Spectroscopic properties of Yb3+-doped TeO2-BaO-BaF2-Nb2O5-based oxyfluoride tellurite glasses

doi:10.1088/1674-1056/23/9/097801

Abstract A series of oxyfluoride glasses with the compositions of 75 mol% TeO₂, 10 mol% Nb₂O₅, (15 mol%-x) BaO, x BaF₂ (x=0 mol%, 5 mol%, 10 mol%, 15 mol%) doped with Yb₂O₃ were prepared by the melt-quenching method. Their emission cross-sections, fluorescence lifetimes, and gain properties were investigated by using the absorption spectra and the fluorescence decay curves. The results show that by substituting BaF₂ for BaO, the emission cross-section decreases from 1.37 pm² to 1.21 pm², and the fluorescence lifetime increases from 0.71 ms to 0.96 ms. These properties indicate that this oxyfluoride tellurite glass may have potential uses as the Yb₂O₃-doped gain medium in a solid laser.

Keywords: Yb oxyfluoride tellurite glass spectroscopic properties gain coefficient

Received: 07 February 2014
Revised: 25 March 2014
Accepted manuscript online:

PACS:	78.55.Qr	(Amorphous materials; glasses and other disordered solids)
	32.50.+d	(Fluorescence, phosphorescence (including quenching))

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 61177086, 61307046, and 61308086) and the West Light Foundation of the Chinese Academy of Sciences (Grant No. Y129261213).

Corresponding Authors: Peng Bo
E-mail: bpeng@opt.ac.cn

Cite this article:

Lin She-Bao (林社宝), Wang Peng-Fei (王鹏飞), She Jiang-Bo (佘江波), Guo Hai-Tao (郭海涛), Xu Shen-Nuo (许慎诺), Yu Cheng-Long (于成龙), Liu Chun-Xiao (刘春晓), Peng Bo (彭波) Spectroscopic properties of Yb³⁺-doped TeO₂-BaO-BaF₂-Nb₂O₅-based oxyfluoride tellurite glasses 2014 Chin. Phys. B 23 097801

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Spectroscopic properties of Yb3+-doped TeO2-BaO-BaF2-Nb2O5-based oxyfluoride tellurite glasses

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Spectroscopic properties of Yb³⁺-doped TeO₂-BaO-BaF₂-Nb₂O₅-based oxyfluoride tellurite glasses