Photoluminescence and persistent luminescence properties of non-doped and Ti4+-doped Mg2SnO4 phosphors

doi:10.1088/1674-1056/20/9/094211

Abstract Mg₂SnO₄ exhibits green photoluminescence and persistent luminescence, which originate from oxygen vacancies. When Ti⁴⁺ions were doped, an interesting Mg₂SnO₄:Ti⁴⁺ phosphor with bluish white photoluminescence under ultraviolet irradiation and with green persistent luminescence was first obtained. Our investigation reveals that two emission centres exist in Mg₂SnO₄:Ti⁴⁺. The centres responsible for the green emission are considered to be the F centres (oxygen vacancies) and the blue centres are the TiO₆ complex. Trap clusters in the band gap with different depths, such as [Sn_Mg^‥—O_i^″], [Sn_Mg^‥—V_O^·], [Sn_Mg^‥—V_O^×] and Mg_Sn^″, correspond to the components at 85 ℃, 146 ℃ and 213 ℃ of the thermoluminescence curve.

Keywords: phosphor Mg₂SnO₄ persistent luminescence photoluminescence

Received: 02 March 2011
Revised: 30 April 2011
Accepted manuscript online:

PACS:

42.70.-a

(Optical materials)

Cite this article:

Zhang Jia-Chi(张加驰), Qin Qing-Song(秦青松), Yu Ming-Hui(于明汇), Zhou Hong-Liang(周宏亮), and Zhou Mei-Jiao(周美娇) Photoluminescence and persistent luminescence properties of non-doped and Ti⁴⁺-doped Mg₂SnO₄ phosphors 2011 Chin. Phys. B 20 094211

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Photoluminescence and persistent luminescence properties of non-doped and Ti4+-doped Mg2SnO4 phosphors

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Photoluminescence and persistent luminescence properties of non-doped and Ti⁴⁺-doped Mg₂SnO₄ phosphors