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Chin. Phys. B, 2021, Vol. 30(4): 048202    DOI: 10.1088/1674-1056/abc2c1
INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY Prev   Next  

Grain boundary effect on structural, optical, and electrical properties of sol-gel synthesized Fe-doped SnO2 nanoparticles

Archana V1, Lakshmi Mohan1,2,†, Kathirvel P3, and Saravanakumar S4
1 Department of Sciences, Amrita School of Engineering, Coimbatore, Amrita Vishwa Vidyapeetham, India\vglue3pt; 2 Research and Development Center, Bharathiar University, Coimbatore-641046, Tamilnadu, India; 3 GRD Center for Materials Research, Department of Physics, P S G College of Technology, Coimbatore-641004, Tamilnadu, India; 4 Department of Physics, N S S College, Pandalam-689501, Kerala, India
Abstract  Tin oxide (SnO2) and iron-doped tin oxide (Sn1-xFexO2 , x = 0.05 wt%, 0.10 wt%) nanoparticles are synthesized by the simple sol-gel method. The structural characterization using x-ray diffraction (XRD) confirms tetragonal rutile phases of the nanoparticles. The variations in lattice parameters and relative intensity with Fe-doping concentration validate the incorporation of iron into the lattice. The compressive strain present in the lattice estimated by using peak profile analysis through using Williamson-Hall plot also exhibits the influence of grain boundary formation in the lattice. The radiative recombination and quenching observed in optical characterization by using photoluminescence spectrum (PL) and the shift in the band gap estimated from UV-visible diffused reflectance spectrum corroborate the grain boundary influence. Raman spectrum and the morphological analysis by using a field emission scanning electron microscope (FESEM) also indicate the formation of grain boundaries. The compositional analysis by using energy dispersive x-ray spectrum (EDAX) confirms Fe in the SnO2 lattice. The conductivity studies exhibit that the impendence increases with doping concentration increasing and the loss factor decreases at high frequencies with doping concentration increasing, which makes the Sn1-xFexO2 a potential candidate for device applications.
Keywords:  sol-gel      compressive strain      grain boundary      AC conductivity  
Received:  11 July 2020      Revised:  27 September 2020      Accepted manuscript online:  20 December 2020
PACS:  82.33.Ln (Reactions in sol gels, aerogels, porous media)  
  75.75.Fk (Domain structures in nanoparticles)  
  72.80.Ey (III-V and II-VI semiconductors)  
  74.62.Dh (Effects of crystal defects, doping and substitution)  
Corresponding Authors:  Corresponding author. E-mail: lakshmi_mohan@cb.amrita.edu   

Cite this article: 

Archana V, Lakshmi Mohan, Kathirvel P, and Saravanakumar S Grain boundary effect on structural, optical, and electrical properties of sol-gel synthesized Fe-doped SnO2 nanoparticles 2021 Chin. Phys. B 30 048202

