Abstract Zeeman modulation-magnetic rotation spectroscopic (ZM-MRS) technique is provided with not only high sensitivity and high signal-to-noise ratio, but also apparent phase character for studying molecular spectrum. It is quite helpful for assigning some complex molecular rotational spectra. As an example, the ZM-MRS spectra of NO2 molecule was measured in the region between 16838cm-1 and 16860cm-1 with high resolution. The semi-classical magnetic rotation theory was used to explain the spectral feature and its phase relation with transition quantum number. It is in agreement with the experimental results. Finally, by using matrix diagonalization of effective Hamiltonian, the ZM-MRS spectra of NO2 molecule were analyzed and a reasonable assignment was obtained.
Received: 30 January 1996
Accepted manuscript online:
Dynamic polarizabilities of the clock states of Al+ Yuan-Fei Wei(魏远飞), Zhi-Ming Tang(唐志明), Cheng-Bin Li(李承斌), Yang Yang(杨洋), Ya-Ming Zou(邹亚明), Kai-Feng Cui(崔凯枫), and Xue-Ren Huang(黄学人). Chin. Phys. B, 2022, 31(8): 083102.
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