Effects of Fe additive on diamond crystallization from carbonyl nickel powders-C system under HPHT condition

doi:10.1088/1674-1056/24/8/088104

Abstract In this paper, diamond crystallization from carbonyl nickel powders-C and carbonyl nickel powders+Fe–C systems are investigated in detail at a pressure of 6.0 GPa and temperatures ranging from 1410 ℃–to 1435 ℃ by temperature gradient growth. The effects of Fe additive on the crystal morphology are discussed in the diamond crystallization process. Furthermore, Fourier infrared measurement results indicate that the spectrum of the diamond obtained from Ni+Fe–C system after annealing treatment is nearly consistent with that of natural diamond crystal. We believe that this study is of benefit to a further understanding of the growth mechanism of natural diamond.

Keywords: high pressure and high temperature carbonyl nickel powder catalyst annealing diamond

Received: 08 February 2015
Revised: 11 March 2015
Accepted manuscript online:

PACS:	81.05.ug	(Diamond)
	81.10.Aj	(Theory and models of crystal growth; physics and chemistry of crystal growth, crystal morphology, and orientation)
	07.35.+k	(High-pressure apparatus; shock tubes; diamond anvil cells)

Fund: Project supported by the National Natural Science Foundation of China (Grant No. 51172089), the Natural Science Foundation of Guizhou Provincial Education Department, China (Grant No. KY [2013]183), and the Research Fund for the Doctoral Program of Tongren University, China (Grant Nos. DS1302 and trxyS1415).

Corresponding Authors: Ma Hong-An
E-mail: maha@jlu.edu.cn

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Li Yong (李勇), Jia Xiao-Peng (贾晓鹏), Feng Yun-Guang (冯云光), Fang Chao (房超), Fan Li-Juan (樊丽娟), Li Ya-Dong (李亚东), Zeng Xiang (曾祥), Ma Hong-An (马红安) Effects of Fe additive on diamond crystallization from carbonyl nickel powders-C system under HPHT condition 2015 Chin. Phys. B 24 088104

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Effects of Fe additive on diamond crystallization from carbonyl nickel powders-C system under HPHT condition

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