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Chin. Phys. B, 2013, Vol. 22(12): 124207    DOI: 10.1088/1674-1056/22/12/124207
ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS Prev   Next  

Resisting shrinkage properties of volume holograms recorded in TiO2 nanoparticle-dispersed acrylamide-based photopolymer

Zhao Lei (赵磊)a b, Han Jun-He (韩俊鹤)a, Li Ruo-Ping (李若平)a, Wang Long-Ge (王龙阁)a, Huang Ming-Ju (黄明举)a
a Key Discipline Open Laboratory of Photonic and Electronic Information Materials and Devices, Henan University, Kaifeng 475004, China;
b College of Peili Engineering Technology, Lanzhou City University, Lanzhou 730070, China
Abstract  A novel organic–inorganic nanoparticle–photopolymer composite system is developed, and its fundamental holographic recording characteristics are studied. In this hydrophilic TiO2-nanoparticle-dispersed acrylamide photopolymer composite system, the counter-diffusion of monomers and nanoparticles plays a fundamental and key role in hologram grating formation. The experimental results indicate that the volume shrinkage of the nanoparticle–photopolymer film during the holographic recording can be drastically reduced compared with the undoped photopolymer film. It is also found that the diffraction efficiency of the grating recorded in the nanoparticle–photopolymer film depends strongly on the concentration of the TiO2-nanoparticles, and there exists an optimal TiO2-nanoparticle-doping concentration to make the diffraction efficiency and the refractive index modulation reach their maxima. Additionally, the digital data page is stored and reconstructed in the nanoparticle–photopolymer film.
Keywords:  holographic proprieties      TiO2-nanoparticle      diffraction efficiency      Bragg-mismatch  
Received:  24 December 2012      Revised:  04 April 2013      Accepted manuscript online: 
PACS:  42.70.Ln (Holographic recording materials; optical storage media)  
  42.40.Lx (Diffraction efficiency, resolution, and other hologram characteristics)  
  42.40.Pa (Volume holograms)  
Fund: Project supported by the National Natural Science Foundation of China (Grant No. 61177004).
Corresponding Authors:  Huang Ming-Ju     E-mail:  hmingju@163.com

Cite this article: 

Zhao Lei (赵磊), Han Jun-He (韩俊鹤), Li Ruo-Ping (李若平), Wang Long-Ge (王龙阁), Huang Ming-Ju (黄明举) Resisting shrinkage properties of volume holograms recorded in TiO2 nanoparticle-dispersed acrylamide-based photopolymer 2013 Chin. Phys. B 22 124207

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