1 Chavali M S and Nikolova M P 2019 SN Appl. Sci. 1 607
2 Bajpai N, Khan S A, Kher R S, Bramhe N, Dhoble S J and Tiwari A 2014 J. Lumin. 145 940
3 Jiang Q, Zhang X and You J 2018 Nano-Micro Small 14 1
4 Carre? no N L V, Nunes M R, Garcia I T S, Orlandi M O, Fajardo H V and Longo E 2009 J. Nanoparticle Res. 11 955
5 Batzill M and Diebold U 2005 Prog. Surf. Sci. 79 47
6 Doke S, Ganguly P and Mahamuni S2020 D Liq. Cryst. 00 1
7 Li H, Su Q, Kang J, Huang M, Feng M, Feng H, Huang P and Du G 2018 Mater. Lett. 217 276
8 Elango G and Roopan S M2016 E J. Photochem. Photobiol. B Biol. 155 34
9 Viet P Van, Thi C M and Hieu L Van2016 J. Nanomater. 2016
10 Li Z and Yi J 2017 Sensors Actuators B Chem. 243 96
11 Hermawan A, Asakura Y, Inada M and Yin S 2019 Ceram. Int. 45 15435
12 Xie H, Yin X, Chen P, Liu J, Yang C, Que W and Wang G 2019 Mater. Lett. 234 311
13 Karthik K, Revathi V and Tatarchuk T 2018 Mol. Cryst. Liq. Cryst. 671 17
14 Arularasu M V, Anbarasu M, Poovaragan S, Sundaram R, Kanimozhi K, Magdalane C M, Kaviyarasu K, Thema F T, Letsholathebe D, Mola G T and Maaza M 2017 J. Nanosci. Nanotechnol. 18 3511
15 Shanmugam N, Sathya T, Viruthagiri G, Kalyanasundaram C, Gobi R and Ragupathy S 2016 Appl. Surf. Sci. 360 283
16 Patil G E, Kajale D D, Gaikwad V B and Jain G H 2012 Int. Nano Lett. 2 2
17 Zhang J and Gao L2004 S J. Solid State Chem. 177 1425
18 Marzec A, Radecka M, Maziarz W, Kusior A and Pedzich Z2016 S J. Eur. Ceram. Soc. 36 2981
19 Voon C H, Foo K L, Lim B Y, Gopinath S C B and Al-Douri Y2020 Synthesis and Preparation of Metal-Oxide Powders, Metal Oxides ed Al-Douri(Elsevier) pp. 31-65
20 Al-Samarai R A, Mahmood A S and Al-Douri Y2020 5 Metal Oxides ed Al-Douri(Elsevier) pp. 83-99
21 Wang E, Chen P, Yin X, Wu Y and Que W2019 Sol. RRL 3 1
22 Alexandrescu R, Morjan I, Dumitrache F, Birjega R, Fleaca C, Luculescu C R, Popovici E, Soare I, Sandu I, Dutu E and Prodana G2010 J. Optoelectron. Adv. Mater. 12 599
23 Tian Z M, Yuan S L, He J H, Li P, Zhang S Q, Wang C H, Wang Y Q, Yin S Y and Liu L 2008 J. Alloys Compd. 466 26
24 Toloman D, Popa A, Stan M, Socaci C, Biris A R, Katona G, Tudorache F, Petrila I and Iacomi F 2017 Appl. Surf. Sci. 402 410
25 Dorneanu P P, Airinei A, Grigoras M, Fifere N, Sacarescu L, Lupu N and Stoleriu L 2016 J. Alloys Compd. 668 65
26 Mani R, Vivekanandan K and Vallalperuman K 2017 J. Mater. Sci. Mater. Electron. 28 4396
27 Kaur N, Abhinav, Singh G P, Singh V, Kumar S and Kumar D2016 AIP Conf. Proc. 1728 1
28 Barkley T K, Vastano J E, Applegate J R and Bakrania S D2012 Adv. Mater. Sci. Eng. 2012
29 Tran R, Xu Z, Zhou N, Radhakrishnan B, Luo J and Ong S P 2016 Acta Mater. 117 91
30 Ben Haj Othmen W, Sdiri N, Elhouichet H and Férid M 2016 Mater. Sci. Semicond. Process. 52 46
31 Garnet N S, Ghodsi V, Hutfluss L N, Yin P, Hegde M and Radovanovic P V 2017 J. Phys. Chem. C 121 1918
32 Cullity B D1956 Elements of X-ray Diffraction(Addison-Wesley Publishing)
33 Howard C J, Hunter B A and Kim D1998 43 241
34 Kaur J, Shah J, Kotnala R K and Verma K C2012 R Ceram. Int. 38 5563
35 Sabri N S, Deni M S M, Zakaria A and Talari M K 2012 Phys. Procedia 25 233
