High pressure structural phase transitions of TiO2 nanomaterials

doi:10.1088/1674-1056/25/7/076107

Abstract

Recently, the high pressure study on the TiO₂ nanomaterials has attracted considerable attention due to the typical crystal structure and the fascinating properties of TiO₂ with nanoscale sizes. In this paper, we briefly review the recent progress in the high pressure phase transitions of TiO₂ nanomaterials. We discuss the size effects and morphology effects on the high pressure phase transitions of TiO₂ nanomaterials with different particle sizes, morphologies, and microstructures. Several typical pressure-induced structural phase transitions in TiO₂ nanomaterials are presented, including size-dependent phase transition selectivity in nanoparticles, morphology-tuned phase transition in nanowires, nanosheets, and nanoporous materials, and pressure-induced amorphization (PIA) and polyamorphism in ultrafine nanoparticles and TiO₂-B nanoribbons. Various TiO₂ nanostructural materials with high pressure structures are prepared successfully by high pressure treatment of the corresponding crystal nanomaterials, such as amorphous TiO₂ nanoribbons, α -PbO₂-type TiO₂ nanowires, nanosheets, and nanoporous materials. These studies suggest that the high pressure phase transitions of TiO₂ nanomaterials depend on the nanosize, morphology, interface energy, and microstructure. The diversity of high pressure behaviors of TiO₂ nanomaterials provides a new insight into the properties of nanomaterials, and paves a way for preparing new nanomaterials with novel high pressure structures and properties for various applications.

Keywords: high pressure nanomaterials phase transition TiO₂

Received: 05 June 2015
Revised: 02 July 2015
Accepted manuscript online:

PACS:

61.46.Df

(Structure of nanocrystals and nanoparticles ("colloidal" quantum dots but not gate-isolated embedded quantum dots))

Fund:

Project supported by the National Basic Research Program of China (Grant No. 2011CB808200), the National Natural Science Foundation of China (Grant Nos. 11374120, 11004075, 10979001, 51025206, 51032001, and 21073071), and the Cheung Kong Scholars Programme of China.

Corresponding Authors: Bing-Bing Liu
E-mail: liubb@jlu.edu.cn

Cite this article:

Quan-Jun Li(李全军), Bing-Bing Liu(刘冰冰) High pressure structural phase transitions of TiO₂ nanomaterials 2016 Chin. Phys. B 25 076107

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