Energy transfer relation of a novel Ce3+/Pr3+/Eu3+ co-doped Sr2.975-xLaxAlO4+xF1-x solid solution phosphor

doi:10.1088/1674-1056/23/10/107805

Abstract The photoluminescence properties and energy transfer of a new Ce³⁺/Pr³⁺/Eu³⁺ co-doped solid-solution composition of Sr_2.975-xLa_xAlO_4+xF_1-x (LSAF) phosphor are investigated. Upon doping Pr³⁺ into lattices of LSAF:Ce host, a shoulder emission peak is observed at about 620 nm, owing to the transition of ¹D₂→³H₄. Addition of Eu³⁺ to LSAF:Ce³⁺, Pr³⁺ phosphor results in a sharp emission peaked at 675 nm for the ⁵D₀→⁷F₃ transition and an increase of the intensity of red emission for Pr³⁺ with increasing Eu³⁺ concentration. The pathways of energy transfer among Ce³⁺, Pr³⁺, and Eu³⁺ are proposed to be responsible for color addition of a red component to the primary yellow emission, enabling a potential adjustable color for blue excitable warm white.

Keywords: energy transfer solid solution red emission phosphor

Received: 07 March 2014
Revised: 22 April 2014
Accepted manuscript online:

PACS:

78.55.-m

(Photoluminescence, properties and materials)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 21076161 and 50872091).

Corresponding Authors: Wang Da-Jian
E-mail: djwang@tjut.edu.cn

About author: 78.55.-m

Cite this article:

Wang Yan-Ze (王延泽), Ma Jian (马健), Sun Liang (孙亮), Li Rui (李蕊), Wang Da-Jian (王达健) Energy transfer relation of a novel Ce³⁺/Pr³⁺/Eu³⁺ co-doped Sr_2.975-xLa_xAlO_4+xF_1-x solid solution phosphor 2014 Chin. Phys. B 23 107805


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Energy transfer relation of a novel Ce3+/Pr3+/Eu3+ co-doped Sr2.975-xLaxAlO4+xF1-x solid solution phosphor

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Energy transfer relation of a novel Ce³⁺/Pr³⁺/Eu³⁺ co-doped Sr_2.975-xLa_xAlO_4+xF_1-x solid solution phosphor