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Chin. Phys. B, 2013, Vol. 22(7): 077801    DOI: 10.1088/1674-1056/22/7/077801
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES Prev   Next  

Photoluminescence properties of Ce3+ and Mn2+-activated Ba9Sc2Si6O24 phosphor for white light emitting diodes

Bian Liu (边柳), Wang Ting (王婷), Song Zhen (宋振), Liu Zhao-Hui (刘朝晖), Li Jia-Xu (李嘉旭), Liu Quan-Lin (刘泉林)
School of Materials Science & Engineering and State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
Abstract  A single-phased silicate compound (Ba1-xCex)9(Sc1-yMny)2Si6O24 was prepared by solid-state reaction at high temperature. From powder X-ray diffraction (XRD) analysis, the formation of Ba9Sc2Si6O24 with R3 space group was confirmed. In the photoluminescence spectra under ultraviolet (UV) ray excitation, the Ba9Sc2Si6O24:Ce3+, Mn2+ phosphor emits two distinctive color light bands: a blue one originating from Ce3+ and a red one caused by Mn2+. The energy transfer process from Ce3+ to Mn2+ was confirmed, the critical radius as well as the transfer efficiency was calculated, and the energy transfer mechanism was discussed. In addition, the decay-time testing indicates that the energy transfer efficiencies from Ce(1) to Mn2+ and Ce(2) to Mn2+ are different. The emission chromaticity of Ba9Sc2Si6O24:Ce3+, Mn2+ phosphor could be tuned from blue to red by altering the Ce3+/Mn2+ concentration ratio.
Keywords:  Ba9Sc2Si6O24      Ce3+      Mn2+ co-doped      energy transfer  
Received:  26 January 2013      Revised:  04 March 2013      Accepted manuscript online: 
PACS:  78.55.-m (Photoluminescence, properties and materials)  
  87.15.mq (Luminescence)  
  33.50.-j (Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion))  
Fund: Project supported by the National Natural Science Foundation of China (Grant No. 51272027) and the Ph. D. Program Foundation of Education Ministry of China (Grant No. 20100006110011).
Corresponding Authors:  Liu Quan-Lin     E-mail:  qlliu@ustb.edu.cn

Cite this article: 

Bian Liu (边柳), Wang Ting (王婷), Song Zhen (宋振), Liu Zhao-Hui (刘朝晖), Li Jia-Xu (李嘉旭), Liu Quan-Lin (刘泉林) Photoluminescence properties of Ce3+ and Mn2+-activated Ba9Sc2Si6O24 phosphor for white light emitting diodes 2013 Chin. Phys. B 22 077801

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