mid-infrared luminescence of Dy³⁺-doped Ga₂S₃-Sb₂S₃-CsI chalcohalide glasses