Structure and chemical valence study of Srn+1RunO3n+1 (n=1, 2, ∞) series

doi:10.1088/1674-1056/24/5/056101

Abstract Effect of structure parameter n and its coupling with the connection mode among RuO₆ octahedra of Sr_n+1Ru_nO_3n+1 (n=1, 2, ∞) are investigated. The gradually enhanced rotation and tilting effect with increasing n are observed in Sr_n+1Ru_nO_3n+1. Besides, the chemical valence of Ru is not changed, while the one of Sr gradually varies with increasing n, which highlights the great contribution of connection mode to the chemical environment. Our results show a strong n dependence on the connection mode between octahedra in Sr_n+1Ru_nO_3n+1 (n=1, 2, ∞).

Keywords: ruthenates structure parameter x-ray diffraction extended x-ray absorption fine structure

Received: 13 November 2014
Revised: 17 December 2014
Accepted manuscript online:

PACS:	61.05.cp	(X-ray diffraction)
	78.70.Ck	(X-ray scattering)

Corresponding Authors: Zheng Long
E-mail: zhengphy@163.com

About author: 61.05.cp; 78.70.Ck

Cite this article:

Zheng Long (郑龙), Zhu Xiao-Qin (朱小芹), Sui Yong-Xing (眭永兴), Xue Jian-Zhong (薛建忠), Liu Bo (刘波), Pei Ming-Xu (裴明旭) Structure and chemical valence study of Sr_n+1Ru_nO_3n+1 (n=1, 2, ∞) series 2015 Chin. Phys. B 24 056101

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Structure and chemical valence study of Srn+1RunO3n+1 (n=1, 2, ∞) series

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Structure and chemical valence study of Sr_n+1Ru_nO_3n+1 (n=1, 2, ∞) series