36 Asiltürk M and Sayílkan F2009 J. Photochem. Photobio.A 203 64
37 Liu C M, Fang L M, Zu X T and Zhou W L 2007 Chin. Phys. 16 95
38 Chang C H, Gong M, Dey S, Liu F and Castro R H R 2015 J. Phys. Chem. C 119 6389
39 Pereira M S, Ribeiro T S, Lima F A S, Santos L P M, Silva C B, Freire P T C and Vasconcelos I F2018 J. Nanoparticle Res. 20 2029
40 Rani S, Roy S C, Karar N and Bhatnagar M C 2007 Solid State Commun. 141 214
41 Rohith N M, Kathirvel P, Saravanakumar S and Mohan L2018 Optik (Stuttg.) 172 940
42 Bindu P and Thomas S2014 J. Theor. Appl. Phys. 8 123
43 A Narmada, P Kathirvel, Mohan L, S Saravanakumar, R Marnadu and J Chandrasekhar2020 Optik (Stuttg.) 202 163701
44 Muhammed Shafi P and Chandra Bose A2015 AIP Adv. 5 057137
45 Fang L M, Zu X T, Li Z J, Zhu S, Liu C M, Zhou W L and Wang L M 2008 J. Alloys Compd. 454 261
46 Winyayong A and Wongsaprom K2019 N Journal of Physics: Conference Series Vol. 1380
47 Mohan L, Sisupalan N, Ponnusamy K and Sadagopalan S 2020 J. Inorg. Organomet. Polym. Mater. 30 2626
48 Babu B, Neelakanta Reddy I, Yoo K, Kim D and Shim J 2018 Mater. Lett. 221 211
49 Adàn C, Bahamonde A, Fernàndez-Garc\'ía M and Mart\'ínez-Arias A 2007 Appl. Catal. B Environ. 72 11
50 Kumar V and Singh J K2010 Indian J. Pure Appl. Phys. 48 571
51 Haouanoh D, TalaIghil R Z, Toubane M, Bensouici F and Mokeddem K 2019 Mater. Res. Express 6 086422
52 Zadsar M, Fallah H R, Haji Mahmoodzadeh M, Hassanzadeh A and Ghasemi Varnamkhasti M 2012 Mater. Sci. Semicond. Process. 15 432
53 Gu F, Wang S F, Song C F, Lü M K, Qi Y X, Zhou G J, Xu D and Yuan D R 2003 Chem. Phys. Lett. 372 451
54 Gu F, Wang S F and Lu M K2004 Photoluminescence Properties of SnO2 Nanoparticles Synthesized by Sol-Gel Method 8119-23
55 Romano-rodr\imath A2001 T J. Appl. Phys. 90 1550
56 Das S, Kar S and Chaudhuri S2006 J. Appl. Phys. 99 058201
57 Ben W, Othmen H, Sieber B, Elhouichet H, Addad A, Gelloz B, Moreau M, Szunerits S and Boukherroub R 2018 Mater. Sci. Semicond. Process. 77 31
58 Abello L, Bochu B, Gaskov A, Koudryavtseva S, Lucazeau G and Roumyantseva M 1998 J. Solid State Chem. 135 78
59 Periyasamy M and Kar A 2020 J. Mater. Chem. C 8 4604
60 Shajira P S, Prabhu V G and Bushiri M J 2015 J. Phys. Chem. Solids 87 244
61 Moldovan D, Wolf D, Phillpot S R and Haslam A J2003 Trends in Nanoscale Mechanics pp. 35-59
62 Moldovan D, Wolf D and Phillpot S R 2001 Acta Mater. 49 3521
63 Barik Subrat, Choudhary R N and Singh A K 2011 Adv. Mater. Lett. 2 419
64 Chenari H M, Hassanzadeh A, Golzan M M, Sedghi H and Talebian M 2011 Curr. Appl. Phys. 11 409
65 Khan R and Fashu S 2017 J. Mater. Sci. Mater. Electron. 28 4333
66 Azam A, Ahmed A S, Ansari M S, M M S and Naqvi A H 2010 J. Alloys Compd. 506 237
67 Ashokkumar M and Muthukumaran S 2015 J. Lumin. 162 97
68 Wang C J, Wang Y and Gao C X 2019 Acta Phys. Sin. 68 206401 (in Chinese)
69 Marnadu R, Chandrasekaran J, Maruthamuthu S, Balasubramani V, Vivek P and Suresh R 2019 Appl. Surf. Sci. 480 308
70 Soitah T N, Yang C and Sun L 2011 Mater. Sci. Semicond. Process. 13 125
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